Question 21 Using the acetoacetic ester synthesis, to produce 5-methyl-2-heptanone, the alkyl halide that should be used is:ο ο οι1-bromo-2-methylpentane1-bromo-2-methylnonane1-bromo-2-methylbutane1-bromo-2-methyldecane1-bromo-5-methylheptane

Answered: Image /qna-images/answer/64bae38c-867f-410c-9399-8abb2113ab65.jpg

Using the acetoacetic ester synthesis, to produce 5-methyl-2-heptanone, the alkyl halide that should be used is: O 1-bromo-2-methylpentane O 1-bromo-2-methylnonane O 1-bromo-2-methylbutane 1-bromo-2-methyldecane 1-bromo-5-methylheptane

Using the acetoacetic ester synthesis, to produce 5-methyl-2-heptanone, the alkyl halide that should be used is: O 1-bromo-2-methylpentane O 1-bromo-2-methylnonane O 1-bromo-2-methylbutane 1-bromo-2-methyldecane 1-bromo-5-methylheptane

Organic Chemistry

9th Edition

ISBN:9781305080485

Author:John E. McMurry

Publisher:John E. McMurry

Chapter21: Carboxylic Acid Derivatives: Nucleophilic Acyl Substitution Reactions

Section21.SE: Something Extra

Problem 54AP: The following reactivity order has been found for the saponification of alkyl acetates by aqueous...

See similar textbooks

Related questions

Q: Draw a carboxylic acid that results from the hydrolysis of glyceryl tributyrate (Figure 1). Include…

A: Glyceryl tributyrate is an ester. On hydrolysis, it yields a carboxylic acid and a trialcohol.

Q: Propose an efficient synthesis for the following transformation: The transformation above can be…

Q: Sample 15 ppm calcium 2 10 ppm calcium and 10ppm phosphate 3 5ppm Ca,10ppm phosphate and 1%…

A: Solution- The given data is the absorbance of calcium and their ingredients.

Q: 4. Calculate the hydroxide ion concentration in a 0.0100 M sodium hypochlorite solution.

A: Sodium hypochlorite, NaOCl(aq) is the conjugate base of hypochlorous acid, HOCl with Ka = 2.95*10-8…

Q: Which one of the following is the solubility product constant for Mn(OH)₂?

Q: Complete the statement, "Cyclooctadeca-1,3,5,7,9,11,13,15,17-nonaene [C18H18] is O antiaromatic;…

Q: Given the reaction below, which is the major product? д ABC O DEF HBr ОН ABC Br + Br DEF ОН

Q: What is the first step in the mechanism for electrophilic aromatic substitutions and What is the…

Q: Choose the correct statement(s) regarding Aryl halides participation in Transition metal catalyzed…

Q: How much heat is needed to melt 10.0 grams of ice at -10°C until it is water at 10°C?

A: Given, mass of ice = 10.0 g Initial temperature (Ti) = -10°C Final temperature (Tf) = 10°C Amount of…

Q: A student sets up the following equation to convert a measurement. (The ? stands for a number the…

Q: (d) Substituent X was varied between electron donating and electron withdrawing groups in the…

Q: Multiple Response Question Select the criteria for any compound to be considered aromatic. The…

A: We have to select the criteria for any compound to be considered aromatic from the given statements.

Q: Use the following two titration curves to answer each of the following statements. Select the choice…

A: A solution with pH greater than 7 is a basic. A solution with pH leass than 7 is a acidic. A…

Q: IUPAC Naming Instructions: Provide proper IUPAC names. Name: el

Q: of 31 > 02 31 Complete and balance the equation for the single displacement reaction between…

Q: A gaseous fuel containing methane and ethane is burned with excess air. The fuel enters the furnace…

Q: Ca[Mo(CN)2(C2O4)(en)]2 coordination compound name

Q: Drag and drop the terms to label this diagram of a titration apparatus accurately. burette stopcock…

A: Here, we have to label the given diagram of a titration apparatus.

