Products of given reactions has to be predicted. Concept introduction: Given set of conditions gives a final product of reaction through a series of steps. Ester reacts with a base to form an enolate ion which undergoes intramolecular reaction. Carboxylic acid undergoes α substitution by Hell Volhard Zelinsky reaction. A strong base like LDA abstracts α proton from a carbon atom of acetone to form an enolate ion. Enolate ion attacks on carbonyl of ester to form a product. Ester reacts with a base to form an enolate ion which undergoes intramolecular reaction. Ester reacts with a base to form an enolate ion which attacks alkyl bromide to form an alkylated product. Hydrolysis and decarboxylation take place to form a product. A strong base like LDA abstracts α proton from a carbon atom of the ketone to form an enolate ion. Enolate ion attacks on carbonyl of ester to form a product.

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Answer 1

Question

Definition Definition Class of organic compounds that contain a carboxyl group ( - COOH ) and has a general formula R - COOH or R - CO 2 H , where R refers to the alkyl, alkenyl, aryl, or other groups. They can undergo different chemical reactions, such as acid-base reactions, esterification, and oxidation. These are essential components of living organisms, playing important roles in metabolic processes, signaling, and as pharmaceuticals.

Chapter 18, Problem 48P

(a)

Interpretation Introduction

Interpretation: Products of given reactions has to be predicted.

Concept introduction: Given set of conditions gives a final product of reaction through a series of steps.

Ester reacts with a base to form an enolate ion which undergoes intramolecular reaction.

Carboxylic acid undergoes α substitution by Hell Volhard Zelinsky reaction.

A strong base like LDA abstracts α proton from a carbon atom of acetone to form an enolate ion. Enolate ion attacks on carbonyl of ester to form a product.

Ester reacts with a base to form an enolate ion which undergoes intramolecular reaction.

Ester reacts with a base to form an enolate ion which attacks alkyl bromide to form an alkylated product. Hydrolysis and decarboxylation take place to form a product.

A strong base like LDA abstracts α proton from a carbon atom of the ketone to form an enolate ion. Enolate ion attacks on carbonyl of ester to form a product.

(b)

Interpretation Introduction

Interpretation: Products of given reactions has to be predicted.

Concept introduction: Given set of conditions gives a final product of reaction through a series of steps.

Ester reacts with a base to form an enolate ion which undergoes intramolecular reaction.

Carboxylic acid undergoes α substitution by Hell Volhard Zelinsky reaction.

A strong base like LDA abstracts α proton from a carbon atom of acetone to form an enolate ion. Enolate ion attacks on carbonyl of ester to form a product.

Ester reacts with a base to form an enolate ion which undergoes intramolecular reaction.

Ester reacts with a base to form an enolate ion which attacks alkyl bromide to form an alkylated product. Hydrolysis and decarboxylation take place to form a product.

A strong base like LDA abstracts α proton from a carbon atom of the ketone to form an enolate ion. Enolate ion attacks on carbonyl of ester to form a product.

(c)

Interpretation Introduction

Interpretation: Products of given reactions has to be predicted.

Concept introduction: Given set of conditions gives a final product of reaction through a series of steps.

Ester reacts with a base to form an enolate ion which undergoes intramolecular reaction.

Carboxylic acid undergoes α substitution by Hell Volhard Zelinsky reaction.

A strong base like LDA abstracts α proton from a carbon atom of acetone to form an enolate ion. Enolate ion attacks on carbonyl of ester to form a product.

Ester reacts with a base to form an enolate ion which undergoes intramolecular reaction.

Ester reacts with a base to form an enolate ion which attacks alkyl bromide to form an alkylated product. Hydrolysis and decarboxylation take place to form a product.

A strong base like LDA abstracts α proton from a carbon atom of the ketone to form an enolate ion. Enolate ion attacks on carbonyl of ester to form a product.

(d)

Interpretation Introduction

Interpretation: Products of given reactions has to be predicted.

Concept introduction: Given set of conditions gives a final product of reaction through a series of steps.

Ester reacts with a base to form an enolate ion which undergoes intramolecular reaction.

Carboxylic acid undergoes α substitution by Hell Volhard Zelinsky reaction.

A strong base like LDA abstracts α proton from a carbon atom of acetone to form an enolate ion. Enolate ion attacks on carbonyl of ester to form a product.

Ester reacts with a base to form an enolate ion which undergoes intramolecular reaction.

Ester reacts with a base to form an enolate ion which attacks alkyl bromide to form an alkylated product. Hydrolysis and decarboxylation take place to form a product.

A strong base like LDA abstracts α proton from a carbon atom of the ketone to form an enolate ion. Enolate ion attacks on carbonyl of ester to form a product.

(e)

Interpretation Introduction

Interpretation: Products of given reactions has to be predicted.

Concept introduction: Given set of conditions gives a final product of reaction through a series of steps.

Ester reacts with a base to form an enolate ion which undergoes intramolecular reaction.

