Organic Chemistry - Standalone book
10th Edition
ISBN: 9780073511214
Author: Francis A Carey Dr., Robert M. Giuliano
Publisher: McGraw-Hill Education
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Chapter 7.9, Problem 16P
Identify the
a)
b)
c)
d)
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Give the structure corresponding to each IUPAC name:
a) 3-methyl-3-pentanol
b) 4-methyl -2-pentanol
c) 2,4 dimethyl -2-hexanol
d) 1,3-propanediol
e) 3,5-dimethylcyclohexanol
f) 6,6-diethyl-4-nonanol
Write the chemical equation showing reactants, products and catalysts needed (if any) for thefollowing reactions. Write the IUPAC name of the product right beside the structure.
a) Reaction of two phenol
b) Reaction of 2-bromophenol with sodium hydroxide
c) Reaction of potassium phenoxide with 2-chloropentane
d) Reaction of isopropyl propyl ether with HBr
e) Reaction of 3-methylpentan-3-ol with sulfuric acid
f) Dehydration of 1,5-hepta-diolg) Oxidation of 1-decanolh) Hydration od hepta-2,3-diene
Name the alkene obtained on dehydration of each of the following alcohols:
a) 1-propanol
b) 2-propanol
c) 2-methyl-2-propanol
d) 2,3,3-trimethyl-2-butanol
Chapter 7 Solutions
Organic Chemistry - Standalone book
Ch. 7.1 - Name each of the following using IUPAC...Ch. 7.1 - Prob. 2PCh. 7.2 - How many carbon atoms are sp2-hybridized in the...Ch. 7.3 - Prob. 4PCh. 7.3 - Are cis-2-hexene and trans-3-hexene stereoisomers?...Ch. 7.4 - Prob. 6PCh. 7.4 - Prob. 7PCh. 7.4 - Give the IUPAC name of each of the compounds in...Ch. 7.5 - Arrange the following in order of increasing...Ch. 7.6 - Prob. 10P
Ch. 7.6 - Standard enthalpies of formation are known for all...Ch. 7.6 - Prob. 12PCh. 7.6 - Despite numerous attempts, the alkene...Ch. 7.6 - Write structural formulas for the six isomeric...Ch. 7.7 - Place a double bond in the carbon skeleton shown...Ch. 7.9 - Identify the alkene obtained on dehydration of...Ch. 7.10 - Prob. 17PCh. 7.11 - Prob. 18PCh. 7.12 - Prob. 19PCh. 7.13 - The alkene mixture obtained on dehydration of...Ch. 7.14 - Write the structures of all the alkenes that can...Ch. 7.14 - Write structural formulas for all the alkenes that...Ch. 7.15 - A study of the hydrolysis behavior of...Ch. 7.15 - Use curved arrows to illustrate the electron flow...Ch. 7.15 - Predict the major product of the reaction shown.Ch. 7.16 - Prob. 26PCh. 7.17 - Prob. 27PCh. 7.18 - Prob. 28PCh. 7.19 - Predict the major organic product of each of the...Ch. 7.19 - A standard method for the synthesis of ethers is...Ch. 7 - Write structural formulas for each of the...Ch. 7 - Prob. 32PCh. 7 - Give an IUPAC name for each of the following...Ch. 7 - A hydrocarbon isolated from fish oil and from...Ch. 7 - Prob. 35PCh. 7 - Prob. 36PCh. 7 - Prob. 37PCh. 7 - Prob. 38PCh. 7 - Choose the more stable alkene in each of the...Ch. 7 - Suggest an explanation for the fact that...Ch. 7 - Prob. 41PCh. 7 - Write structural formulas for all the alkene...Ch. 7 - Prob. 43PCh. 7 - Prob. 44PCh. 7 - Predict the major organic product of each of the...Ch. 7 - Prob. 46PCh. 7 - Prob. 47PCh. 7 - The rate of the reaction In the first order in...Ch. 7 - Prob. 49PCh. 7 - Prob. 50PCh. 7 - You have available 2,2-dimethylcyclopentanol (A)...Ch. 7 - Prob. 52PCh. 7 - Prob. 53PCh. 7 - Prob. 54PCh. 7 - Acid-catalyzed dehydration of...Ch. 7 - The ratio of elimination to substitution is...Ch. 7 - Prob. 57PCh. 7 - Prob. 58DSPCh. 7 - Prob. 59DSPCh. 7 - Prob. 60DSPCh. 7 - Prob. 61DSPCh. 7 - A Mechanistic Preview of Addition Reactions The...Ch. 7 - Prob. 63DSPCh. 7 - Prob. 64DSPCh. 7 - Prob. 65DSP
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- Identify the IUPAC name of the given compound. a) 1-propylbenzophenone b) 1-phenyl-1-propanone c) 1-propylphenylketone d) 1-phenylpropyl ketonearrow_forward7) Write the IUPAC/common name of the following compounds: A) HCOO-Li B) CH3CH₂CH₂COO NH4+ 8) Write the condensed structural formulas and IUPAC names of the two compounds from which: CH3CH₂CH₂CH2CH2CONHCH₂CH₂CH3 is formed. 9) Draw the structure for each compound. A) Propyl hexanoate B) Methyl benzoate C) Phenyl benzoate D) Ethyl 3-methyl hexanoatearrow_forward③/ Draw the alkene products of the dehydration of the following alcohols: a) 2- Butanol b) - Butanol c) 2- Propanol d) 4-Bromo-2-hexanolarrow_forward
- Draw the structures of the chief product formed when the following alcohols are dehydrated to alkenes: a. b.arrow_forwardDraw structures for the four constitutional isomers of molecular formula C4H10O that contain an OH group. Give the IUPAC name for each alcohol.arrow_forwardWhich of the following is a secondary alcohol? a) 2-methyl-2-propanol b) trans-2-methylcyclohexanol c) 2,2-dimethyl-1-propanol d) 3-methylbutanolarrow_forward
- What is the function of acid in the dehydration reaction of alcohols?arrow_forwardThe IUPAC name for the following compound is: CH3-CH2-CH a) acetaldehyde b) 1-ethanal Od propanal O d) propionaldehydearrow_forwardDraw the structures of the following aldehydes / ketones: 1.) 3-chloro-3-methylhexanal 2.) 3,4-diethyl-3-methylhexan-2-one 3.) 5-bromo-3-methyheptanalarrow_forward
- 2-methylhexanoic acid can be synthesized by oxidation of which of the following compounds? A) 2-methylhexane B) 2-methyl-1-hexanol C) 2-methyl-1-hexene D) 2-methyl-1-hexyne E) 2-methyl-2-hexanonearrow_forward47) What is the common name of this compound? n CH3-C-O-CH3 A) ethyl methyl ester B) diethyl ester C) ethyl methanoate D) 2-ether-2-butanone E) ethyl acetatearrow_forwardDraw the condensed structural formula of the following compounds: acid a) 2-Bromo-3-chloro-4-methylhexanoic b) 4-Hydroxycyclohexanecarboxylic acid c) y-Chlorocaprylic acid d) 2,4,6-Tribromobenzoic acid e) 3-Phenylhexanoic acidarrow_forward
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