What will happen to the C=C bond of the ligand and oxidation state of the metal centre upon undergoing the cyclometallation reaction? C=C bond - oxidized ; oxidation state of metal centre -oxidizedO b. C=C bond - reduced ; oxidation state of metal centre -reducedC=C bond - oxidized ; oxidation state of metal centre -reducedO d. C=C bond - reduced ; oxidation state of metal centre -oxidized

This reaction is the oxidation reaction in organometallic compound.

Answered: What will happen to the C=C bond of the…

What will happen to the C=C bond of the ligand and oxidation state of the metal centre upon undergoing the cyclometallation reaction?

Chemistry: Principles and Reactions

8th Edition

ISBN:9781305079373

Author:William L. Masterton, Cecile N. Hurley

Publisher:William L. Masterton, Cecile N. Hurley

Chapter21: Chemistry Of The Nonmetals

Section: Chapter Questions

Problem 73QAP: The amount of sodium hypochlorite in a bleach solution can be determined by using a given volume of...

See similar textbooks

Related questions

Q: Draw the structures of the compounds given below. In every case, unambiguously r the complex…

Q: Using the 18-electron rule as a guide, indicate the probable number of carbonyl ligands in the…

A: The addition of all electrons exhibiting in d- as well as s-orbitals of metals and contributed by…

Q: (c) Design syntheses of (i) cis and (ii) trans isomers of [PtCl₂(CN)(NH3)], using K₂PtCl4, KCN and…

Q: What are all the possible hapticities for the interaction of each of the following ligands with a…

A: Hapticity is the property of a ligand to coordinate to a metal centre by a continuous series of…

Q: 1. "Are all the organometallic complexes stable to moisture and temperature?" Explain.

A: Since you have asked multiple question, we will solve the first question for you. If you want any…

Q: Draw the Lewis diagrams for each ligand. Indicate the lone pair(s) that may be donated to the metal.…

A: Lewis structures are the structures showing arrangement of valence electrons in an atom or a…

Q: 5) Consider the rhodium complex below. Reaction with 1 equivalent of oxygen gas oxidizes the metal…

A: Coordination complexes undergo different type of reactions which are oxidative addition reaction,…

Q: Use the 18-electron rule to predict the number of carbonyl ligands, n, in each of the following…

Q: It refers to addition of auxiliary ligand that potentially forms highly stable complexes with the…

Q: Which of the following classes of ligands has the strongest trans effect? а. A o-acceptor ligand b.…

A: The legand which contains π - bond and ,are π-acceptor have greatest trans effect.

Q: [Co(ONO)(NH3)5] Cl2 and [Co(NO2(NH3)5]Cl2 interpret the infrared spectroscopy spectrums of…

Q: Zinc on forms a 1:1 complex with a ligand called triethylenetetraamine. The formation constant for…

A: Given: Zinc forms 1 : 1 complex with a ligand called triethylenetetraamine (EDTA). Concentration of…

Q: 4. In transition metal complexes, ligands largely interact with metal center via lone pairs:…

A: Ethylenediamine intract metal with two lone pairs. Cl- Co and CN are monodentate ligand.

Q: Fe3+ (a hard metal) forms the n stable complex with which of tl Following bases: 1.

A: Hard metal forms stable complex with hard base.

Q: 7 How would you expect the molecule 1,10-phenanthroline (shown below) to function as a ligand? H H H…

A: A ligand is a ion or molecule which donates the loan pair of electrons to other to form a bond…

Q: Which of the following complexes may undergo b-H elimination O Al [(CH,Si(CH3)al2 (Et) O…

Q: Provide a name for the following complex ion:[Ni(H20)5Cl]^+

A: Naming an inorganic complexRules to followFirst name all the ligands in alphabetical order and then…

Q: Which of the following species could best act as a bidentate ligand for a metal ion? C2O42− N2H5+…

A: Bidentate ligand: A Lewis base which is capable of donating two lone pair of electrons to metal atom…

Q: How we calculate the charge of ligands in this complex? [Ir(C≡C-Ph)(PMe3)4]

