Solid calcium (CaF2) reacts with sulfuric acid to form solid calcium sulfate and gaseous hydrogen fluoride. The HF is then dissolved in water to form hydrofluoric acid. A source of calcium fluoride is fluorite ore containing 96 wt% CaF2 and 4% SiO2. In a typical hydrofluoric acid manufacturing process, fluorite ore is reacted with 93 wt% aqueous sulfuric acid, supplied 15% in excess of the stoichiometric amount. Ninety-five percent of the ore dissolves in the acid. Some of the HF formed reacts with the dissolved silica in the reaction 6 HF + SIO2 (aq) → H2SIF6 (s) +2 H2O 0 The hydrogen fluoride exiting from the reactor is subsequently dissolved in enough water to produce 60 wt% hydrofluoric acid. Calculate the quantity of fluorite ore needed to produce a metric ton of acid. Express your answer into three significant figures.

Chemistry: Principles and Reactions
8th Edition
ISBN:9781305079373
Author:William L. Masterton, Cecile N. Hurley
Publisher:William L. Masterton, Cecile N. Hurley
Chapter16: Spontaneity Of Reaction
Section: Chapter Questions
Problem 48QAP
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Solid calcium (CaF2) reacts with sulfuric acid to form solid calcium sulfate and gaseous hydrogen fluoride. The HF is
then dissolved in water to form hydrofluoric acid. A source of calcium fluoride is fluorite ore containing 96 wt% CaF2
and 4% SiO2.
In a typical hydrofluoric acid manufacturing process, fluorite ore is reacted with 93 wt% aqueous sulfuric acid, supplied
15% in excess of the stoichiometric amount. Ninety-five percent of the ore dissolves in the acid. Some of the HF formed
reacts with the dissolved silica in the reaction
6 HF + SIO2 (aq) – H2SİF6 (9) + 2 H2O (1)
The hydrogen fluoride exiting from the reactor is subsequently dissolved in enough water to produce 60 wt%
hydrofluoric acid. Calculate the quantity of fluorite ore needed to produce a metric ton of acid. Express your answer
into three significant figures.
Transcribed Image Text:Solid calcium (CaF2) reacts with sulfuric acid to form solid calcium sulfate and gaseous hydrogen fluoride. The HF is then dissolved in water to form hydrofluoric acid. A source of calcium fluoride is fluorite ore containing 96 wt% CaF2 and 4% SiO2. In a typical hydrofluoric acid manufacturing process, fluorite ore is reacted with 93 wt% aqueous sulfuric acid, supplied 15% in excess of the stoichiometric amount. Ninety-five percent of the ore dissolves in the acid. Some of the HF formed reacts with the dissolved silica in the reaction 6 HF + SIO2 (aq) – H2SİF6 (9) + 2 H2O (1) The hydrogen fluoride exiting from the reactor is subsequently dissolved in enough water to produce 60 wt% hydrofluoric acid. Calculate the quantity of fluorite ore needed to produce a metric ton of acid. Express your answer into three significant figures.
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