What are the molar concentrations of acetic acid (CH3COOH) and sodium acetate (CH3COONa) in an aqueous solution buffered at a pH of 4.22 that has a freezing point of −2.87 °C? Assume complete dissociation of sodium acetate and a density of 1.02 g/mL for the solution. The p?a for CH3COOH is 4.75.

Introduction to General, Organic and Biochemistry
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Author:Frederick A. Bettelheim, William H. Brown, Mary K. Campbell, Shawn O. Farrell, Omar Torres
Publisher:Frederick A. Bettelheim, William H. Brown, Mary K. Campbell, Shawn O. Farrell, Omar Torres
Chapter8: Acids And Bases
Section: Chapter Questions
Problem 8.81P
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What are the molar concentrations of acetic acid (CH3COOH) and sodium acetate (CH3COONa) in an aqueous solution buffered at a pH of 4.22 that has a freezing point of −2.87 °C? Assume complete dissociation of sodium acetate and a density of 1.02 g/mL for the solution. The p?a for CH3COOH is 4.75.

What are the molar concentrations of acetic acid (CH, COOH) and sodium acetate (CH,COONA) in an aqueous solution
buffered at a pH of 4.22 that has a freezing point of -2.87 °C? Assume complete dissociation of sodium acetate and a density
of 1.02 g/mL for the solution. The pKa for CH, COOH is 4.75.
[CH, COOH] =
M
[CH, COONA] =
M
* TOOLS
х10
Transcribed Image Text:What are the molar concentrations of acetic acid (CH, COOH) and sodium acetate (CH,COONA) in an aqueous solution buffered at a pH of 4.22 that has a freezing point of -2.87 °C? Assume complete dissociation of sodium acetate and a density of 1.02 g/mL for the solution. The pKa for CH, COOH is 4.75. [CH, COOH] = M [CH, COONA] = M * TOOLS х10
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