A. How many monosaccharide units are there? B. What is the specific glycosidic linkage labelled as LINK B? C. Is TAMIS a non-reducing sugar?
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- Based on the structure of sucrose below, is it classified as a reducing sugar? ОН 6CH OH 5 5 ОН 3 6CH OH a-Glucose 2 ОН 0. ОН HO 3 1 ОН ОН 2 CH₂OH 1 B-Fructose ОН CH₂OH ОН CH₂OH ОН OH НО a, B (1-2) linkage CH₂OH Sucrose + H2O8) Consider the tetrasaccharide stachyose drawn below. Stachyose is found in white jasmine, soybeans, and lentils. Because humans cannot digest it, its consumption causes flatulence. HO How ОН OH stachyose OH HO HO OH HO OH OH OH OH «ОН a. Label all glycoside bonds. b. Classify each glycosidic linkage as a or ẞ and use numbers to designate its location between two rings (e.g., 1-4-3). c. What products are formed when stachyose is hydrolyzed with H,O"? d. Is stachyose a reducing sugar? e. What product is formed when stachyose is treated with excess CHI, Ag₂O? f. What products are formed when the product in (e) is treated with H₂O"?Which of the following statements is correct regarding the structures below? CHO CHO CHO -Н НО H НО н- ОН -Н - ОН CH2OH CAB All are structures of D-sugars. All are structures of ketohexoses. Only CAR is a monosaccharide. O Only CAP is a L-sugar. -ОН -ОН H-OH H-OH H- ОН CH₂OH CAR но-н H-OH н НО т н-он CH₂OH CAP CH₂OH Fo НО-Н H НО-Н H он CH₂OH CAT
- Match the following nucleobases (designated AD) with their names and answer questions about them. NH, NH, C D NH2 Note that some of the items from the answer list should NOT be used. Guanine 1. Aand B - Cytosine 2 Cand D • Adenine 3. Not shuwn v Thymine 4. D v Uracil 5. B a Aand C v Which of tho shown bases are pyrimidines? 7. A and O v Which of the shown bases form canonical A-T Watson-Crick base pair? S. A v Which of the shown bases form canonical G-C Watson.Crick base-pair? 9. Band C 10. C 11. Band DConsider the ff dissacharides.a. Classify the glycosidic linkage as α or β and use numbers to designate its location (e.g. β1→3) b. What monosaccharides are formed when each of the disaccharides is hydrolyzed? c. Draw the chair conformation of each monosaccharide, where applicable.From the following monosaccharides, identify the a anomers. Select all that apply. Select one or more: OH он OH OH O a. OH OH HO но- Ob. ÓH H OH HO но- он H OH O c. HO OH ÓH ÓH d.
- a. Is the disaccharide below a non-reducing sugar? yes or no b. The glycosidic linkage in the disaccharide is what β-(1-2) linkage, α-(1-2) linkage, β-(1-4) linkage, or α-(1-4) linkage? c. The products of hydrolysis of the disaccharide (which of the ff.) α-galactose and α-ribose α-glucose and α-fructose α-fructose and α-galactose α-glucose and α-galactoseConsider the positively charged amino acid lysine Lys2+ 21 COOH I H&N-C-H I pH 14 12 10 8 6 4 2 0 CH₂ I CH₂ I CH₂ I CH₂ T NH₂+ 0 Nelson p85 2.18 = 2.18 PK₁ Lys+ COO™ I H₂N-C-H H₂N-C-H ī I -----) 8.95 Lysº 8.95 pK₂ pka carboxyl = 2.19 pkaamino = 9.67 pka sidechain = 4.25 COO™ I CH₂ I CH₂ I CH₂ I CH₂ I NH₂¹ 1.0 2.0 Equivalents of OH added- COO™ I H₂N-C-H I 10.79 1 10.79 pk Isoelectric point Lys CH₂2 I CH₂ I CH₂ I CH₂ T NH₂ 3.0 +H3N NH3+ T CH₂ T CH₂ CH₂ CH₂ -COO™ H Lysine (Lys, K) Physiological pH = 7.4 < pl → Amino acid is positively charged at physiological pH 1. Consider glutamate in its fully protonated form (e.g. in a pH = 1 solution) 1) Draw all the forms of glutamate at various pH 2) Calculate the pl of this amino acid 3) Sketch a titration curve showing pH as a function of added [OH-] and locate the predominant forms of histidine in the curve STEPS: 1. Find the H atoms that can be removed on the molecule 2. Associated a pka value to each removable H. 3. Draw the Aa structure at:…In the structure in the picture, the monosaccharide units (alpha-D-galactopyranosyl and beta-D-allopyranose) are linked via alpha-1->3 glycosidic bond. Then, the formed disaccharide units are linked via beta-1->4 glycosidic bond. Then, an Oligosaccharide is formed which has 10 monosaccharide units, meaning that it contains 5 disaccharide units. Question: Is this oligosaccharide a good substrate for glycolysis? Provide two reasons for your answer.
- Help me1) Please list all glycosidic linkages between each monosaccharide units. For example, α(1→4)2) Please discuss whether these oligo/polysaccharides would be reducing or non-reducing sugar. Remember to state your reasoning in complete sentence.Draw the Fischer, Haworth & chair representations of the given monosaccharides. Sugar Fischer Haworth Chair a CHO Но H. H OH H. OH. CH,OH D-idose (a-anomer) b. CH,OH C=0 Он OH CH,OH D-ribulose (B-anomer)