Fundamentals Of Analytical Chemistry
9th Edition
ISBN: 9781285640686
Author: Skoog
Publisher: Cengage
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- 4-102 Aspartame, an artificial sweetener used as a sugar substitute in some foods and beverages, has the molecular formula C14H18N2O5. (a) How many mg of aspartame are present in 3.72 × 1026 molecules of aspartame? (b) Imagine you obtain 25.0 mL of aspartame, which is known to have a density of 1.35 g/mL. How many molecules of aspartame are present in this volume? (c) How many hydrogen atoms are present in 1.00 mg of aspartame? (d) Complete the skeletal structure of aspartame, where all the bonded atoms are shown but double bonds, triple bonds, and/or lone pairs are missing. (e) Identify the various types of geometries present in each central atom of aspartame using VSEPR theory. (f) Determine the various relative bond angles associated with each central atom of aspartame using VSEPR theory. (g) What is the most polar bond in aspartame? (h) Would you predict aspartame to be polar or nonpolar? (i) Is aspartame expected to possess resonance? Explain why or why not. (j) Consider the combustion of aspartame, which results in formation of NO2(g) as well as other expected products. Write a balanced chemical equation for this reaction. (k) Calculate the weight of C02(g) that can be prepared from 1.62 g of aspartame mixed with 2.11 g of oxygen gas.arrow_forwardYou take 1.00 g of an aspirin tablet (a compound consisting solely of carbon, hydrogen, and oxygen), burn it in air, and collect 2.20 g CO2 and 0.400 g H2O. You know that the molar mass of aspirin is between 170 and 190 g/mol. Reacting 1 mole of salicylic acid with I mole of acetic anhydride (C4H6O3) gives you 1 mole of aspirin and 1 mole of acetic acid (C2H4O2). Use this information to determine the molecular formula of salicylic acid.arrow_forwardHow many grams of beryllium (Be) are needed to react completely with 45.0 g of nitrogen (N2) in the synthesisof Be3N2?arrow_forward
- 3.113 MgCl2 is often found as an impurity in table salt (NaCl). If a 0.05200-g sample of table salt is found to contain 61.10% Cl by mass, describe how you could determine the percentage of MgCl2 in the sample.arrow_forwardPhosphoric acid, H3PO4, can be prepared by the reaction of phosphorus(V) oxide, P4O10, with water. 14P4O10(s)+32H2O(l)H3PO4(aq);H=96.2kJ What is H for the reaction involving 1 mol of P4O10? P4O10(s)+6H2O(l)4H3PO4(aq)arrow_forward4.69 The pictures below show a molecular-scale view of a chemical reaction between H2 and CO to produce methanol, CH3OH. The box on the left represents the reactants at the instant of mixing, and the box on the right shows what is left once the reaction has gone to completion. Was there a limiting reactant in this reaction? If so, what was it? Write a balanced chemical equation for this reaction. As usual, your equation should use the smallest possible whole number coefficients for all substances.arrow_forward
- A mixture of Fe2O3, and FeO was found to contain 72.00% Fe by mass. What is the mass of Fe2O3 in 0.750 g of this mixture?arrow_forwardThe active ingredient in some antiperspirants is aluminum chlorohydrate, Al2(OH)5Cl. Analysis of a 2.000-g sample of antiperspirant yields 0.334 g of aluminum. What percent (by mass) of aluminum chlorohydrate is present in the antiperspirant? (Assume that there are no other compounds containing aluminum in the antiperspirant.)arrow_forward3.117 For the oxides of iron, FeO, Fe2O3, and Fe3O4, describe how you would determine which has the greatest percentage by mass of oxygen. Would you need to look up any information to solve this problem?arrow_forward
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