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- With the help of the two preceding problems, show that S between states 1 and 2 of nmoles an ideal gas is given by S=CnplnT2T1nRlnP2P1.A diatomic ideal gas is brought from an initial equilibrium state at p1=0.50 atm and T1=300K to a final stage with p2=0.20 atm and T1=500K. Use the results of the previous problem to determine the entropy change per mole of the gas.(a) A 5.0-kg rock at a temperature of 20 is dropped into a shallow lake also at 20 from a height of 1.0103 m. What is the resulting change in entropy of the universe? (b) If the temperature of the lock is 100 when it is dropped, what is the change of entropy of the universe? Assume that air friction is negligible (not a good assumption) and that c=860 J/kg K is the specific heat of the rock.
- A cylinder contains 500 g of helium at 120 atm and 20 . The valve is leaky, and all the gas slowly escapes isothermally into the atmosphere. Use the results of the preceding problem to determine the resulting change in entropy of the universe.Two moles of a monatomic ideal gas such as oxygen is compressed adiabatically and reversibly from a state (3 atm, 5 L) to a state with a pressure of 4 atm. (a) Find the volume and temperature of the final state. (b) Find the temperature of the initial state. (c) Find work done by the gas in the process. (d) Find the change in internal energy in the process. Assume Cv=5R and Cp=Cv+R for the diatomic ideal gas in the conditions given.(a) infinitesimal amount of heat is added reversibly to a system. By combining the first and second laws, show that dU=TdSdW. (b) When heat is added to an ideal gas, its temperature and volume change from T1 and V1 to T2 and V2 . Show that the entropy change of n moles of the gas is given by S=CnvlnT2T1nRlnV2V1 .
- One mole of an ideal monatomic gas is confined to a rigid container. When heat is added reversibly to die gas, its temperature changes from T1 to T2 . (a) How much heat is added? (b) What is the change in entropy of the gas?(a) A 5.0-kg rock at a temperature of 20 °C is dropped into a shallow lake also at 20 °C from a height of 1.0 × 103 m . What is the resulting change in entropy of the universe? (b) If the temperature of the rock is 100 °C when it is dropped, what is the change of entropy of the universe? Assume that air friction is negligible (not a good assumption) and that c = 860 J/kg · K is the specific heat of the rock.Problem 3: Consider an Einstein solid with N oscillators and total energy U = qe, in the limit N,q » 1 (with no assumptions made about the relative size of N and q). + N° (9 +N\9 a) Starting with this formula, find an expression for the entropy of an Einstein solid as a function of N and q. Explain why factors omitted from the formula have no effect on the entropy. b) Derive an expression for the temperature of the solid, as a function of N and q. Simplify your expression as a much as possible. c) Invert the result of part (c) to get the energy U as a function of temperature T. As always, simplify the final result as much as possible. d) Show that, in the high temperature limit (q » N), the heat capacity is C = Nkg. (Hint: when x is small, e* = 1+ x.) Is this the result you would expect? Explain. e) Plot energy U vs. temperature T using dimensionless variables, Cy/(Nkg) vs. t = kgT/e, for t in the range from 0 to 2. Discuss your prediction for the heat capacity at low temperature…
- The partition function of a hypothetical system is given by In Z = «TªV where a is a constant. Evaluate the mean energy E, the pressure P, and the entropy S.Write the mathematical relationships for each of the following Conclude the thermodynamic properties (parameters) of ideal gas same as ( energy , prussure, entropy , specific heat at fixed prussure , specific heat at fixed volume ) e 12:31 VDerive the change in the entropy due to pressure increase from p; to p; at constant T of a gas that obeys the following equation of state: nRT p= V-nb Compare the obtained expression to that of an ideal gas.