A student wishes to determine the chloride ion concentration in a water sample at 25 °C using a galvanic cell constructed with a graphite electrode and a half-cell of AgCl(s) + e⁻ → Ag(s) + Cl⁻(aq) E°red = 0.2223 V And a copper electrode with 0.500 M Cu²⁺ as the second half cell Cu²⁺(aq) + 2 e⁻ → Cu(s) E°red= 0.337 V The measured cell potential when the water sample was placed into the silver side of the cell was 0.0925 V. Given the standard cell potential for this cell is 0.115 V, and the measured cell potential is 0.0925, what is the concentration of chloride ions in the solution? N

Chemistry: Principles and Practice
3rd Edition
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Author:Daniel L. Reger, Scott R. Goode, David W. Ball, Edward Mercer
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Chapter18: Electrochemistry
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Problem 18.103QE
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A student wishes to determine the chloride ion concentration in a water sample at 25 °C using a galvanic cell constructed with a graphite electrode and a half-cell of AgCl(s) + e⁻ → Ag(s) + Cl⁻(aq) E°red = 0.2223 V And a copper electrode with 0.500 M Cu²⁺ as the second half cell Cu²⁺(aq) + 2 e⁻ → Cu(s) E°red= 0.337 V The measured cell potential when the water sample was placed into the silver side of the cell was 0.0925 V. Given the standard cell potential for this cell is 0.115 V, and the measured cell potential is 0.0925, what is the concentration of chloride ions in the solution?

N

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