All methyl esters of long-chain aliphatic acids (e.g., methyl tetradecanoate, C13H27COOCH3) show significant fragment ions at m/z 74, 59, and 31. What are the structures of these ions? How are they formed?
All methyl esters of long-chain aliphatic acids (e.g., methyl tetradecanoate, C13H27COOCH3) show significant fragment ions at m/z 74, 59, and 31. What are the structures of these ions? How are they formed?
Organic Chemistry
8th Edition
ISBN:9781305580350
Author:William H. Brown, Brent L. Iverson, Eric Anslyn, Christopher S. Foote
Publisher:William H. Brown, Brent L. Iverson, Eric Anslyn, Christopher S. Foote
Chapter14: Mass Spectrometry
Section: Chapter Questions
Problem 14.37P
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All methyl esters of long-chain aliphatic acids (e.g., methyl tetradecanoate, C13H27COOCH3) show significant fragment ions at m/z 74, 59, and 31. What are the structures of these ions? How are they formed?
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