Carboxylic acid undergoes α substitution by Hell Volhard Zelinsky reaction.

A strong base like LDA abstracts α proton from a carbon atom of acetone to form an enolate ion. Enolate ion attacks on carbonyl of ester to form a product.

Ester reacts with a base to form an enolate ion which undergoes intramolecular reaction.

Ester reacts with a base to form an enolate ion which attacks alkyl bromide to form an alkylated product. Hydrolysis and decarboxylation take place to form a product.

A strong base like LDA abstracts α proton from a carbon atom of the ketone to form an enolate ion. Enolate ion attacks on carbonyl of ester to form a product.

(f)

Interpretation Introduction

Interpretation: Products of given reactions has to be predicted.

Concept introduction: Given set of conditions gives a final product of reaction through a series of steps.

Ester reacts with a base to form an enolate ion which undergoes intramolecular reaction.

Carboxylic acid undergoes α substitution by Hell Volhard Zelinsky reaction.

A strong base like LDA abstracts α proton from a carbon atom of acetone to form an enolate ion. Enolate ion attacks on carbonyl of ester to form a product.

Ester reacts with a base to form an enolate ion which undergoes intramolecular reaction.

Ester reacts with a base to form an enolate ion which attacks alkyl bromide to form an alkylated product. Hydrolysis and decarboxylation take place to form a product.

A strong base like LDA abstracts α proton from a carbon atom of the ketone to form an enolate ion. Enolate ion attacks on carbonyl of ester to form a product.

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Answer 2

Question

Definition Definition Class of organic compounds that contain a carboxyl group ( - COOH ) and has a general formula R - COOH or R - CO 2 H , where R refers to the alkyl, alkenyl, aryl, or other groups. They can undergo different chemical reactions, such as acid-base reactions, esterification, and oxidation. These are essential components of living organisms, playing important roles in metabolic processes, signaling, and as pharmaceuticals.

Chapter 18, Problem 48P

(a)

Interpretation Introduction

Interpretation: Products of given reactions has to be predicted.

Concept introduction: Given set of conditions gives a final product of reaction through a series of steps.

Ester reacts with a base to form an enolate ion which undergoes intramolecular reaction.

Carboxylic acid undergoes α substitution by Hell Volhard Zelinsky reaction.

A strong base like LDA abstracts α proton from a carbon atom of acetone to form an enolate ion. Enolate ion attacks on carbonyl of ester to form a product.

Ester reacts with a base to form an enolate ion which undergoes intramolecular reaction.

Ester reacts with a base to form an enolate ion which attacks alkyl bromide to form an alkylated product. Hydrolysis and decarboxylation take place to form a product.

A strong base like LDA abstracts α proton from a carbon atom of the ketone to form an enolate ion. Enolate ion attacks on carbonyl of ester to form a product.

(b)

Interpretation Introduction

Interpretation: Products of given reactions has to be predicted.

Concept introduction: Given set of conditions gives a final product of reaction through a series of steps.

Ester reacts with a base to form an enolate ion which undergoes intramolecular reaction.

Carboxylic acid undergoes α substitution by Hell Volhard Zelinsky reaction.

A strong base like LDA abstracts α proton from a carbon atom of acetone to form an enolate ion. Enolate ion attacks on carbonyl of ester to form a product.

Ester reacts with a base to form an enolate ion which undergoes intramolecular reaction.

Ester reacts with a base to form an enolate ion which attacks alkyl bromide to form an alkylated product. Hydrolysis and decarboxylation take place to form a product.

A strong base like LDA abstracts α proton from a carbon atom of the ketone to form an enolate ion. Enolate ion attacks on carbonyl of ester to form a product.

(c)

Interpretation Introduction

Interpretation: Products of given reactions has to be predicted.

Concept introduction: Given set of conditions gives a final product of reaction through a series of steps.

Ester reacts with a base to form an enolate ion which undergoes intramolecular reaction.

Carboxylic acid undergoes α substitution by Hell Volhard Zelinsky reaction.

A strong base like LDA abstracts α proton from a carbon atom of acetone to form an enolate ion. Enolate ion attacks on carbonyl of ester to form a product.

Ester reacts with a base to form an enolate ion which undergoes intramolecular reaction.

Ester reacts with a base to form an enolate ion which attacks alkyl bromide to form an alkylated product. Hydrolysis and decarboxylation take place to form a product.

A strong base like LDA abstracts α proton from a carbon atom of the ketone to form an enolate ion. Enolate ion attacks on carbonyl of ester to form a product.

(d)

Interpretation Introduction

Interpretation: Products of given reactions has to be predicted.

Concept introduction: Given set of conditions gives a final product of reaction through a series of steps.

Ester reacts with a base to form an enolate ion which undergoes intramolecular reaction.

Carboxylic acid undergoes α substitution by Hell Volhard Zelinsky reaction.

A strong base like LDA abstracts α proton from a carbon atom of acetone to form an enolate ion. Enolate ion attacks on carbonyl of ester to form a product.

