Ascorbic acid, H₂C6H6O6, is a diprotic acid usually known as vitamin C. For this acid, pk1 is 4.10 and pKa2 is 11.79. When 125 mL of a solution of ascorbic acid was evaporated to dryness, the residue of pure ascorbic acid had a mass of 3.30 g. Calculate the molar concentration of ascorbic acid in the solution before it was evaporated. i What was the pH of the ascorbic acid solution before it was evaporated? pH = i What was the concentration of the ascorbate ion, C6H6062, before the solution was evaporated? i M M
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- The ethyl acetate concentration in an alcoholic solution was determined by diluting a 10.00-mL sample to 100.00 mL. A 19.00-mL portion of the diluted solution was refluxed with 40.00 mL of 0.04601 M KOH: CH3 СОО С2H; + ОН — СH3 COO + C2H; ОН After cooling, the excess OH was back-titrated with 3.02 mL of 0.05056 M H2 SO4. Calculate the amount of ethyl acetate (88.11 g/mol) in the original sample in grams. Amount of ethyl acetate =Chemists working with fluorine and its compounds some- times find it helpful to think in terms of acid-base reac- tions in which the fluoride ion (F¯) is donated and ассеpted. (a) Would the acid in this system be the fluoride donor or fluoride acceptor? (b) Identify the acid and base in each of these reactions: CIF;O2 + BF; CIF,O, · BF, -- TiF, + 2 KF – K2[TiF,]We want to determine the acetylsalicyclic acid content of a series of aspirin tablets by titration with NaOH(aq). Each of the tablets is expected to contain about 0.32 g of HC9H7O4. What molarity of NaOH(aq) should we use for titration volumes of about 23 mL? HC9H7O4(aq) + OH-(aq) C9H7O4-(aq) + H2O(l)
- (b) Sodium hydroxide reacts with propanoic acid in the following equation: NaOH + CH3CH,COOHCH3CH2COONA + HLO A buffer solution is formed when sodium hydroxide is added to an excess of aqueous propanoic acid. (i) Calculate the number of moles of propanoic acid in 50.0 cm of 0.125 mol dm aqueous propanoic acid. (ii) Use your answers to part (b)(i) to calculate the number of moles of propanoic acid in the buffer solution when 2.00 cm' of 0.500 mol dm aqueous sodium -3 hydroxide are added to 50.0 cm' of 0.125 mol dm aqueous propanoic acid. ) Hence calculate the pH of this buffer solution at 298.15 K.Calcium oxalate is a sparingly soluble ionic compound composed of calcium ions (Ca2+) and oxalate ions (C2O42–). It is a main culprit in kidney stone disease due to the formation of calcium oxalate crystals in the urine. A typical value for the concentration of calcium in urine is 0.3 grams per liter. Given a Ksp value for calcium oxalate of 1.3 × 10–8, calculate the minimum concentration of oxalate ion in urine that could lead to precipitation of calcium oxalate.A 0.2088 g sample of primary-standard-grade sodium carbonate, Na₂CO₃ (105.99 g/mol) was dissolved in water and diluted to 100.00 mL in a volumetric flask. A 30.00-mL portion of this solution was used to standardize a hydrochloric acid (HCl) solution based on the following reaction: CO₃²⁻ + 2H⁺ → H₂O + CO₂. If 36.09 mL of the HCl solution was used to reach the end point, what is the molarity of the HCl?
- When butanoic acid (C3H7COOH) reacts with the strong base potassium hydroxide (KOH), potassium butanoate (C3H7COOK), a salt of the weak acid is formed. Write a balanced chemical equation with physical states to show the dissociation of the potassium butanoate (C3H7COOK).Phosphoric acid, H3PO4 (aq), is found in soda. Write the balanced chemical equation for the neutralization of phosphoric acid with NaOH.True or false? A) Calcium acetate and sodium carbonate is Ca2+(aq) + 2C2H3O2-(aq) ----> Ca(C2H3O2)2(s) B) Magnesium chloride and sodium hydroxide is Mg2+(aq) + 2OH-(aq) ----> Mg(OH)2(s) C) Sodium phosphate and potassium nitrate, no reaction occurs. D) Ammonium sulfate and barium nitrate is Ba2+(aq) + SO42-(aq) ----> BaSO4(s)
- Limestone consists mainly of the mineral calcite, CaCO3. The carbonate content of 0.5413 g of powdered limestone was measured by suspending the powder in water, adding 10.00 mL of 1.396 M HCl, and heating to dissolve the solid and expel CO2: CaCO3(s, 100.087 g/mol) + 2 H+ → Ca2+ + CO2(g) + H2O The excess acid required 39.96 mL of 0.1004 M NaOH for complete titration to a phenolphthalein end point. Find the weight percent of calcite in the limestone.You are working in a forensic lab and are given a blood sample from a suspected drunk driver and asked to determine the person's blood alcohol level. The legal limit is 0.08% by mass in most states. You use the following reaction in your determination, assuming only the ethanol (C2H5OH) in the blood sample will react with the dichromate.16H+(aq) + 2Cr2O72−(aq) + C2H5OH(l) 4Cr3+(aq) + 11H2(l) + 2CO2(g) If 14.6 mL of 0.10 M K2Cr2O7 are needed to react completely with 28 g of blood, what is the blood alcohol level of the driver?Treatment of ammonia with phenol in the presence of hypochlorite yields indophenol, a blue product that absrobs light at 625 nm, which can be used for the spectrophotometric determination of ammonia. ocr -OH • NH, indophenol anion To determine the ammonia concentration in a sample of lake water, three samples are prepared. In sample A, 10.0 mL of lake water is mixed with 5 mL of phenol solution and 2 mL of sodium hypochlorite solution, and diluted to 25.0 mL in a volumetric flask. In sample B, 10.0 mL of lake water is mixed with 5 mL. of phenol solution, 2 mL of sodium hypochlorite solution, and 2.50 mL of a 5.50 x 10-4 M ammonia solution, and diluted to 25.0 mL. Sample C is a reagent blank. It contains 10.0 mL of distilled water, 5 mL of phenol solution, and 2 ml. of sodium hypochlorite solution, diluted to 25.0 mL. The absorbance of the three samples is then measured at 625 nm in a 1.00 cm cuvette. The results are shown in the table. Sample Absorbance (625 nm) A 0.374 В 0.621 0.045…