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- Please assign priority groups and assign R or S stereochemistry for eachIn which compound is the halogen substituted most rapidly by aq hydroxide ions? a. CH3CH2CH2CH2Cl b. (CH3)3CI c. (CH3)3CCl d. CH3CH2CH2CH2IA)Circle all of the stereo centers in MDMA. B) assign the absolute stereochemistry (R or S) for each stereo center
- 1. Why P(CH₂CH₃)₃ dissociiation is faster than PF3?2. What is the product from cis-[PtCl2(NH3)2] + 2py and explainWhy does the final product has the opposite configuration compared to the reactant? Shouldn’t it form OMs first, then OMs gets substituted by Cl- via Sn2 (the 1st inversion of configuration) then the Cl- gets substituted by OCH3- (the 2nd inversion of configuration? To my understanding 2 inversions = same configurationArrange the alkyl halides in order of increasing reactivity in an SN2 reaction with KI in acetone (least first). I, IV, III, II II, III, I, IV IV, I, III, II III, II, IV, I
- What are the final products. Show stereochemistry if needed.Organotin compounds play a significant role in diverse industrial applications. They have been used as plastic stabilizers and as pesticides or fungicides. One method used to prepare simple tetraalkylstannanes is the controlled direct reaction of liquid tin(IV) chloride with highly reactive trialkylaluminum compounds, such as liquid triethylaluminum (Al(CzHs)3). 3SnCl4 + 4Al(C2H5)3 → 3Sn(C2H5)4 + 4AlCl3 In one experiment, 0.160 L of SnCl4 (d= 2.226 g/mL) was treated with 0.346 L of triethylaluminum (Al(C2H5)3); d = 0.835 g/mL). What is the theoretical yield in this experiment (mass of tetraethylstannane, Sn(C2H5)4)? If 0.257L of tetraethylstannane (d= 1.187 g/mL) were actually isolated in this experiment, what was the percent yield?Why does the melting point (70-71) above match neither the enantiomers’ nor the racemate’s? Does it mean that the substance is impure, or perhaps isn’t even ibuprofen at all? (Racemic mixture:75-77C, Enantiomer:52-53C)