Inorganic Chemistry
5th Edition
ISBN: 9781292134147
Author: Housecroft, Catherine E.
Publisher: Pearson,
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Chapter 1, Problem 42P
The sign convention for
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Given:
Enthalpy of atomisation of calcium =+ 178 kJ
First ionisation energy of calcium =+590 kJ
Second ionisation energy of calcium = +1145 kJ
Enthalpy of atomisation of chlorine =+ 121 kJ
Electron affinity of chlorine
Lattice energy of calcium chloride =- 2258 kJ
= - 346 kJ
Construct a Born-Haber cycle for calcium chloride, CaCl2 by using the data
given above. Hence, calculate the enthalpy of formation of calcium chloride.
b. The enthalpy of solution for calcium chloride crystal is -81.3 kJ mol'. Based on
the data from the above Born-Haber cycle, calculate the enthalpy change for the
reaction below:
Ca" (g) + 2CI (g)–→ Ca* (aq) + 2CI¯ (aq)
how do you calculate the energy of one mole of AlCl3 from its elements in their standard states if HCL has an energy of -167 kj/mol
QUESTION 7
In which of the following situations does the potential energy decrease? Check ALL that apply.
a. A ball falls to the ground.
b. The distance between two electrons is increased.
Oc. The distance between a proton and an electron is increased.
Chapter 1 Solutions
Inorganic Chemistry
Ch. 1 - Chromium has four isotopes C2450r, C2452r, C2453r...Ch. 1 - Prob. 2PCh. 1 - Using the list of naturally occurring isotopes in...Ch. 1 - Hydrogen possesses three isotopes, but tritium ,...Ch. 1 - (a) By using the data in appendix 5, account for...Ch. 1 - Calculate the corresponding wavelength of...Ch. 1 - State which of the following n'n transitions in...Ch. 1 - Calculate the energy (in kJ per mole of photons)...Ch. 1 - 1.9 Four of the lines in Balmer series are at...Ch. 1 - 1.10 Using the Bohr model, determine the values of...
Ch. 1 - 1.11 How is the (a) energy and (b) size of an ns...Ch. 1 - 1.12 Write down a set of quantum numbers that...Ch. 1 - Do the three 4p atomic orbitals possess the same...Ch. 1 - How many radial nodes does each of the following...Ch. 1 - 1.15 Comment on the differences between plots of...Ch. 1 - 1.16 Write down the sets of quantum numbers that...Ch. 1 - Write down the three sets of quantum numbers that...Ch. 1 - How many atomic orbitals make up the set with n=4...Ch. 1 - Prob. 19PCh. 1 - (a) Will a plot of R(r) for the 1s atomic orbital...Ch. 1 - Prob. 21PCh. 1 - Prob. 22PCh. 1 - Write down the six sets of quantum numbers that...Ch. 1 - For a neutral atom, X, the following atomic...Ch. 1 - Using the concepts of shielding and penetration,...Ch. 1 - For each of the following atoms, write down a...Ch. 1 - 1.27 Draw energy level diagrams (see Fig. 1.15) to...Ch. 1 - 1.28 Write down the ground state electronic...Ch. 1 - Write down (with reasoning) the ground state...Ch. 1 - Draw energy level diagrams to show the ground...Ch. 1 - The ground state electronic configuration of a...Ch. 1 - (a) Write down an equation that defines the...Ch. 1 - 1.33 The first four ionization energies of an atom...Ch. 1 - 1.34 In Fig. 1.16, identify the trend in the first...Ch. 1 - 1.35 Figure 1.17 shows the values of for the...Ch. 1 - Using the data in Table 1.5, determine a value for...Ch. 1 - Prob. 37PCh. 1 - What is the evidence that the aufbau principle is...Ch. 1 - The first list in the table on the left contains...Ch. 1 - Prob. 40PCh. 1 - Using data from appendix 8, construct a graph to...Ch. 1 - The sign convention for electron affinity can...Ch. 1 - Prob. 43PCh. 1 - 1.45 Figure 1.18 shows the emission spectrum of...
