To draw: The structure of the given compound with the proper representation of pi bond and geometry. Interpretation: The structure of the given compound with the proper representation of pi bond and geometry is to be drawn. Concept introduction: Isomers are the compounds with similar formula but different structures. Stereoisomers are the type of isomers in which arrangement of atoms differ in space. Geometric isomers are one of the types of stereoisomers. These are of two types and are named as, cis and trans isomers. These types of isomers generate due to the restricted rotations around the carbon-carbon double bond within the molecule.

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Answer 1

Question

Chapter 1, Problem 1.56SP

(a)

Interpretation Introduction

To draw: The structure of the given compound with the proper representation of pi bond and geometry.

Interpretation: The structure of the given compound with the proper representation of pi bond and geometry is to be drawn.

Concept introduction: Isomers are the compounds with similar formula but different structures. Stereoisomers are the type of isomers in which arrangement of atoms differ in space. Geometric isomers are one of the types of stereoisomers. These are of two types and are named as, cis and trans isomers. These types of isomers generate due to the restricted rotations around the carbon-carbon double bond within the molecule.

(b)

Interpretation Introduction

To determine: The six coplanar atoms in the given compound.

Interpretation: Six coplanar atoms in the given compound are to be circled.

Concept introduction: Carbon –carbon double bonds exist in the same plane. Hydrogen or any other group also lies in the same plane to satisfy its valency. In the given compound, sp2 hybridization is present. In this type of hybridization, all the groups lie in the same plane.

(c)

Interpretation Introduction

To draw: The structure of the trans isomer of the given compound with circled coplanar atoms and if there are still six coplanar atoms.

Interpretation: The structure of the trans isomer of the given compound with circled coplanar atoms is to be drawn and the existence of six coplanar atoms is to be validated.

Concept introduction: Stereoisomers are the type of isomers in which arrangement of atoms differ in space. Geometric isomers are one of the types of stereoisomers. These are of two types and are named as, cis and trans isomers. These types of isomers generate due to the restricted rotations around the carbon-carbon double bond within the molecule.

(d)

Interpretation Introduction

To determine: The representation of circled coplanar atoms in the given compound.

Interpretation: The coplanar atoms in the given compound are to be circled.

Concept introduction: Carbon –carbon double bonds exist in the same plane. Hydrogen or any other group also lies in the same plane to satisfy its valency. In the given compound, sp2 hybridization is present. In this type of hybridization, all the groups lie in the same plane.

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Predict all bond angles in each compound. a. CH3Cl b. NH2OH c. CH2=NCH3 d. HC≡CCH2OH

1. Draw three molecules of each compound, i.e. draw the molecules next to one another to visualize IMFa. Propane, CH3CH2CH3b. Heptane, CH3(CH2)5CH3 c. Propanol, CH3CH2CH2OH d. Heptanol, CH3(CH2)6OH2. For each compound, consider whether or not H-bonding can occur between its molecules. Use a dashed line to show any H-bonding.3. For each compound, consider whether or not any polar bonds are presenta. Use a different coloured pen to identify any polar bondsb. Which compounds are polar? Which compounds are nonpolar? Explain your reasoning4. Compare your drawings for propanol and heptanol.a. Which compound has stronger dispersion forces? Explain your answerb. Which compound has a higher boiling point? Explain your answer5. Compare your drawings of heptanes and heptanola. Which compound is more polar? Explain your answerb. Which compound is more soluble in water? Explain your answer

Draw an orbital picture of propene. The bond between and is formed by the overlap of which types of orbitals? a. sp2 and sp2 b. sp3 and sp3 c. sp2 on Ca and sp3 on Cb d. sp3 on Ca and sp2 on Cb The double bond between and is formed by what? a. two sigma bonds b. two pi bonds c. overlap of a p orbital on Cb with a sp2 orbital on Cc. d. overlap of two p orbitals plus overlap of two sp2 orbitals

Answer 2

Question

Chapter 1, Problem 1.56SP

(a)

Interpretation Introduction

To draw: The structure of the given compound with the proper representation of pi bond and geometry.

