The initial rate method was used to investigate the following reaction: 2Hze) + 2NO + 2H2Ou + Nata) The results of some studies which were made at 775°C are shown below: [H2] / 10 mol dm [NO]/ 10 mol dm Rate / 106 mol dms1 2.0 2.50 4.8 2.0 1.25 1.2 2.0 5.00 19.2 1.0 1.25 0.6 4.0 2.50 9.6 Using the data shown above, answer the questions on the following page.

Principles of Modern Chemistry
8th Edition
ISBN:9781305079113
Author:David W. Oxtoby, H. Pat Gillis, Laurie J. Butler
Publisher:David W. Oxtoby, H. Pat Gillis, Laurie J. Butler
Chapter18: Chemical Kinetics
Section: Chapter Questions
Problem 53AP
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Part A
Magnesium reacts with hydrochloric acid to form hydrogen gas. The data below shows how the
hydrochloric acid concentration varied with time.
Time (s)
[HCI) (mol dm-3)1.00 0.51
10
70
0.08
20
30
40
50
60
80
0.25 0.16
0.13
0.11
0.09
0.06
a) Plot a graph of acid concentration against time.
b) By drawing gradients, calculate the rate at 0, 10, 20 and 30 seconds.
c) Explain why the rate changes during the reaction as it does.
Part B
The initial rate method was used to investigate the following reaction:
2Hzia) + 2NOLg) + 2H2Olg) + Naia)
The results of some studies which were made at 775°C are shown below:
[H2] / 102 mol dm
[NO]/ 102 mol dm3
Rate / 10 mol dms1
2.0
2.50
4.8
2.0
1.25
1.2
2.0
5.00
19.2
1.0
1.25
0.6
4.0
2.50
9.6
Using the data shown above, answer the questions on the following page.
a) What is the order of reaction with respect to Hzg)?
b) What is the order of reaction to NOy?
c) Write down the rate equation for this reaction.
d) Calculate a value for the rate constant for this reaction at 775°C.
Transcribed Image Text:Part A Magnesium reacts with hydrochloric acid to form hydrogen gas. The data below shows how the hydrochloric acid concentration varied with time. Time (s) [HCI) (mol dm-3)1.00 0.51 10 70 0.08 20 30 40 50 60 80 0.25 0.16 0.13 0.11 0.09 0.06 a) Plot a graph of acid concentration against time. b) By drawing gradients, calculate the rate at 0, 10, 20 and 30 seconds. c) Explain why the rate changes during the reaction as it does. Part B The initial rate method was used to investigate the following reaction: 2Hzia) + 2NOLg) + 2H2Olg) + Naia) The results of some studies which were made at 775°C are shown below: [H2] / 102 mol dm [NO]/ 102 mol dm3 Rate / 10 mol dms1 2.0 2.50 4.8 2.0 1.25 1.2 2.0 5.00 19.2 1.0 1.25 0.6 4.0 2.50 9.6 Using the data shown above, answer the questions on the following page. a) What is the order of reaction with respect to Hzg)? b) What is the order of reaction to NOy? c) Write down the rate equation for this reaction. d) Calculate a value for the rate constant for this reaction at 775°C.
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