[S] >> [Etotal]. The rate of formation of ES equals its rate of breakdown. The rate of breakdown of ES to E + P is much faster than the rate of breakdown of ES back to E + S. KM = [E][S]/[ES] The concentration of ES is small relative to the concentration of Etotal. [Etotal] >> [Efree]. The rate of reaction is equal to k₂[ES]. The velocity of the catalyzed reaction is equal to k₁ [E][S].

[S] >> [Etotal]. The rate of formation of ES equals its rate of breakdown. The rate of breakdown of ES to E + P is much faster than the rate of breakdown of ES back to E + S. KM = [E][S]/[ES] The concentration of ES is small relative to the concentration of Etotal. [Etotal] >> [Efree]. The rate of reaction is equal to k₂[ES]. The velocity of the catalyzed reaction is equal to k₁ [E][S].

Chemistry by OpenStax (2015-05-04)

1st Edition

ISBN:9781938168390

Author:Klaus Theopold, Richard H Langley, Paul Flowers, William R. Robinson, Mark Blaser

Publisher:Klaus Theopold, Richard H Langley, Paul Flowers, William R. Robinson, Mark Blaser

Chapter20: Organic Chemistry

Section: Chapter Questions

Problem 28E: Acetylene is a very weak acid; however, it will react with moist silver(I) oxide and form water and...

See similar textbooks

Similar questions

7. Reaction Scheme. о А N 1. xs Mel, xs K2CO3 2. Ag2O, H₂O 3. heat NH2 NH2 or two differnet methods (no same steps/reagents) C5H12N2 Br2, xs NaOH, xs H₂O OHC 1.03 2. DMS CHO
Identify which product(s) would be formed in the reaction below. H20 H;SO4 OH OH OH (1) (II) (III) a. C. ||I O d.1 & |I e. || & III O f. 1 & III
What results from the reaction shown? ОН H H CH;OH но- но. OH cat. HC1 OH OH H OCH; H |-0 H H А) НО но. B) H;CO OCH3 H OH H;CO. он HH;COH OCH; OCH; H H H С) Но- но. D) H;CO H;CO. OCH HHH;COH
What is the major product of the following Grignard reaction? OH Он OH OH Br 1. Mg, THF OH ... | 2. O CH3 3. H;O* b. С. d. е. a.
H-CI II CH3NH2 N-CH3 II N-H ELOH H2SO, (cat) H2N OEt O a! Which of the following reactions will proceed as written? Ob." Oc II C. Odly II Oe. Todas proceden según están escritas. (All)
2) mny Starting mater 1al and product. Provide condihons for a reaction when givern I. 3) HH
The product of the following reaction is: (Nat, CN-)/ ACETONE H. H. Br CI NC H- H. Br 1 CI CI CN CN II II 50% I & 50%|| II
What i the MAJOR praduct of the reaction below? Ch H3C- - NHČCH3 FeCl - NHČCH; H3C- H3C- - NHČCH; © H;C- - NHČCH, O H3C- - NHCH;
7. Reaction Scheme. NH₂ NH2 or two differnet methods (no same steps/reagents) C5H12N2 1. xs Mel, xs K2CO3 2. Ag2O, H₂O 3. heat Br2, xs NaOH, xs H₂O OHC 1.03 2. DMS CHO
CH3 CH3 H3C N. H Tetracaine Tetracaine can be synthesized from benzene. The synthesis involves the following steps: 1. Benzene + CH3CI, AICI3 to form product A; 2. A + HNO3, H2SO4 to form product B; 3. B + KMNO4, H2O to form product C; 4. C + SOCI, to form product D; 5. D + HOCH2CH2N(CH3)2 to form product E; 6. E + H2, Pt to form product F; 7. F + CH3CH2CH2CHO to form product G; 8. G + NABH3CN to form Tetracaine. Draw the structures of product A and product G. You do not have to consider stereochemistry. • You do not have to explicitly draw H atoms. • Do not include lone pairs in your answer. They will not be considered in the grading. • Draw one structure per sketcher. Add additional sketchers using the drop-down menu in the bottom right corner. Show the order of synthesis by drawing a reaction arrow between A and G, pointing toward the later-synthesized product.
21. The reaction scheme for the preparation of Z starting from benzene is as follows: CH,CI/AICI; KMNO. H" ClyAICl; C6H6 What is Z? A. CI В. C. D. CH,COCI COOH CH,COOH CICH B. D 27
Provide the products and detailed arrow pushing mechanisms for the following reactions: OSIME3 EtN CO.Me 1. base, dilute solution (10mM) 2. NaOH/MEOH-H,0 Acid, heat CO.Me