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- Given the following data calculate H for the reaction On the basis of the enthalpy change, is this a useful reaction for the synthesis of ammonia?arrow_forwardg 6.941 mol atomic mass electronegativity 0.98 kJ 59.6 mol electron affinity kJ 520.2 mol ionization energy kJ 3.0 mol heat of fusion Does the following reaction absorb or release energy? O release O absorb (1) Li (g) + e Li(g) O Can't be decided with the data given. Is it possible to calculate the amount of energy absorbed or released by reaction (1) using only the data above? O yes no If you answered yes to the previous question, enter the amount of energy absorbed or released by reaction (1): I kJ/mol Does the following reaction absorb or release energy? O release O absorb (2) Li(g) → Li (g) + e O Can't be decided with the data given. Is it possible to calculate the amount of energy absorbed or released by reaction (2) using only the data above? O yes O no If you answered yes to the previous question, enter the amount of energy absorbed or released by reaction (2): I kJ/molarrow_forwardThe first ionization energy of potassium is 419 kJ mol-1. The first electron affinity of chlorine is –349 kJ mol-1. Use your knowledge of thermochemistry to calculate the overall change in energy for the process shown below. Show all thermochemical equations for the processes involvedarrow_forward
- Electron affinity is the energy change that occurs when an electron is added to a gaseous atom. For most atoms, would you expect the sign for this energy change to be positive (energy required) or negative (energy released) and why? O Negative, because energy is required to add an electron. O Negative, because energy is released to add an electron. Positive, because energy is released to add an electron. Positive, because energy is required to add an electron.arrow_forwarddoes electron gain enthalpy depends upon atomic size?arrow_forward6.941 mol atomic mass electronegativity 0.98 kJ 59.6 mol electron affinity kJ 520.2 mol ionization energy kJ 3.0 mol heat of fusion Does the following reaction absorb or release energy? O release O absorb (1) Li (g) + e Li(g) O Car be decided with the data given. Is it possible to calculate the amount of energy absorbed or released by reaction (1) using only the data above? O yes O no If you answered yes to the previous question, enter the amount of energy absorbed or released by reaction (1): O k/mol Does the following reaction absorb or release energy? O release O absorb (2) Li(g) → Li (g) + e O Can't be decided with the data given. Is it possible to calculate the amount of energy absorbed or released by reaction (2) using only the data above? O yes O no If you answered yes to the previous question, enter the amount of energy absorbed or released by reaction (2): I kJ/molarrow_forward
- Write the electron configuration for a neutral atom of potassium. C.arrow_forward1) Calculate the lattice energy for NaCl(s) using a Born-Haber cycle and the following information: NaCl(s) → Nat(g) + Cl-(g) Na(s) + 1/2 C12(g) → NaCl(s) Na(s) → Na(g) Na(g) → Na+(g) + e- 1/2 C12(g) → Cl(g) Cl(g) + e- → Cl-(g) ? -411.0 kJ/mol +107.3 kJ/mol +495.8 kJ/mol +121.7 kJ/mol -348.6 kJ/molarrow_forwardWrite the electron configurations of a phosphorus atom and its negative ion. Give the charge on the anion.arrow_forward
- 1. Silicon has the electronic configuration 1s2 2s2 2p6 3s2 3p2. Discuss how you can determine that 1s2 2s2 2p6 3s2 3p2 is the electronic configuration for silicon. 2. What is a reason potassium tends to lose one electron to form a +1 ion K+1? What is the reason chlorine tends to add one electron to form the -1 ion Cl-1 ? Hint: They are the same reason. 3. In the abbreviated electronic figure for phosphorus [Ar] 3s2 3p3 how do you know what are the core electrons? 4. A student got a problem wrong. They were asked, “How many grams of MgCl2 (molar mass = 95.21 g/mol) are needed to make 3.16 L of a 0.500 M MgCl2 solution?” The correct answer is 150. but the student got 1.58. What mistake did the student make? 5. To solve the following problem what is the reason you must subtract the vapor pressure of water, 24 torr, from the total pressure, 747 torr in order to solve the problem? “A 500.0-mL sample of H2 gas is collected over water at 298 K and 747 torr. What volume would the…arrow_forwardCyanamide is a compound containing two hydrogen atoms and some amount of C and N. There are a total of 5 atoms in the compound. The products of combustion were found to be CO2, NO2, and H2O. If the enthalpy of combustion for cyanamide is – 671.9 kJ/mol and the enthalpy of formation is 58.8 kJ/mol, what is the chemical formula for cyanamide? ( ΔfH (CO2) = - 393.51 kJ/mole; ΔfH (NO2) = + 33.10 kJ/mole; ΔfH (H2O) = - 241.826 kJ/mole)arrow_forwardWhat are “valence electrons”?arrow_forward
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