Organic Chemistry - Standalone book
10th Edition
ISBN: 9780073511214
Author: Francis A Carey Dr., Robert M. Giuliano
Publisher: McGraw-Hill Education
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Chapter 25.2, Problem 1P
What fatty acids are produced on hydrolysis of
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True/ False
Lipids are non-polar compounds and are soluble in water
Steroids and Prostaglandins are classes of compounds which are not saponifiable
Triglycerides are simple lipids and are made up of long chain fatty acids esterified with the trihydroxy groups of glycerol.
Waxes are esters of long chain fatty acids with long chain alcohols.
Sphingomyelins are a class of saponifiable complex lipids and are made up of sphingosine phosphate and amino alcohols.
How HCl converts the hemiacetal to an acetal called a glycoside ?
Draw the structure of a triacylglycerol formed from glycerol, one molecule of stearic acid, and two molecules of oleic acid. The stearic acid should form an ester bond with the 2° OH group of glycerol.
Chapter 25 Solutions
Organic Chemistry - Standalone book
Ch. 25.2 - What fatty acids are produced on hydrolysis of...Ch. 25.3 - Give the structure of the keto acyl-ACP formed...Ch. 25.4 - Prob. 3PCh. 25.4 - Prob. 4PCh. 25.5 - Prob. 5PCh. 25.6 - Write the structural formula and give the IUPAC...Ch. 25.6 - Prob. 7PCh. 25.7 - Locate the isoprene units in each of the...Ch. 25.7 - Prob. 9PCh. 25.9 - Prob. 10P
Ch. 25.9 - Prob. 11PCh. 25.10 - Prob. 12PCh. 25.11 - Prob. 13PCh. 25.11 - Prob. 14PCh. 25.12 - Prob. 15PCh. 25.16 - Prob. 16PCh. 25 - Prob. 17PCh. 25 - Prob. 18PCh. 25 - Prob. 19PCh. 25 - Pyrethrins are a group of naturally occurring...Ch. 25 - Prob. 21PCh. 25 - Prob. 22PCh. 25 - Prob. 23PCh. 25 - Prob. 24PCh. 25 - Prob. 25PCh. 25 - Prob. 26PCh. 25 - Prob. 27PCh. 25 - Prob. 28PCh. 25 - A synthesis of triacylglycerols has been described...Ch. 25 - Prob. 30PCh. 25 - Prob. 31PCh. 25 - Prob. 32PCh. 25 - Prob. 33DSPCh. 25 - Prob. 34DSPCh. 25 - Prob. 35DSPCh. 25 - Prob. 36DSPCh. 25 - Prob. 37DSPCh. 25 - Prob. 38DSP
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- Draw and label a strcture of: Cervonic acid 22:6 Δ4,7,10,13,16,19. This is a fatty acid found in cold fish.arrow_forwardV F2 # 3 E 80 F3 What is the difference between integral and peripheral proteins? $ 4 F4 R A) Integral proteins are required for the cell to function, while peripheral proteins are accessory. B) Integral proteins are found on the outside of the cell, while peripheral proteins are found on the inside of the cell. C) Integral proteins extend through the lipid bilayer, and peripheral proteins are just on the surface of the inside or outside of the cell. Question 11 of 19 D) Integral proteins are found on the inside of the cell, while peripheral proteins are found on the outside of the cell. E) Integral proteins are channel proteins and peripheral proteins act as enzymes. % 5 F5 T <6 MacBook Air F6 Y & 7 ♡ F7 U * 8 DII F8 1 ( - 9 F9 0 O F10arrow_forwardWaste cooking oil contains free fatty acids as well as triacylglycerols. Draw the chemical equation (with molecular structures) for the acid-catalysed esterification of octanoic acid with 1-propanol (Fischer esterification). Show the product(s) Draw the mechanism (with curly arrows) for the first step of this reactionarrow_forward
- For each of the triacylglycerol molecules in Problem 19-36, indicate how many of each of the following entities are present in the molecule. In certain cases, the answer may be zero.arrow_forwardIs safflower oil considered a triacylglycerol or fatty acid?arrow_forwardWhat is the composition of the soap prepared by hydrolysis of the following triacylglycerol?arrow_forward
- Waste cooking oil contains free fatty acids as well as triacylglycerols. Draw the chemical equation (with molecular structures) for the acid-catalysed esterification of octanoic acid with 1-propanol (Fischer esterification). Show the product(s).arrow_forwardWhich is a characteristic of the phospholipids in cell membranes? Select one: Phospholipids in a membrane interact with other membrane molecules, in part, through covalent forces Phospholipids are lipid molecules with a polar head and a non-polar tail, where the interaction of these components with other molecules of itself, results in membrane formation Increasing the proportion of protein in a membrane increases the amount of membrane symmetry Increasing the proportion of saturated fatty acids in a membrane increases membrane fluidity A phospholipid molecule glows in the dark after exposure to visible lightarrow_forward19-22 What is the relationship between degree of unsaturation and melting point for fatty acids? te associat locule?arrow_forward
- Hyaluronic acid acts as a lubricant in the synovial fluid of joints. In rheumatoid arthritis, inflammation breaks down hyaluronic acid to smaller molecules. Under these conditions, what happens to the lubricating power of the synovial fluid?arrow_forwardDraw the products formed when triacylglycerol A is treated with each reagent. Rank compounds A, B, and C in order of increasing melting point. a. H20, H* b. H2 (excess), Pd-C→ B c. H2 (1 equiv), Pd-C →C Aarrow_forwardDraw a phosphoglyceride formed by the reaction of glycerol, 1 molecule of myristic acid, 1 molecule of linoleic acid, 1 phosphate and 1 molecule of ethanolamine. The drawing should be in the form found at physiological pH. Use a line drawing for the fatty acids. Becarful with the geometry of the unsaturated fatty acid. Make sure you attach the ethanolamine via the correct atom.arrow_forward
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