The diffusivity of I₂ in CCI, is 1.5 x 10-cm³s¹ at 320 K. At the same temperature the rate coefficient for combination of atomic iodine in CCI, was recorded as 7 × 10¹² cm³ mols with a flash method. If the reaction is diffusion controlled, and the diffusivity of the atom is the same as for the diatomic molecule, do the data give an acceptable model? The equilibrium nuclear separation of I, is 2.66 x 10-8 cm.

Introduction to Chemical Engineering Thermodynamics
8th Edition
ISBN:9781259696527
Author:J.M. Smith Termodinamica en ingenieria quimica, Hendrick C Van Ness, Michael Abbott, Mark Swihart
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The diffusivity of I, in CCI, is 1.5 x 10 cm's at 320 K. At the same temperature the
rate coefficient for combination of atomic iodine in CCI, was recorded as 7 x 102 cm
mol-s- with a flash method. If the reaction is diffusion controlled, and the diffusivity of
the atom is the same as for the diatomic molecule, do the data give an acceptable model?
The equilibrium nuclear separation of I, is 2.66 x 10-8 cm.
Transcribed Image Text:The diffusivity of I, in CCI, is 1.5 x 10 cm's at 320 K. At the same temperature the rate coefficient for combination of atomic iodine in CCI, was recorded as 7 x 102 cm mol-s- with a flash method. If the reaction is diffusion controlled, and the diffusivity of the atom is the same as for the diatomic molecule, do the data give an acceptable model? The equilibrium nuclear separation of I, is 2.66 x 10-8 cm.
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