Show the complete mechanism of the acidification of disodium adipate and calculate pKeq for both protonation steps. Note: pKa1 = 4.0, pKa2 = 4.4 for adipic acid. A mechanism must show all nbe’s and show movement of e’s with curved arrows.

Chemistry: Principles and Reactions
8th Edition
ISBN:9781305079373
Author:William L. Masterton, Cecile N. Hurley
Publisher:William L. Masterton, Cecile N. Hurley
Chapter22: Organic Chemistry
Section: Chapter Questions
Problem 28QAP: When the conjugate acid of aniline, C6H5NH3+, reacts with the acetate ion, the following reaction...
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Show the complete mechanism of the acidification of disodium adipate and calculate pKeq for both protonation steps. Note: pKa1 = 4.0, pKa2 = 4.4 for adipic acid. A mechanism must show all nbe’s and show movement of e’s with curved arrows.

cyclohexene
+
MnO47OH*
heat
+ MnO₂
COO™
COO
disodium adipate
HCI
COOH
COOH
adipic acid
(hexanedioic acid)
Transcribed Image Text:cyclohexene + MnO47OH* heat + MnO₂ COO™ COO disodium adipate HCI COOH COOH adipic acid (hexanedioic acid)
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