Interpretation: The structure of the given compound with the proper representation of pi bond and geometry is to be drawn.

Concept introduction: Isomers are the compounds with similar formula but different structures. Stereoisomers are the type of isomers in which arrangement of atoms differ in space. Geometric isomers are one of the types of stereoisomers. These are of two types and are named as, cis and trans isomers. These types of isomers generate due to the restricted rotations around the carbon-carbon double bond within the molecule.

(b)

Interpretation Introduction

To determine: The six coplanar atoms in the given compound.

Interpretation: Six coplanar atoms in the given compound are to be circled.

Concept introduction: Carbon –carbon double bonds exist in the same plane. Hydrogen or any other group also lies in the same plane to satisfy its valency. In the given compound, sp2 hybridization is present. In this type of hybridization, all the groups lie in the same plane.

(c)

Interpretation Introduction

To draw: The structure of the trans isomer of the given compound with circled coplanar atoms and if there are still six coplanar atoms.

Interpretation: The structure of the trans isomer of the given compound with circled coplanar atoms is to be drawn and the existence of six coplanar atoms is to be validated.

Concept introduction: Stereoisomers are the type of isomers in which arrangement of atoms differ in space. Geometric isomers are one of the types of stereoisomers. These are of two types and are named as, cis and trans isomers. These types of isomers generate due to the restricted rotations around the carbon-carbon double bond within the molecule.

(d)

Interpretation Introduction

To determine: The representation of circled coplanar atoms in the given compound.

Interpretation: The coplanar atoms in the given compound are to be circled.

Concept introduction: Carbon –carbon double bonds exist in the same plane. Hydrogen or any other group also lies in the same plane to satisfy its valency. In the given compound, sp2 hybridization is present. In this type of hybridization, all the groups lie in the same plane.

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Answer 3

Question

Chapter 1, Problem 1.56SP

(a)

Interpretation Introduction

To draw: The structure of the given compound with the proper representation of pi bond and geometry.

Interpretation: The structure of the given compound with the proper representation of pi bond and geometry is to be drawn.

Concept introduction: Isomers are the compounds with similar formula but different structures. Stereoisomers are the type of isomers in which arrangement of atoms differ in space. Geometric isomers are one of the types of stereoisomers. These are of two types and are named as, cis and trans isomers. These types of isomers generate due to the restricted rotations around the carbon-carbon double bond within the molecule.

(b)

Interpretation Introduction

To determine: The six coplanar atoms in the given compound.

Interpretation: Six coplanar atoms in the given compound are to be circled.

Concept introduction: Carbon –carbon double bonds exist in the same plane. Hydrogen or any other group also lies in the same plane to satisfy its valency. In the given compound, sp2 hybridization is present. In this type of hybridization, all the groups lie in the same plane.

(c)

Interpretation Introduction

To draw: The structure of the trans isomer of the given compound with circled coplanar atoms and if there are still six coplanar atoms.

Interpretation: The structure of the trans isomer of the given compound with circled coplanar atoms is to be drawn and the existence of six coplanar atoms is to be validated.

Concept introduction: Stereoisomers are the type of isomers in which arrangement of atoms differ in space. Geometric isomers are one of the types of stereoisomers. These are of two types and are named as, cis and trans isomers. These types of isomers generate due to the restricted rotations around the carbon-carbon double bond within the molecule.

(d)

Interpretation Introduction

To determine: The representation of circled coplanar atoms in the given compound.

Interpretation: The coplanar atoms in the given compound are to be circled.

Concept introduction: Carbon –carbon double bonds exist in the same plane. Hydrogen or any other group also lies in the same plane to satisfy its valency. In the given compound, sp2 hybridization is present. In this type of hybridization, all the groups lie in the same plane.

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Answer 4

Question

Chapter 1, Problem 1.56SP

(a)

Interpretation Introduction

To draw: The structure of the given compound with the proper representation of pi bond and geometry.

Interpretation: The structure of the given compound with the proper representation of pi bond and geometry is to be drawn.

