Essential Organic Chemistry (3rd Edition)
3rd Edition
ISBN: 9780321937711
Author: Paula Yurkanis Bruice
Publisher: PEARSON
expand_more
expand_more
format_list_bulleted
Concept explainers
Videos
Textbook Question
Chapter 3.6, Problem 22P
Predict the approximate size of the following bond angles. (Hint: See Sections 1.11 and 1.12.)
- a. the C–O–C bond angle in an ether
- b. the C–N–C bond angle in a secondary
amine - c. the C–O–H bond angle in an alcohol
Expert Solution & Answer
Trending nowThis is a popular solution!
Students have asked these similar questions
What is the class of organic compound to which the molecule
belong?
A .
H3C
CH3
H3C
CH3
B.
H3C
CH3
С.
но
CH3
Zーエ
2. To the left, complete the Lewis diagram for a
simple amide described by the condensed
formula CH(O)NH2.
Use your Lewis diagram to fill in the table below:
H's
Electronic Geometry
Shape
C
O
N
What bond angles would you assign for this molecule? Hint there should be six different bond
angles or five different "types" of bond angles.
Consider an organic molecule with the molecular formula C13H10O.
a. Propose a chemically correct structure for this molecule that contains a ketone.
b. Propose a chemically correct structure for this molecule that contains a functional group other than a ketone
Chapter 3 Solutions
Essential Organic Chemistry (3rd Edition)
Ch. 3.1 - Name each of the following:Ch. 3.1 - Draw the structures and name the four...Ch. 3.1 - Draw the structure for each of the following...Ch. 3.1 - Name the following compounds:Ch. 3.1 - Prob. 7PCh. 3.2 - What is each compounds systematic name?Ch. 3.2 - Prob. 11PCh. 3.3 - Prob. 12PCh. 3.3 - Convert the following condensed structures into...Ch. 3.3 - The molecular formula for ethyl alcohol (CH3CH2OH)...
Ch. 3.3 - Draw a condensed and a skeletal structure for the...Ch. 3.3 - What is each compounds systematic name?Ch. 3.4 - Prob. 17PCh. 3.4 - Give two names for each of the following alkyl...Ch. 3.5 - Are the following compounds primary, secondary, or...Ch. 3.5 - Name the following amines and tell whether they...Ch. 3.5 - Draw the structures and provide systematic names...Ch. 3.6 - Predict the approximate size of the following bond...Ch. 3.7 - What is the smallest straight-chain alkane that is...Ch. 3.7 - Prob. 24PCh. 3.7 - Prob. 25PCh. 3.7 - Prob. 26PCh. 3.7 - List the compounds in each set from highest...Ch. 3.8 - Rank the following compounds in each set from most...Ch. 3.8 - In which solvent would cyclohexane have the lowest...Ch. 3.8 - Prob. 30PCh. 3.9 - Prob. 31PCh. 3.9 - a. Draw the three staggered conformations and the...Ch. 3.9 - a. Draw the most stable conformation of pentane...Ch. 3.11 - Draw 1,2,3,4,5,6-hexachlorocyclohexane with a. all...Ch. 3.12 - At any one time, would you expect there to be more...Ch. 3.13 - Prob. 36PCh. 3 - a. How many hydrogens does an alkane with 17...Ch. 3 - Prob. 2PCh. 3 - Draw a condensed structure and a skeletal...Ch. 3 - Prob. 39PCh. 3 - Prob. 40PCh. 3 - Which of the following represents a cis isomer?Ch. 3 - a. How many primary carbons does each of the...Ch. 3 - Name the following amines and tell whether they...Ch. 3 - Which of the following conformers of isobutyl...Ch. 3 - What is each compounds name? a. CH3CH2CH2OCH2CH3Ch. 3 - Draw the structural formula for an alkane that has...Ch. 3 - Which has a. the higher boiling point:...Ch. 3 - Ansaid and Motrin belong to the group of drugs...Ch. 3 - A student was given the structural formulas of...Ch. 3 - Which of the following conformers has the highest...Ch. 3 - Prob. 51PCh. 3 - Draw skeletal structures for the following: a....Ch. 3 - Prob. 53PCh. 3 - For rotation about the C-3 8 C-4 bond of...Ch. 3 - Prob. 55PCh. 3 - What is each compounds systematic name?Ch. 3 - Draw the two chair conformers for each of the...Ch. 3 - Draw the nine constitutional isomers with...Ch. 3 - Prob. 59PCh. 3 - Prob. 60PCh. 3 - Prob. 61PCh. 3 - Using Newman projections, draw the most stable...Ch. 3 - For each of the following disubstituted...Ch. 3 - Prob. 64PCh. 3 - Prob. 65PCh. 3 - What is each compounds systematic name?Ch. 3 - Prob. 67PCh. 3 - Bromine is a larger atom than chlorine, but the...Ch. 3 - Prob. 69PCh. 3 - Prob. 70PCh. 3 - a. Draw a potential energy diagram for rotation...
Additional Science Textbook Solutions
Find more solutions based on key concepts
Label each statement about the polynucleotide ATGGCG as true or false. The polynucleotide has six nucleotides. ...
General, Organic, & Biological Chemistry
The method to determine the volume of a powered solid, liquid and a rock needs to be determined. Concept introd...
Living by Chemistry
4. 38 Strontium has four naturally occurring isotopes, with mass numbers 84, 86, 87, arid 88.
a. Write the atom...
Basic Chemistry (5th Edition)
The active ingredient in Tylenol and a host of other over-the-counter pain relievers is acetaminophen (C8H9NO2)...
