why do amides boil at higher temperatures than hydrocarbons or ethers of similar molecular weights

Chemistry: The Molecular Science
5th Edition
ISBN:9781285199047
Author:John W. Moore, Conrad L. Stanitski
Publisher:John W. Moore, Conrad L. Stanitski
Chapter10: Fuels, Organic Chemicals, And Polymers
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why do amides boil at higher temperatures than hydrocarbons or ethers of similar molecular weights
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This answer explains why amides have higher boiling points than hydrocarbons or ethers of similar molecular weights. It starts by introducing the concept of intermolecular forces and specifically, hydrogen bonding. It then goes on to explain how the presence of a highly polar carbonyl group in amides allows for the formation of hydrogen bonds between neighboring amide molecules. Finally, it contrasts this with the nonpolar nature of hydrocarbons and ethers, which do not have the ability to form hydrogen bonds and therefore have weaker intermolecular forces and lower boiling points.

 

 

 

 

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