Concept introduction: Isomers are the compounds with similar formula but different structures. Stereoisomers are the type of isomers in which arrangement of atoms differ in space. Geometric isomers are one of the types of stereoisomers. These are of two types and are named as, cis and trans isomers. These types of isomers generate due to the restricted rotations around the carbon-carbon double bond within the molecule.

(b)

Interpretation Introduction

To determine: The six coplanar atoms in the given compound.

Interpretation: Six coplanar atoms in the given compound are to be circled.

Concept introduction: Carbon –carbon double bonds exist in the same plane. Hydrogen or any other group also lies in the same plane to satisfy its valency. In the given compound, sp2 hybridization is present. In this type of hybridization, all the groups lie in the same plane.

(c)

Interpretation Introduction

To draw: The structure of the trans isomer of the given compound with circled coplanar atoms and if there are still six coplanar atoms.

Interpretation: The structure of the trans isomer of the given compound with circled coplanar atoms is to be drawn and the existence of six coplanar atoms is to be validated.

Concept introduction: Stereoisomers are the type of isomers in which arrangement of atoms differ in space. Geometric isomers are one of the types of stereoisomers. These are of two types and are named as, cis and trans isomers. These types of isomers generate due to the restricted rotations around the carbon-carbon double bond within the molecule.

(d)

Interpretation Introduction

To determine: The representation of circled coplanar atoms in the given compound.

Interpretation: The coplanar atoms in the given compound are to be circled.

Concept introduction: Carbon –carbon double bonds exist in the same plane. Hydrogen or any other group also lies in the same plane to satisfy its valency. In the given compound, sp2 hybridization is present. In this type of hybridization, all the groups lie in the same plane.

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Answer 5

Chapter 1, Problem 1.56SP

(a)

Interpretation Introduction

To draw: The structure of the given compound with the proper representation of pi bond and geometry.

Interpretation: The structure of the given compound with the proper representation of pi bond and geometry is to be drawn.

Concept introduction: Isomers are the compounds with similar formula but different structures. Stereoisomers are the type of isomers in which arrangement of atoms differ in space. Geometric isomers are one of the types of stereoisomers. These are of two types and are named as, cis and trans isomers. These types of isomers generate due to the restricted rotations around the carbon-carbon double bond within the molecule.

(b)

Interpretation Introduction

To determine: The six coplanar atoms in the given compound.

Interpretation: Six coplanar atoms in the given compound are to be circled.

Concept introduction: Carbon –carbon double bonds exist in the same plane. Hydrogen or any other group also lies in the same plane to satisfy its valency. In the given compound, sp2 hybridization is present. In this type of hybridization, all the groups lie in the same plane.

(c)

Interpretation Introduction

To draw: The structure of the trans isomer of the given compound with circled coplanar atoms and if there are still six coplanar atoms.

Interpretation: The structure of the trans isomer of the given compound with circled coplanar atoms is to be drawn and the existence of six coplanar atoms is to be validated.

Concept introduction: Stereoisomers are the type of isomers in which arrangement of atoms differ in space. Geometric isomers are one of the types of stereoisomers. These are of two types and are named as, cis and trans isomers. These types of isomers generate due to the restricted rotations around the carbon-carbon double bond within the molecule.

(d)

Interpretation Introduction

To determine: The representation of circled coplanar atoms in the given compound.

Interpretation: The coplanar atoms in the given compound are to be circled.

Concept introduction: Carbon –carbon double bonds exist in the same plane. Hydrogen or any other group also lies in the same plane to satisfy its valency. In the given compound, sp2 hybridization is present. In this type of hybridization, all the groups lie in the same plane.

Answer 6

Chapter 1, Problem 1.56SP

(a)

Interpretation Introduction

To draw: The structure of the given compound with the proper representation of pi bond and geometry.

Interpretation: The structure of the given compound with the proper representation of pi bond and geometry is to be drawn.

Concept introduction: Isomers are the compounds with similar formula but different structures. Stereoisomers are the type of isomers in which arrangement of atoms differ in space. Geometric isomers are one of the types of stereoisomers. These are of two types and are named as, cis and trans isomers. These types of isomers generate due to the restricted rotations around the carbon-carbon double bond within the molecule.

