Alkane nalogenation is a two-step reaction, as shown in the image. Using the table of bona dissociation energies, calculate the enthalpy of each step and the enthalpy of the overall reaction. Bond Dissociation Energies (for A-BA+ • B) Bond broken AH (kJ/mol) Bond broken AH (kJ/mol) Bond broken AH (kJ/mol) H-H 436 413 432 355 243 Step 1 H T CH3CHCH3 + CI: Step 2 CH3CHCH3 + Cl₂ Overall reaction H I CH3CHCH3 + Cl₂ (CH3)₂CH-H (CH3)₂CH-CI CH3CHCH3 + HCI CI CH3CHCH3 + .CI: CI CH.CHCH. + HCI H-Cl Cl-Cl AH = AH = AH = kJ/mol kJ/mol kJ/mol

Chemistry: The Molecular Science
5th Edition
ISBN:9781285199047
Author:John W. Moore, Conrad L. Stanitski
Publisher:John W. Moore, Conrad L. Stanitski
Chapter10: Fuels, Organic Chemicals, And Polymers
Section: Chapter Questions
Problem 121QRT
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Aikane nalogenation is a two-step reaction, as shown in the image. Using the table of bona dissociation energies, calculate the
enthalpy of each step and the enthalpy of the overall reaction.
Bond Dissociation Energies (for A-B
A. +. B)
Bond broken AH (kJ/mol) Bond broken AH (kJ/mol) Bond broken AĦ (kJ/mol)
H-H
436
413
432
355
243
Step 1
H
CH3CHCH3 + CI:
Step 2
CH3CHCH3 + Cl₂
Overall reaction
CH₂ CHCH₂
CH3CHCH3 + Cl₂
(CH₂)₂CH-H
(CH₂)₂CH-CI
CH3CHCH3 + HCI
CI
CH3CHCH3 +
.CI:
CI
CH.CHCH. + HOL
H-Cl
CI-CI
ΔΗ =
AH =
ΔΗ =
kJ/mol
kJ/mol
kJ/mol
Transcribed Image Text:Aikane nalogenation is a two-step reaction, as shown in the image. Using the table of bona dissociation energies, calculate the enthalpy of each step and the enthalpy of the overall reaction. Bond Dissociation Energies (for A-B A. +. B) Bond broken AH (kJ/mol) Bond broken AH (kJ/mol) Bond broken AĦ (kJ/mol) H-H 436 413 432 355 243 Step 1 H CH3CHCH3 + CI: Step 2 CH3CHCH3 + Cl₂ Overall reaction CH₂ CHCH₂ CH3CHCH3 + Cl₂ (CH₂)₂CH-H (CH₂)₂CH-CI CH3CHCH3 + HCI CI CH3CHCH3 + .CI: CI CH.CHCH. + HOL H-Cl CI-CI ΔΗ = AH = ΔΗ = kJ/mol kJ/mol kJ/mol
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