Organic Chemistry: A Guided Inquiry
2nd Edition
ISBN:9780618974122
Author:Andrei Straumanis
Publisher:Andrei Straumanis
Chapter20: Acidity And Pka Of Phenols
Section: Chapter Questions
Problem 11E
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Question
Complete the synthesis reaction showing curved arrows and mechanisms for each reaction.
Expert Solution
Step 1
For the above organic synthesis, the following transformations must be known:
1. H2 in presence of Lindlar's catalyst reduces alkyne to cis-alkene.
2. p-Toluenesulfonic acid reacts with 3o alcohol to form tosylate and elimination occurs.
3. H2 , Pd/C reduces alkenes to alkanes.
4. Oppenauer Oxidation is a simple method for selectively oxidizing 2o acohols to ketones.
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