Chemistry: Atoms First
During the early part of the 20th century, sulfanilamide (an antibacterial drug) was only administered by injec...
Elementary Principles of Chemical Processes, Binder Ready Version
Knowledge Booster
Learn more about
Need a deep-dive on the concept behind this application? Look no further. Learn more about this topic, chemistry and related others by exploring similar questions and additional content below.Similar questions
- Consider the carbon skeleton shown below. To form a primary alcohol, the functional group can be bonded to which carbon atom(s)? -C C C-C 5 6 7 O a. 1, 2, or 7 O b. 2 or 6 O c. 4 O d. 3, 5, or 6 O e. any of them A Moving to another question will save this response. Question 6 c 28°C O G 1) EN ace 4.arrow_forward4. There are two isomers corresponding to the chemical formula C2H6O. One is an alcohol, and the other is an ether. (hint use the table of electronegativity) a. Draw each compound. b. Which compound would you expect to be more water soluble, and why? c. Which compound would you expect to have the higher boiling point, and why?arrow_forwardFunctional Group Classes Alcohol Amide Ester • CH₂CH₂OH * CHIO-CH, 7. H₂C1O Amine Ketone Circle each functional group(s) and identify the class to which each of the groups belongs. 9. H₂C Aldehyde Thiol Aromatics Carboxylic Acid 2. CH,SH 6. Alkenes 4. H₂NCH₂CH₂ 10. Ether NM₂ 11. Which of the functional groups in the top list must be on a terminalC in the carbon chain?arrow_forward
- 1. Substance X dissolves in Substance Y. Which of the following statements is true? a.Substances X and Y do not have a significantly large difference of polarities. b.Substance X has many hydroxyl substituents that can hydrogen bond with the n-alkane Substance X. c.Substance Y is non-polar and is able to dissolve the polar Substance X. d.Substance Y is polar and is capable of dipole-dipole interaction with the nonpolar Substance X. 2. Substances A,B,C,D, and E are mixed together. Substances B and E form into a separate immiscible layer above the solution. Which of the following statements is true? a.B and E are non-polar. They can hydrogen bonds with each other in order to separate from the polar A,C, and D b.B and E have similar polarities with A, C, and D. c.B and E are non-polar. A,C and D are polar. d.B and A are polar. It follows the like dissolves like rule.arrow_forward1. The following molecule contains the functional groups A. secondary amine, secondary alcohol, ketone, carboxylic ester B. amide, primary alcohol, aldehyde, carboxylic acid C. secondary amine, two secondary alcohols, and two ketones D. primary amine, secondary alcohol, ketone, and carboxylic acid The following molecule contains the functional groups 2. A. primary alcohol and primary amine C. secondary alcohol and primary amine 3. A. alkene and secondary alcohol C. ketone and seconary alcohol The following molecule contains the functional groups B. ether and ketone D. ether and alkene 4. The following molecule A. primary amine and ketone C. secondary amine and alkyne NH₂ contains the functional groups B. secondary amine and alkene D. secondary amine and ketone ОН OH B. secondary alcohol and secondary amine D. primary alcohol and secondary amine NH₂ OHarrow_forward7. The molecule pictured to the right has which functional group? A. aldehyde B. alcohol C. carboxylic acid HO D. esterarrow_forward
- A. Identify the name of the functional group where the given organic compounds belong (alcohol, ether, aldehyde, ketone, carboxylic acid, ester, amine) 1. H H Br H H -C C-H H H H 2. H H Н—с H -5- H H N- H- 3. H H -нн I-arrow_forward12. Which bonding pattern is NOT typical of carbon atoms in organic compounds? A. B. C. D. E. 13. Which compound is classified as ether? A. CH3 -0- CH₁ B. C. D. CH3 O-H CH3-CH2-0-H CH3-CH2-0-CH3 E. CH–CH,NH,arrow_forwardWhat is the class of organic compound to which the molecule belong? A. но CH3 B. CH3 H3C CH3 . I. H3C CH3 D. H3C CH3arrow_forward
- 2. Some students confuse the ester and ether functional groups. Both linkages are formed by condensation reactions. a) Complete this statement: An ether linkage is formed by the condensation of: b) Use structures to show the condensation of cyclohexanol molecules to create the alternate synthesis product discussed in the report sheet of your Dehydration experiment (Lab 04).arrow_forwardIdentify the circled functional group(s) for each molecule. OH CH3CHCH3 a. ΙΟ ——CH2 b. NH2CH2CH2CH2NHCH3 C. H₂N d. 0 Circle and name all functional group(s) for each molecule CH3 HO OH SH CH2CHCH NHCH(CH3)2 OHarrow_forwardWhich functional group is not present in the following compound? 'NH O A. ether B. ketone O C. ester O D. amidearrow_forward
arrow_back_ios
SEE MORE QUESTIONS
arrow_forward_ios
Recommended textbooks for you
Chemistry: An Atoms First ApproachChemistryISBN:9781305079243Author:Steven S. Zumdahl, Susan A. ZumdahlPublisher:Cengage Learning
ChemistryChemistryISBN:9781305957404Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCostePublisher:Cengage Learning
Chemistry: An Atoms First Approach
Chemistry
ISBN:9781305079243
Author:Steven S. Zumdahl, Susan A. Zumdahl
Publisher:Cengage Learning
Chemistry
Chemistry
ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Cengage Learning
Alcohols, Ethers, and Epoxides: Crash Course Organic Chemistry #24; Author: Crash Course;https://www.youtube.com/watch?v=j04zMFwDeDU;License: Standard YouTube License, CC-BY