Answered: Suppose the decomposition of ozone…

Suppose the decomposition of ozone proceeds by the following mechanism: step elementary reaction rate constant 1 03(g) → O₂(g) + O(g) k₁ 2 03(g) + O(g) → 20₂(g) k₂ Suppose also k₁<

Chemistry: Matter and Change

1st Edition

ISBN:9780078746376

Author:Dinah Zike, Laurel Dingrando, Nicholas Hainen, Cheryl Wistrom

Publisher:Dinah Zike, Laurel Dingrando, Nicholas Hainen, Cheryl Wistrom

Chapter16: Reaction Rates

Section: Chapter Questions

Problem 69A

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Question

TIA

Suppose the decomposition of ozone proceeds by the following mechanism:
step elementary reaction rate constant
103(g) 0₂(g) + O(g)
2 O3(g) + O(g) → 20₂(g)
Suppose also k₁<<k₂. That is, the first step is much slower than the second.
Write the balanced
chemical equation for the
overall chemical reaction:
Write the experimentally-
observable rate law for the
overall chemical reaction.
Note: your answer should
not contain the
concentrations of any
intermediates.
Express the rate constant
k for the overall chemical
reaction in terms of k₁, K₂,
and (if necessary) the rate
constants k-₁ and k-2 for
the reverse of the two
elementary reactions in
the mechanism.
0
rate = k
k =
k₁
k₂
0
1-0
X
5
?

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