Spectrum of Cu(NH), λ (nm) 420 430 440 450 460 470 480 490 Beer's Law ml. 0.1 M CuSO 1 2 3 4 5 6 7 8 9 10 0.015 0.027 0.066 0.055 0.053 0.024 0.058 0.134 moles A CuSO 0.001 0.002 0.003 0.004 0.005 0.006 0.007 0.008 0.009 0.010 mL 2.5M NH₂ 5 5 5 5 5 5 5 5 5 5 (nm) 500 510 520 530 540 550 560 570 moles NH₂ A 0.182 0.205 0.271 0.847 0.395 0.457 0.513 0.570 moles Cu(NH₂) formed 0.001 0.002 0.003 0.004 0.005 0.006 0.007 0.008 0.009 0.010 (nm) 580 590 600 610 620 630 640 650 conc Cu(NH₂) conc Cu(NH₂) x 10¹ A 0.612 0.6010 0.625 0.629 0.675 0.646 0.613 0.591 A 0.100 0.210 0.185 0.252 0.273 0.328 0.211 0.403 0.352 0.293

Principles of Instrumental Analysis
7th Edition
ISBN:9781305577213
Author:Douglas A. Skoog, F. James Holler, Stanley R. Crouch
Publisher:Douglas A. Skoog, F. James Holler, Stanley R. Crouch
Chapter34: Particle Size Determination
Section: Chapter Questions
Problem 34.9QAP
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fill in the blanks solution volume is 50/1000
Spectrum of Cu(NH₂),
λ (nm)
420
430
440
450
460
470
480
490
Beer's Law
mL
0.1 M
CuSO
1
2
3
4
5
6
7
8
9
10
0.015
0.027
0.066
0.055
0.053
0.024
0.058
0.134
moles
A
mL.
CuSO4 2.5M
NH₂
5
0.001
0.002
0.003
0.004
0.005
0.006
0.007
0.008
0.009
0.010
5
5
5
5
5
5
5
5
5
Unknown
Absorbance of unknown Cu(NH₂):
λ(nm)
500
510
520
530
540
550
560
570
moles
NH₂
A
0.182
0.205
0.271
0.847
0.395
0.457
0.513
0.570
moles
Cu(NH₂)
formed
0.001
0.002
0.003
0.004
0.005
0.006
0.007
0.008
0.009
0.010
(nm)
580
590
600
610
620
630
640
650
conc
Cu(NH₂)
conc
Cu(NH₂)
x 10¹¹
A
0.612
0.6010
0.625
0.629
0.675
0.646
0.613
0.591
0.100
0.210
0.185
0.252
0.273
0.328
0.211
0.403
0.352
0.293
Transcribed Image Text:Spectrum of Cu(NH₂), λ (nm) 420 430 440 450 460 470 480 490 Beer's Law mL 0.1 M CuSO 1 2 3 4 5 6 7 8 9 10 0.015 0.027 0.066 0.055 0.053 0.024 0.058 0.134 moles A mL. CuSO4 2.5M NH₂ 5 0.001 0.002 0.003 0.004 0.005 0.006 0.007 0.008 0.009 0.010 5 5 5 5 5 5 5 5 5 Unknown Absorbance of unknown Cu(NH₂): λ(nm) 500 510 520 530 540 550 560 570 moles NH₂ A 0.182 0.205 0.271 0.847 0.395 0.457 0.513 0.570 moles Cu(NH₂) formed 0.001 0.002 0.003 0.004 0.005 0.006 0.007 0.008 0.009 0.010 (nm) 580 590 600 610 620 630 640 650 conc Cu(NH₂) conc Cu(NH₂) x 10¹¹ A 0.612 0.6010 0.625 0.629 0.675 0.646 0.613 0.591 0.100 0.210 0.185 0.252 0.273 0.328 0.211 0.403 0.352 0.293
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