A: Given complex is [Ir(C≡C-Ph)(PMe3)4] We have to find the charge on ligand

Q: Which of the following will form the most stable complex with Pt2+ cation * 2-2 Bipyridine…

A: The question is based on the concept of coordination chemistry. We have to identify which of the…

Q: What is the half wave potential (E1/2)s of the free Cd2+ metal ion in the absence of ammonia ligand…

A: The redox reaction under study is: Cd2++6 NH3↔Cd(NH3)62+ E0=0.16 V

Q: Which of the following compounds follow the effective atomic number rule, and which do not?(27Co,…

A: Effective atomic number rule is defined as the total number of electrons present around the central…

Q: Assuming the 18-electron rule applies for (n4-CsHe)Cr(CO)n, the number of carbonyl ligand (n) should…

A: Assuming 18 electron rule applies for (η4-C5H6)Cr(CO)n , the number of carbonyl ligand (n) should be…

Q: Which complex undergoes the slowest ligand exchange of ligands at room temperature A) [Fe(H2O)e]**…

Q: what will happen to the rate of a reaction of the crystal violet concentration triples

A: The second order graph of crystal violet hydroxylation is a plot of inverse of absorbance vs time…

Q: What is the nomenclature of the K2[Zn(NCS)4] complex according to the Stock system? Which one?

A: The formal oxidation state of the metal present in the complex is written after the metal name using…

Q: What will happen to the C=C bond of the ligand and oxidation state of the metal centre upon…

A: In organometallic chemistry, a metallacycle is a derivative of a carbocyclic compound wherein a…

Q: copper complex crystallises straightaway when synthesising but the cobalt complex required the…

A: Recrystallisation is dependents on solubility of the complex.

Q: Which of the following statements is TRUE? 1. Fe²+ form a 1:6 complex with 1,10-phenanthroline II.…

A: Statement 1 False. Fe2+ form a 1:3 complex with 1,10- phenanthroline. Statement 2 True. The iron…

Q: [Co(CN):(OH;)J* + [Co(NH3)s(NCS)}* = [Co(CN):(SCN)]* + [Co(OH,);F* 3. Explain why, in the products…

Q: Which ligand will be dissociated from the [RhCl(OX)(en)(PPH3)] octahedral complex during…

Q: Which of the following is not one of the characteristics of edtan? A. Stability in alkaline…

A: Introduction- Ethylenediaminetetraacetic acid (EDTA) is an aminopolycarboxylic acid with the formula…

Q: [Co(CN),(OH;)]* + [Co(NH3)s(NCS)* = [Co(CN):(SCN)]* + [Co(OH,);}** 3. Explain why, in the products…

Q: Depict and explain the Crystal field stabilization theory based on the color the below complexes.…

Q: SAIC Pr7.1 The compound Na,lrCl, reacts with triphenylphosphine in diethyleneglycol in an atmosphere…

A: Isomers are compounds with same molecular formula but different structural formula.…

Q: spectrum

A: Dear student I have given answer to your question in the image format.

Q: 10.What is the oxidation number for Cr in Cr2O72- Group of answer choices +2 +3 +5 +6 +7

Q: Hand- draw the structure of the complex below. Predict using the "18 Electron Rule" if the following…

Q: Which of the following is responsible for the chelate effect exhibited by multidentate ligands? Only…

A: The chemical reasons for the chelate effect involve relative enthalpy and entropy changes upon…

Q: With phosphine ligands, the more electron-donating the R group, the better the phosphine is as a Tt-…

A: Phosphine ligands are neutral ligands having one phosphorous atom and 3 substituents. The general…

Q: Identify complexes that can have low and high spin configurations and rationalize why they adopt a…

A: The presence of ligands breaks degenerate state of an orbital in transition metal complexes,…

Q: What is the relationship between the magnitude of ∆ and the energy of the d-d transition for a d1…

Q: In this complex, what is the chelating agent?

A: Chelating agent is the compound that reacts with metal ion to form a stable compound.

Q: Which of the following cations forms the most thermodynamically stable complex with EDTA? Cu2+…

A: A multiple choice question based on coordination complex, which is to be accomplished.