Answer 7

Chapter 1, Problem 1.56SP

(a)

Interpretation Introduction

To draw: The structure of the given compound with the proper representation of pi bond and geometry.

Interpretation: The structure of the given compound with the proper representation of pi bond and geometry is to be drawn.

Concept introduction: Isomers are the compounds with similar formula but different structures. Stereoisomers are the type of isomers in which arrangement of atoms differ in space. Geometric isomers are one of the types of stereoisomers. These are of two types and are named as, cis and trans isomers. These types of isomers generate due to the restricted rotations around the carbon-carbon double bond within the molecule.

Answer 8

(b)

Interpretation Introduction

To determine: The six coplanar atoms in the given compound.

Interpretation: Six coplanar atoms in the given compound are to be circled.

Concept introduction: Carbon –carbon double bonds exist in the same plane. Hydrogen or any other group also lies in the same plane to satisfy its valency. In the given compound, sp2 hybridization is present. In this type of hybridization, all the groups lie in the same plane.

Answer 9

(b)

Interpretation Introduction

To determine: The six coplanar atoms in the given compound.

Interpretation: Six coplanar atoms in the given compound are to be circled.

Concept introduction: Carbon –carbon double bonds exist in the same plane. Hydrogen or any other group also lies in the same plane to satisfy its valency. In the given compound, sp2 hybridization is present. In this type of hybridization, all the groups lie in the same plane.

Answer 10

(c)

Interpretation Introduction

To draw: The structure of the trans isomer of the given compound with circled coplanar atoms and if there are still six coplanar atoms.

Interpretation: The structure of the trans isomer of the given compound with circled coplanar atoms is to be drawn and the existence of six coplanar atoms is to be validated.

Concept introduction: Stereoisomers are the type of isomers in which arrangement of atoms differ in space. Geometric isomers are one of the types of stereoisomers. These are of two types and are named as, cis and trans isomers. These types of isomers generate due to the restricted rotations around the carbon-carbon double bond within the molecule.

Answer 11

(c)

Interpretation Introduction

To draw: The structure of the trans isomer of the given compound with circled coplanar atoms and if there are still six coplanar atoms.

Interpretation: The structure of the trans isomer of the given compound with circled coplanar atoms is to be drawn and the existence of six coplanar atoms is to be validated.

Concept introduction: Stereoisomers are the type of isomers in which arrangement of atoms differ in space. Geometric isomers are one of the types of stereoisomers. These are of two types and are named as, cis and trans isomers. These types of isomers generate due to the restricted rotations around the carbon-carbon double bond within the molecule.

Answer 12

(d)

Interpretation Introduction

To determine: The representation of circled coplanar atoms in the given compound.

Interpretation: The coplanar atoms in the given compound are to be circled.

Concept introduction: Carbon –carbon double bonds exist in the same plane. Hydrogen or any other group also lies in the same plane to satisfy its valency. In the given compound, sp2 hybridization is present. In this type of hybridization, all the groups lie in the same plane.

Answer 13

(d)

Interpretation Introduction

To determine: The representation of circled coplanar atoms in the given compound.

Interpretation: The coplanar atoms in the given compound are to be circled.

Concept introduction: Carbon –carbon double bonds exist in the same plane. Hydrogen or any other group also lies in the same plane to satisfy its valency. In the given compound, sp2 hybridization is present. In this type of hybridization, all the groups lie in the same plane.

Answer 14

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Answer 15

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Answer 16

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Answer 17

Ch. 1.2C - a. Nitrogen has relatively stable isotopes...Ch. 1.4 - Draw Lewis structures for the following compounds....Ch. 1.5 - Write Lewis structures for the following molecular...Ch. 1.5 - Circle any lone pairs (pairs of nonbonding...Ch. 1.6 - Use electronegativities to predict the direction...Ch. 1.8 - Prob. 1.6P Ch. 1.9B - Draw the important resonance forms for the...Ch. 1.9B - Prob. 1.8P Ch. 1.9B - Prob. 1.9P Ch. 1.9B - Use resonance structures to identify the areas of...

Solution Summary: The author explains the structure of the compound with the proper representation of pi bond and geometry.

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