Q: Relative Intensity 100 80 60 40 20 0 tmtmitt 20 40 60 80 100 120 140 160 180 200 220 MF: C₂H5XO3…

A: It is. : C7H5BrO3 (Salicylic acid ) Top peaks at 63, 170,198, 216 Molecular weight is 217

Q: A sample of xenon gas collected at a pressure of 0.978 atm and a temperature of 23.0 °C is found to…

A: Here given----- Pressure (P) = 0.978 atm Volume (V) = 27.7 L Temperature (T) = 23 0C = (273+23) K =…

Q: Propose a multistep synthesis for each of the following transformations. For full credit, be sure to…

A: Note - Since the he given question is a multiple question , hence I solved first question according…

Q: Consider the molecular orbital model of cyclopentadienyl anion. In the ground state how many…

Q: A battery harnesses the power of a spontaneous electrochemical reaction by __________ the two half…

A: There are four options for the question .... A battery harnesses the power of a spontaneous…

Q: Draw the chemical structure. each the Following 2,2,4-TRIMethylpentane Cycloheptene For

Q: Given the structures of different phenols below, answer the following questions: OH OH OH ပုံ ပုံ…

Q: Which of the following could be added across carbon-carbon multiple bonds? I) H₂SO4 II) H₂ III) H₂O…

A: The organic molecules that consist of multiple bond between carbon atoms are called alkenes and…

Q: Which molecule has the most acidic proton? لا iioM OH ند C شد ه مید

A: The acidic proton means the proton that can be easily transfer or can be easily donated. The…

Q: Using the following guidelines, draw four constitutional isomers from this chemical formula: C6H8O.…

A: Double bond equivalent (DBE) = (C+1)-H/2 = (6+1)-8/2 = 7-4 = 3 All the four isomers are shown in…

Q: b) Bond view C3-C2 H3C ㅎ H CH3 eye view +

Q: Benzene Colto, ) was found to be totally unroactive toward addition Reactions. Based upon Resonance…

A: Here we have to explain why addition reaction of benzene is completely unreactive according to…

Q: F F CI F- -NH₂ O F YF F 'N guwolle FF Hs 10 min a

A: When Acid chloride react with primary or secondary amine then amide bond formation takes place. The…

Q: 4. (a) Chemical shift (8) value of CH and CH3 proton in [Al(acac);] are 1.99 and 5.47 ppm,…

Q: g. ´N´ CI

Q: 1. > Balance the following nuclear reactions and provide the missing "?" using appropriate notation.…

Q: Q1) Consider the following decomposition reaction is : C6H12O6 2C₂H5OH + 2CO2 Upon decomposition of…

Q: DATA Calculate Re values for each component Solvent Iron Copper Nickel Group 1 100 mm 90 mm 70 mm 30…

Q: Write equations for the OF Radioactive decay. a. d 230 emission by 924 b. B emission For the…

Q: II. Provide what is asked in the following: A. CI + H₂N- B. Product in A reacted with LiAlH4. C.…

A: In A , amide formation .In B reduction with LiAlH4. In C , N-dialkyl benzene sulfonamide formation.

Q: A lump of lithium phosphate, Li3PO4, was placed in 250.0 mL of pure water. The Ksp for the…

Q: 요

A: Since you have asked multiple type questions, we will solve only first questions for you. If you…

Q: НО H H OH НО НО ОН Н- H н D-glucose ОН ОН H H ОН D-gulose тон ОН sodium citrate (aq) Na2CO3 (aq)…

Q: Identify the important absorption peaks in the following IR spectra and describe the appearance of…

A: IR spectroscopy stands for Infra-red spectroscopy. It is represented as percentage of transmittance…

Q: Draw the major product of this reaction. Ignore inorganic byproducts. NBS Select to Draw

Q: I C E Determine the pH of a 0.095 mol/L HIO4 solution if the K₁₂ = 1.29 x 10-² + H₂O (l) HIO4 (aq)…

Q: If you could drop 12 atoms of copper into a beaker containing nitric acid, how many molecules of NO…

A: Copper, Cu(s) when added to dilute nitric acid, HNO3(aq) produces nitric oxide gas, NO(g).

Q: What is the volume of 60.0 g of ether if the density of ether is 0.70 g/mL?

Q: HO Provide a mechanism for the reaction below. Illustrate the role played by N,N,N- triethylamine in…

A: Trifluoroacyl chloride is highly electrophilic in nature. The aniline adds to the electrophilic…

Q: Q7) A solution of 0.05 M AgNO3 in a conductivity cell found to have a resistance of 75.8 2. By using…

Q: CHỊCH SNa LII,HO 1. LMANHy CH H. Pd

Question

Question 21

Using the acetoacetic ester synthesis, to produce 5-methyl-2-heptanone, the alkyl halide that should be used is:
ο ο οι
1-bromo-2-methylpentane
1-bromo-2-methylnonane
1-bromo-2-methylbutane
1-bromo-2-methyldecane
1-bromo-5-methylheptane

Expert Solution

This question has been solved!

