Answered: with the help of microwaves (yes,…

Chemistry

10th Edition

ISBN:9781305957404

Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste

Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste

Chapter1: Chemical Foundations

Section: Chapter Questions

Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...

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remember endo product is kinetically-controlled

Transcribed Image Text:Shown below is an example of another Diels-Alder reaction performed by James H. Cooley and Richard Vaughan Williams (J. Chem. Educ. 1997, 74, 5, 582) which results in two products. Although in this article the reaction shows relatively low selectivity between the between the thermodynamic and kinetic products, a recent publication by other authors show that this reaction can be performed in 10 minutes with the help of microwaves (yes, microwaves!) with great selectivity. Point out the kinetic and thermodynamic products. Explain your choices with the help of an energy profile diagram. Draw the transition state structure for each product. (Hint: The recent article cites Cooley and Williams work as a reference) 3. N-Ph N-Ph Ph

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