Organic Chemistry (9th Edition)
Organic Chemistry (9th Edition)
9th Edition
ISBN: 9780321971371
Author: Leroy G. Wade, Jan W. Simek
Publisher: PEARSON
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Chapter 1.11, Problem 1.14P

Compute the empirical and molecular formulas for each of the following elemental analyses In each case, propose at least one structure that fits the molecular formula

C H N Cl MW
(a) 40.0% 667% 0 0 90
(b) 32 0% 667% 18.7% 0 75
(c) 256% 4.32% 15 0% 37 9% 93
(d) 38 4% 4 80% 0 56 8% 125
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e) when a compound Containy e, H and 2 N's . Now, when we add two nitrogen atom we Should 2 CH2 unit (a). when a Compound Contaiy only c and H. thet meany C2 Hq urit mupt be elimate from the base formula, 136 = 10 +음 Nou, the mew formula Containing two nitrogen is - Accurding to the formula n=10 and r: 6 the base formula mupt be- Go HiD46 Ov, Cro Hia (d) when a Compound Containg c, H, 2NS and 20's when a Compound Contains e , H and 2 o's . Now, when we add two nitrogen and two orygen atom , we 2 CH4 and 2CH2 unit respectively, ) Now, when wse add two onygen atom Should elimimate 2 CHq unit that meanp G Hg unit myst eliminate from the hase formula. we Should that means we should elimimete C4 H2 unit from the base for mula . Now, the new formula Containig two onygen atom in Now, the new for mula Containing tawo nitrogen and two ozygen sn Cc HA Oz N2 6. Calculate the molecular formulas for possible compounds with molecular mass 136 using the Rule of 13. a. a compound that contains only C…
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Chapter 1 Solutions

Organic Chemistry (9th Edition)

Ch. 1.10A - Draw complete Lewis structures for the following...Ch. 1.10B - Give Lewis structures corresponding to the...Ch. 1.10B - Prob. 1.13PCh. 1.11 - Compute the empirical and molecular formulas for...Ch. 1.16 - a. Use your molecular models to make ethane, and...Ch. 1.17 - a. Predict the hybridization of the oxygen atom in...Ch. 1.17 - Predict the hybridization geometry and bond angles...Ch. 1.17 - Predict the hybridization, geometry, and bond...Ch. 1.17 - Prob. 1.19PCh. 1.17 - Allene, CH2=C=CH2, has the structure shown below...Ch. 1.17 - 1. Draw the important resonance forms for each...Ch. 1.18B - Prob. 1.22PCh. 1.18B - Two compounds with the formula CH3CH=NCH3 are...Ch. 1.19B - Prob. 1.24PCh. 1.19B - Give the relationship between the following pairs...Ch. 1 - a. Draw the resonance forms for SO2 (bonded OSO)....Ch. 1 - Name the element that corresponds to each...Ch. 1 - Prob. 1.28SPCh. 1 - For each compound, state whether its bonding is...Ch. 1 - a. Both PCl3 and PCl5 are stable compounds Draw...Ch. 1 - Draw a Lewis structure for each species a. N2H4 b....Ch. 1 - Prob. 1.32SPCh. 1 - Prob. 1.33SPCh. 1 - Draw Lewis structures for a. two compounds of...Ch. 1 - Prob. 1.35SPCh. 1 - Some of the following molecular formulas...Ch. 1 - Prob. 1.37SPCh. 1 - Give the molecular formula of each compound shown...Ch. 1 - 1. From what you remember of electronegativities,...Ch. 1 - For each of the following structures, 1. Draw a...Ch. 1 - Prob. 1.41SPCh. 1 - Prob. 1.42SPCh. 1 - Prob. 1.43SPCh. 1 - Prob. 1.44SPCh. 1 - For each pair of ions, determine which on is more...Ch. 1 - Use resonance structures to identify the areas of...Ch. 1 - Prob. 1.47SPCh. 1 - In 1934, Edward A. Doisy of Washington University...Ch. 1 - If the carbon atom in CH2Cl2 were fat. there would...Ch. 1 - Cyclopropane (C3H6, a three-membered ring) is more...Ch. 1 - Prob. 1.51SPCh. 1 - Prob. 1.52SPCh. 1 - In most amines, the nitrogen atom is sp3...Ch. 1 - Predict the hybridization and geometry of the...Ch. 1 - Draw orbital pictures of the pi bonding in the...Ch. 1 - Prob. 1.56SPCh. 1 - Prob. 1.57SPCh. 1 - Which of the following compounds show cis-trans...Ch. 1 - Give the relationships between the following pairs...Ch. 1 - Dimethyl sulfoxide (DMSO) has been used as an...
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