Organic Chemistry
7th Edition
ISBN: 9780321803221
Author: Paula Y. Bruice
Publisher: Prentice Hall
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Textbook Question
Chapter 1, Problem 63P
Rank the following compounds from highest dipole moment to lowest dipole moment:
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List the bond lenghts between the carbon and the oxygen atoms for the carboxylic acid and carboxylate ion and rank from shortest to longest.
carboxylic acid
carboxylate ion
c-o c=o
provide an explanation for the differences in the bond lengths and the orientation of the dipole moment between the acid and ion.
Rank compounds by increasing dipole moment. Use (
Which bond has the largest dipole moment?
C-H
H-Cl
C-S
O-H
Chapter 1 Solutions
Organic Chemistry
Ch. 1.1 - Oxygen has three isotopes, 16O, 17O, and 18O. The...Ch. 1.1 - Chlorine has two isotopes, 35Cl and 37Cl; 75.77%...Ch. 1.2 - Prob. 3PCh. 1.2 - a. Write the ground-state electronic configuration...Ch. 1.2 - Look at the relative positions of each pair of...Ch. 1.3 - a. Find potassium (K) in the periodic table and...Ch. 1.3 - Which bond is more polar? a. b. c. d.Ch. 1.3 - Which of the following has a. the most polar bond?...Ch. 1.3 - Use the symbols + and to show the direction of...Ch. 1.3 - Explain why HCL has a smaller dipole moment than...
Ch. 1.3 - After examining the potential maps for LiH, HF,...Ch. 1.4 - An atom with a formal charge does not necessarily...Ch. 1.4 - Prob. 15PCh. 1.4 - a. Draw two Lewis structure for C2H6O. b. Draw...Ch. 1.4 - Draw the lone-pair electrons that are not shown in...Ch. 1.4 - Prob. 19PCh. 1.4 - Which of the atoms in the molecular models in...Ch. 1.4 - Prob. 21PCh. 1.5 - Draw the following orbitals: a. 3s orbital b. 4s...Ch. 1.6 - Prob. 23PCh. 1.6 - Indicate the kind of molecular orbital (, , , or )...Ch. 1.7 - What orbitals are used to form the 10 sigma bonds...Ch. 1.7 - Explain why a bond formed by overlap of s orbital...Ch. 1.9 - Put n number in each of the blanks: a. __ s...Ch. 1.11 - Predict the approximate bond angles in a. the...Ch. 1.11 - According to the potential map for the ammonium...Ch. 1.12 - Prob. 32PCh. 1.13 - a. What are the relative lengths and strengths of...Ch. 1.13 - Prob. 35PCh. 1.14 - Prob. 36PCh. 1.15 - Which of the bond in a carbon-oxygen double bond...Ch. 1.15 - Would you expect a CC bond formed by sp2sp2...Ch. 1.15 - Caffeine is a natural insecticide found in the...Ch. 1.15 - Prob. 41PCh. 1.15 - Predict the approximate bond angles for a. the CNC...Ch. 1.16 - If the dipole moment of CH3F is 1.847 D and the...Ch. 1.16 - Account for the difference in the shape and color...Ch. 1.16 - What of the following molecules would you expect...Ch. 1 - Prob. 46PCh. 1 - Prob. 47PCh. 1 - What is the hybridization of all the atoms (other...Ch. 1 - Draw the condensed structure of a compound that...Ch. 1 - Predict the approximate bond angles: a. the CNH...Ch. 1 - Prob. 51PCh. 1 - Draw a Lewis structure for each of the following:...Ch. 1 - 53. What is the hybridization of each of the...Ch. 1 - Rank the bonds from most polar. a. CO, CF, CN b....Ch. 1 - Draw a Lewis structure for each of the following:...Ch. 1 - What is the hybridization of the indicated atom in...Ch. 1 - Prob. 57PCh. 1 - Prob. 58PCh. 1 - Draw the missing lone-pair electrons and assigns...Ch. 1 - a. Which of the indicated bonds in each molecule...Ch. 1 - For each of the following molecules, indicate the...Ch. 1 - Draw a Lewis structure for each of the following:...Ch. 1 - Rank the following compounds from highest dipole...Ch. 1 - In which orbitals are the lone pairs in nicotine?Ch. 1 - Prob. 65PCh. 1 - Prob. 66PCh. 1 - a. Which of the species have bond angles of 109.5?...Ch. 1 - Prob. 68PCh. 1 - Which compound has a larger dipole moment: CH3Cl...Ch. 1 - Prob. 70PCh. 1 - Prob. 71PCh. 1 - Explain why CH3Cl has a greater dipole moment than...Ch. 1 - Prob. 73P
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- Explain why the dipole moment of ammonia is slightly higher than methylamine.arrow_forwardDonepezil is the drug used to treat Alzheimer's disease. Predict the approximate bond angle, d in Donepezil and the molecular geometry of the indicated Nitrogen atom molecular geometry Donepezil od- 109°, molecular geometry = tetrahedral od- 109°, molecular geometry = trigonal pyramidal od- 109°, molecular geometry bent Od= 109°, molecular geometry linear d= 120°, molecular geometry tetrahedral d = 120°, molecular geometry = trigonal pyramidal d 120°, molecular geometry = bentarrow_forwardTo preview the image click here ↓ For each pair of structures, which of A and B would have the larger Molecular dipole moment? Pair I Pair II :CI H :0: A H CI: Pair I: A is larger, Pair II: A is larger Pair I: A is larger, Pair II: B is larger Pair I: B is larger, Pair II: B is larger Pair 1: B is larger, Pair II: A is larger :0: B :CI: H I H-C-C-H I H:CI: B ..arrow_forward
- Identify the polar bond with the largest dipole moment. Group of answer choices H-N H-O H-H H-Barrow_forwardSpecify whether you expect a molecular dipole moment for each of the following compounds. ball & stick ✓ H3C + labels CH3 Dipole : ball & stick ✓ + labels H2₂C=CCI2 Dipole :arrow_forwardSulfur dioxide has a dipole moment of 1.60 D. Carbon dioxide has a dipole moment of zero, even though C¬O bonds are more polar than S¬O bonds. Explain this apparent contradictionarrow_forward
- Arrange the given bent molecules in order of decreasing dipole moment. Largest dipole moment Smallest dipole moment Answer Bank Н, Те H,O H,S H, Searrow_forward[a] Does SCl have a dipole moment? If so, in which direction does the net dipole point? [b] Does BeCl2 have a dipole moment? If so, in which direction does the net dipole point?arrow_forward19. Based on molecular mass and dipole moment of the five compounds in the table below, which one should have the highest boiling point? Dipole Moment (D) Substance Molecular Mass (amu) Propane, CH3CH2CH3 Dimethyl ether, CH3OCH3 Methylchloride, CH3C1 Acetaldehyde, CH;CHO Acetonitrile, CH3CN 44 0.1 46 1.3 50 1.9 44 2.7 41 3.9 B) CH;CN E) CH3CH2CH3 C) CH3CHO A) CH3OCH3 D) CH;CIarrow_forward
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Types of bonds; Author: Edspira;https://www.youtube.com/watch?v=Jj0V01Arebk;License: Standard YouTube License, CC-BY