Q: How many bonds could each of the following chelating ligands form with a metal ion? (a)…

Q: The DOTA ligand is a cyclic octadentate ligand with four N- donors and four O-donors. * True O False

Q: 1. The Cp2Rh2[p-(CF3C=CCF3)](CO)(CNR) complex has a Rh-Rh bond distance of 2.67 Å, strongly…

A: In the given question we have to calculate the electron count of the given compound and to show it…

Q: 2. For each of the following complexes (A-C), determine the oxidation state of the metal and the…

Q: Using the ligands ethylenediamine (H2NCH2 CH2NH2) and bromide anions, design a cationic chiral…

A: Chiral complex is defined as the atom which has all the substituents different or it doesn't has any…

Q: Write out structure representations for all isomers of the following complexes: (b)…

A: The given question is from inorganic chemistry. It is from Coordination compounds. The main thing…

Concept explainers

Coordination Chemistry

It is a part of chemistry, in which the study of compounds that have central atoms surrounded by molecules or ions, known as ligand, is known as coordination chemistry.

Question

What will happen to the C=C bond of the ligand and oxidation state of the metal centre upon undergoing the cyclometallation reaction?

C=C bond - oxidized ; oxidation state of metal centre -
oxidized
O b. C=C bond - reduced ; oxidation state of metal centre -
reduced
C=C bond - oxidized ; oxidation state of metal centre -
reduced
O d. C=C bond - reduced ; oxidation state of metal centre -
oxidized

Expert Solution

This question has been solved!

Explore an expertly crafted, step-by-step solution for a thorough understanding of key concepts.

SEE SOLUTION Check out a sample Q&A here

Step 1

VIEW

Step 2

VIEW

Step 3

VIEW

Step by step

Solved in 3 steps with 1 images

SEE SOLUTION Check out a sample Q&A here

Knowledge Booster

Learn more about

Need a deep-dive on the concept behind this application? Look no further. Learn more about this topic, chemistry and related others by exploring similar questions and additional content below.

Similar questions

The amount of sodium hypochlorite in a bleach solution can be determined by using a given volume of bleach to oxidize excess iodide ion to iodine; ClO- is reduced to Cl-. The amount of iodine produced by the redox reaction is determined by titration with sodium thiosulfate, Na2S2O3; I2 is reduced to I-. The sodium thiosulfate is oxidized to sodium tetrathionate, Na2S4O6. In this analysis, potassium iodide was added in excess to 5.00 mL of bleach (d=1.00g/cm3) . If 25.00 mL of 0.0700 M Na2S2O3 was required to reduce all the iodine produced by the bleach back to iodide, what is the mass percent of NaClO in the bleach?
define catenation?
Explain Hydroboration–Oxidation reaction ?
estion 1'of 13 Write a balanced chemical equationffor the reaction of [Co(H,O),]²+ with Cl¯. Be sure to include phase symbols. balanced chemical equation:
10. What are the oxidation states of the elements present in S2O3-2?
ОН 1eq. tBuOOH, Ti(OiPr)4 (+)-DET
Fe2S3(s) Oxidation state of Fe :Oxidation state of S :HNO3Oxidation state of H :Oxidation state of N :Oxidation state of O : SOxidation state of S : NO2Oxidation state of N :Oxidation state of O : H2OOxidation state of H :Oxidation state of O :
the oxidation state of vanadium in VO+2 is
What is the oxidations state of S in S3O62-. Explain how this is possible.
11. Chlorine may be prepared in the laboratory from concentrated hydrochloric acid by heating it with A Concentrated H;SO4 B Manganese (IV) oxide C Sodium chloride crystals D Lead (II) oxide
empt35293518&cmid%3D581113&page3D3 One method of producing Cl2 is by reaction of HCI with MnO,. 6 HCI (aq) + 2 MnO4 (aq) - 2 MnO2 (aq) + 3 Cl2 (g) Determine the oxidation state for the indicated atom in each of the following species. NOTE: If the answer is a positive number do not put a plus sign. Only use the sign if the answer is a negative number. Mn in MnO4: Cl in HCI: Mn in MnO2: Cl in Cl2:
Explain Halogenation ?