What is the critical extent of reaction (pc) based on Carother's approach to gelation for the synthesis of a polyamide using equimolar amounts of diethylene triamine and the acid chloride of trimesic acid (see structures below; assume only the primary amines react). Some helpful equations: Carothers Equation: pc = 2/fav, where fav = (EN;fi) / ENi CI + H2N `NH2 CI

Organic Chemistry
8th Edition
ISBN:9781305580350
Author:William H. Brown, Brent L. Iverson, Eric Anslyn, Christopher S. Foote
Publisher:William H. Brown, Brent L. Iverson, Eric Anslyn, Christopher S. Foote
Chapter18: Functional Derivatives Of Carboxylic Acids
Section: Chapter Questions
Problem 18.69P
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What is the critical extent of reaction (pc) based on Carother's approach to gelation for the synthesis of
a polyamide using equimolar amounts of diethylene triamine and the acid chloride of trimesic acid (see
structures below; assume only the primary amines react).
Some helpful equations:
Carothers Equation: p. = 2/fav, where fav = (ENfi) /ENi
CI
H2N
`NH2
Transcribed Image Text:What is the critical extent of reaction (pc) based on Carother's approach to gelation for the synthesis of a polyamide using equimolar amounts of diethylene triamine and the acid chloride of trimesic acid (see structures below; assume only the primary amines react). Some helpful equations: Carothers Equation: p. = 2/fav, where fav = (ENfi) /ENi CI H2N `NH2
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