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- Which compound is the major product of the reaction sequence shown below? (1) РССIСH-CЬ H. H. OH (2) H,SO,(cat.) /H,0 (A) (B) H. HO (C) (D) Compound A Compound D Compound B OCompound C6 of 21 4. Sigmatropic Rearrangements For each reaction: symmetry Indicate which п molecular orbital is the HOMO and its Determine if the rearrangement would be suprafacial or antarafacial Draw an arrow pushing mechanism Draw the structure of the major product Describe the rearrangement e.g. [3,3] type type type type hv hy 6 closure closure closure closurePROBLEMS 5.1. Suggest a mechanism for the following transformation and say how you would test it. CI CI ArC ECH OC CH₂ CH PPh3 tBuOH/H₂O, N₂ PPh3
- Draw a stepwise mechanism for the following transformation: Part 1: Part 2 out of 3 Draw the mechanism that leads to the minor resonance contributor. OH OH view structure :ÖH Н30 H₂O H finish structure... OH H view structure H draw structure... HO™ H₂O H3O+ 0₂ XDraw the major organic product from the reaction sequence provided: Select Draw Rings More // Cl C 1. SOCI2 2. Et,CuLi 3. (a) LIAIH4 (b) H2O OHWhich compound is a major product of the reaction sequence shown below? MgBr OH (1) ether (2) H (dil./H,O (3) PCC/CH-Cl2 (A) (B) HO (C) (D) Compound C Compound D OCompound A OCompound B
- 8:00 Problem 29 of 40 conc. HBr SOS 63 ..... Draw the products of the two step reaction sequence shown below. Use a dash or wedge bond to indicate stereochemistry of substituents on asymmetric centers, Ignore inorganic byproducts. H₂O Done4. a. Provide the reagents necessary to produce the following products. vllatineupozows soubory (KOHO) olmin bohoq sizit nogrol s19vo or bisa ni bosgobydin modWS lo aimsbyd sch org lain di obrvorl attoo Tognori, rahat dest toi toubong famil b. One of these products forms preferentially at low temperature. Which one? Explain.Complete the following reaction sequence by drawing in the expected products. OH SOCI₂ 1.second equivalent of EtMgBr 2. H₂O QUESTION A4 Provide a detailed mechanism with curly arrows for the following reaction: 1. excess LiAlH4 B 2.H₂O OH CI 1 equivalent EtMgBr
- The major product of the following reaction sequence is: 1. B2H 2. H2O2, но a) b) ОН ОНChoose the best reagent(s) for carrying out the following reaction: A B 1. PhMgBr 2. H3O+ (D) C) NaBH4 Br. 1. CH3CH₂CH₂CH₂CH₂CH₂MgBr 2. H3O+ 1. CH3CH₂CH₂CH₂MgBr 2. H3O+ O Br OH :Which compound will be a major product of the reaction sequence shown? NO2 NO2 (1) HNO 3/H,SO,. 4 SO,H (2) H2SOJH0, A (3) SnCl,/HCl CI NO2 NH2 D SO2CI Compound D O Compound A O Compound C OCompound B C.
