Use full-headed or half-headed curved arrows to show the movement of electrons in each reaction. d. / + Br2 a. :O: b. CH3-C-CH3 e. CH,CH,Br: + FỘH CH,CH,ÖH + CH CH3 CH3 CH3 c-c-H H c. CH3 CH,-i: f. + FÖH C=C + Hzö: CH3 CH3
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- 12. Predict the products of the following reactions. HBr a. OH conc. H₂SO4 heat b. C₁ H₂C d. H CH3 OH OH H H Br₂/ heat Br NaOCH₂CH3 ethanol heat -CH3 NaOCH₂CH3 ethanol heat A HO 9. OH h. X Br f. j. OH conc. H₂PO4 heat SOCI₂ G conc. acid heat NaOCH 3 methanol heat methanolUse full-headed a. GEO :0 curved arrows to show the movement of electrons in each reaction. b. CH3-C-CH3 CI: + :0: + Br CH3 CH3 CE C. CH₂CH₂Br: + OH CH3 H d. C CH3 I -C-H T H + OH CH3CH₂OH + Bri CH3 H C=C CH3 H + H₂O:Draw the products of each reaction. NH3 [1] NH,CI, NaCN a. BrCH,COOH Тarge excess c. CH,CH,CH(CH,)CHO [2] H30* H [1] NaOEt [1) N2OE! b. CH;CONH--cOOEt ČOOEt [2] (CH3),CHCI [3] H3O*, A d. CH;CONH-C-cOOEt cOOEt [2] BRCH,CO,Et [3] H3O*, A
- 15. CH3 CH;C-CHCH3 + HBr- What is the major product for the reaction above? CH3 Da. CH;CH-CHCH3 Br CH3 O b. CH;CH-CH2-CH2 Br CH3 CH;C-CH,CH; Br Br CH3 d. CH3-CH-CH,CH310. Consider the reaction below to answer the following question(s). CH3 CH3 H;C C=CH2 H3C-C-C1 H20 H;C- C-OH + ethanol CH3 CH3 H3C 1. Compound B is the: Sv2 product S,1 product E2 product El product a. b. C. d. II. Compound Cis the: S,2 product Sy1 product E2 product d. El product a. b. C.Draw the product formed in each reaction. [1] NANO2, HCI [2) CuBr [1] NaNO2, HCI [2] HBF, -NH2 c. CH,O- -NH2 a. [1] NaNO2, HCI (2] H20 [1) CUCN [2] LIAIH, [3] H20 b. -NH2 d. -N2* Cr
- 14. CH, =CH-CH,CH, + H.OHSO4 What is the major product of the reaction above? OH a. CH3-CH-CH,CH; OH b.T CH-CH2-CH,CH3 ОН C. CH;-C-CH,CH3 OH d. CH-CH-CH,CH31. Predict the major product. a. b. C. CHO NH₂ + + 1. EtOH, HCI 2. NaOH, H₂O NH2 NaBH3CN, HCI H N 1, excess CH31 2, Ag2O, H2O, heat (ONE carbon more than reactant) d. S f. Ο Ο S 1. KOH, H₂O N 2. Benzoic acid 3. Dibal-H; then work-up KOH, H₂O N then 6 g. 1, LDA, -78°C, then Etl 2, LDA, -78°C, then Mel h. 1, NaH, 25°C, then Etl 2, NaH, 25°C, then MelProvide the appropriate reagents or product in the following examples. 1. OH O Он 2. 1. m-CPBA, CH-C MgBr THF; aq. HCI 2. Me 3. PCC, CH,C, 3. 1. LDA, THF; Mel 2. LDA, THF; Mel 3. EILI (2 equiv), Cul (1 equiv). THF: then Br 4. Meo Meo 5. Meo Meo. OMe 6. Br 1. BuLi, Ph,P. THE OMe Me 2. Br, MeCN 3. aq. HCI (4 M) Me 7. он но Et,N
- Give major product 0. hv OAc H. Ph p. Ph heat 9. NaOEt BF4 NO PhOC- Ph rr. Heat H3C = -Co,Et CH3 s. CH3 Heat ON=N H3C tt. Нeat Ph uu. Нeat CH3 v. 1. H,O2 2. heat SePhDraw the organic products formed in each reaction. H,N. a. CH;OH, H* OH (CH3),CO. е. H2 OCH,C3H5 Pd-C H CH(CH3)2 H CH(CHa)2 H2N b. CeHsCH,OH, H* HBr но. f. starting material in (e) CH,COOH H CH,CH(CH3)2 [(CH3),COCOLO (CH3CH2);N CF;COOH с. NH,CH2COOH g. product in (e) DCC OH NazCO3 d. product in (b) + product in (c) Fmoc-CI H,N H H20Which is the major product of the following reaction ? CH,CH, H;C-c-CH,CH, CH,CH, H,C-CH-CH=CH2 1 CH;CH, H,C-CH-CH-CH, heat II CH,CH, H,C-c-CH-CH, CHCH; H,C-č-CH,CH, OH II IV a. I b. II C.I d. IV