Sulfolene is a precursor for 1,3-butadiene in this experiment. It reacts by a “cycloreversion" reaction (think reverse Diels-Alder). Draw the mechanism that shows the formation of 1,3- butadiene from sulfolene. 140°C SO2 + Once 1,3-butadiene forms, it can participate in the Diels-Alder reaction. Draw the mechanism for the Diels-Alder reaction. 140°C If you measured the optical rotation of the Diels-Alder product, you would observe no optical activity. Why not?
Sulfolene is a precursor for 1,3-butadiene in this experiment. It reacts by a “cycloreversion" reaction (think reverse Diels-Alder). Draw the mechanism that shows the formation of 1,3- butadiene from sulfolene. 140°C SO2 + Once 1,3-butadiene forms, it can participate in the Diels-Alder reaction. Draw the mechanism for the Diels-Alder reaction. 140°C If you measured the optical rotation of the Diels-Alder product, you would observe no optical activity. Why not?
Organic Chemistry
8th Edition
ISBN:9781305580350
Author:William H. Brown, Brent L. Iverson, Eric Anslyn, Christopher S. Foote
Publisher:William H. Brown, Brent L. Iverson, Eric Anslyn, Christopher S. Foote
Chapter20: Dienes, Conjugated Systems, And Pericyclic Reactions
Section: Chapter Questions
Problem 20.35P: The following triene undergoes an intramolecular Diels-Alder reaction to give a bicyclic product....
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