Explore an expertly crafted, step-by-step solution for a thorough understanding of key concepts.

SEE SOLUTION Check out a sample Q&A here

Step 1

VIEW

Step 2

VIEW

Step by step

Solved in 2 steps with 2 images

SEE SOLUTION Check out a sample Q&A here

Knowledge Booster

Learn more about

Need a deep-dive on the concept behind this application? Look no further. Learn more about this topic, chemistry and related others by exploring similar questions and additional content below.

Similar questions

The following reactivity order has been found for the saponification of alkyl acetates by aqueous NaOH. Explain. CH3CO2CH3 > CH3CO2CH2CH3 > CH3CO2CH(CH3)2 > CH3CO2C(CH3)3
Nucleophilic aromatic substitution involves the formation of a resonance-stabilized carbanion intermediate called a Meisenheimer complex as the nucleophile attacks the ring carbon carrying the eventual leaving group; electron-withdrawing groups ortho and/or para to the site of attack help to stabilize this structure via resonance. For the reaction below, draw the structure of the stabilized reaction intermediate in the box below. CI F3C CF3 NO₂ F3C N CF3 NO₂ • You do not have to consider stereochemistry. • Draw the Meisenheimer complex with a formal charge of 0 on the nucleophilic atom. If more than one resonance structure is possible, only draw the most important one.
Which of the following compounds will undergo rearrangement during solvolysis reaction? 3-iodoheptane 3-iodo-2-methylheptane 3-iodo-3-methylheptane 3-iodo-5-methylheptane
1) LiAlH4; ) H3O+ will do which of the following reactions? 3-Phenyl-butanoic acid → 3-phenyl-butan-1-ol Benzene → cyclohexane Benzoic acid → benzaldehyde 2-Phenyl-hexanoic acid → benzoic acid and carbon dioxide 2,3-dimethyl-pent-1-yne → 2,3-dimethyl-pent-1-ene
Draw each reaction and their steps with preparation. 1) C6H5CH2COC6H5 from benzaldehyde as the only source of carbon. 2) CH3CH2COOCH2CH=CH2 from allyl alcohol as the only carbon source. 3) 1-Phenyl-1-butanone (butyrophenone) from butyraldehyde and benzene.
The following reaction involves two sequential Heck reactions. Draw structural formu- las for each organopalladium intermediate formed in the sequence and show how the final product is formed. Note from the molecular formula given under each structural formula that this conversion corresponds to a loss of H and I from the starting material. Acetonitrile, CH,CN, is the solvent. 1% mol Pd(OAc), 4% mol Ph,P CH,CN C4H171 C4H16
What, in general, is the order of decreasing reactivity of these carbonyl compounds towards nucleophilic reagents? H H CH3CCH3 CH3C=0 (CH 3)3CCCH3 HC=0 (CH3)3CCC(CH 3)3 I II III IV V O I> III > IV> I > V O v> III >I> I| > IV O I> IV > || > II > V O IV > || >1>III > V
Provide the reagents necessary to carry out the following conversion: 4-methyl-cyclohexanol -------> 4-methyl- cyclohexanone O KMNO4/NAOH/H20 peroxyacetic acid O Br2, CCl, O NazCr207/H2SO2/H2O O OsO4
single reaction sequence: a certain ketone undergoes alkylation to give new ketone, when reacted with a base and then an alkylating agent, 1-bromopropane. What is the structure of the final ketone product?
Complete the reaction scheme below. Show all reagents and intermediates. No reaction is a possible answer. 1) CH3CH2M9B CH3OH H+ (ехcess) но 2) H30*, H2O B A OCH3
Provide the mechanism for this reaction (include arrow pushing) ОН 2-lodobenzoic acid K2S2O8 H2SO4 ОН OSO3H ОН 양 diphenyliodonium-2-Carboxylate benzyne
Complete the reaction schemes below provinding the reagents required to achieve transformation. Note that more than one step may be required.