Ester reacts with a base to form an enolate ion which undergoes intramolecular reaction.

Ester reacts with a base to form an enolate ion which attacks alkyl bromide to form an alkylated product. Hydrolysis and decarboxylation take place to form a product.

A strong base like LDA abstracts α proton from a carbon atom of the ketone to form an enolate ion. Enolate ion attacks on carbonyl of ester to form a product.

(e)

Interpretation Introduction

Interpretation: Products of given reactions has to be predicted.

Concept introduction: Given set of conditions gives a final product of reaction through a series of steps.

Ester reacts with a base to form an enolate ion which undergoes intramolecular reaction.

Carboxylic acid undergoes α substitution by Hell Volhard Zelinsky reaction.

A strong base like LDA abstracts α proton from a carbon atom of acetone to form an enolate ion. Enolate ion attacks on carbonyl of ester to form a product.

Ester reacts with a base to form an enolate ion which undergoes intramolecular reaction.

Ester reacts with a base to form an enolate ion which attacks alkyl bromide to form an alkylated product. Hydrolysis and decarboxylation take place to form a product.

A strong base like LDA abstracts α proton from a carbon atom of the ketone to form an enolate ion. Enolate ion attacks on carbonyl of ester to form a product.

(f)

Interpretation Introduction

Interpretation: Products of given reactions has to be predicted.

Concept introduction: Given set of conditions gives a final product of reaction through a series of steps.

Ester reacts with a base to form an enolate ion which undergoes intramolecular reaction.

Carboxylic acid undergoes α substitution by Hell Volhard Zelinsky reaction.

A strong base like LDA abstracts α proton from a carbon atom of acetone to form an enolate ion. Enolate ion attacks on carbonyl of ester to form a product.

Ester reacts with a base to form an enolate ion which undergoes intramolecular reaction.

Ester reacts with a base to form an enolate ion which attacks alkyl bromide to form an alkylated product. Hydrolysis and decarboxylation take place to form a product.

A strong base like LDA abstracts α proton from a carbon atom of the ketone to form an enolate ion. Enolate ion attacks on carbonyl of ester to form a product.

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Answer 3

Question

Definition Definition Class of organic compounds that contain a carboxyl group ( - COOH ) and has a general formula R - COOH or R - CO 2 H , where R refers to the alkyl, alkenyl, aryl, or other groups. They can undergo different chemical reactions, such as acid-base reactions, esterification, and oxidation. These are essential components of living organisms, playing important roles in metabolic processes, signaling, and as pharmaceuticals.

Chapter 18, Problem 48P

(a)

Interpretation Introduction

Interpretation: Products of given reactions has to be predicted.

Concept introduction: Given set of conditions gives a final product of reaction through a series of steps.

Ester reacts with a base to form an enolate ion which undergoes intramolecular reaction.

Carboxylic acid undergoes α substitution by Hell Volhard Zelinsky reaction.

A strong base like LDA abstracts α proton from a carbon atom of acetone to form an enolate ion. Enolate ion attacks on carbonyl of ester to form a product.

Ester reacts with a base to form an enolate ion which undergoes intramolecular reaction.

Ester reacts with a base to form an enolate ion which attacks alkyl bromide to form an alkylated product. Hydrolysis and decarboxylation take place to form a product.

A strong base like LDA abstracts α proton from a carbon atom of the ketone to form an enolate ion. Enolate ion attacks on carbonyl of ester to form a product.

(b)

Interpretation Introduction

Interpretation: Products of given reactions has to be predicted.

Concept introduction: Given set of conditions gives a final product of reaction through a series of steps.

Ester reacts with a base to form an enolate ion which undergoes intramolecular reaction.

Carboxylic acid undergoes α substitution by Hell Volhard Zelinsky reaction.

A strong base like LDA abstracts α proton from a carbon atom of acetone to form an enolate ion. Enolate ion attacks on carbonyl of ester to form a product.

Ester reacts with a base to form an enolate ion which undergoes intramolecular reaction.

Ester reacts with a base to form an enolate ion which attacks alkyl bromide to form an alkylated product. Hydrolysis and decarboxylation take place to form a product.

A strong base like LDA abstracts α proton from a carbon atom of the ketone to form an enolate ion. Enolate ion attacks on carbonyl of ester to form a product.

(c)

Interpretation Introduction

Interpretation: Products of given reactions has to be predicted.

Concept introduction: Given set of conditions gives a final product of reaction through a series of steps.

Ester reacts with a base to form an enolate ion which undergoes intramolecular reaction.

Carboxylic acid undergoes α substitution by Hell Volhard Zelinsky reaction.

A strong base like LDA abstracts α proton from a carbon atom of acetone to form an enolate ion. Enolate ion attacks on carbonyl of ester to form a product.

Ester reacts with a base to form an enolate ion which undergoes intramolecular reaction.

Ester reacts with a base to form an enolate ion which attacks alkyl bromide to form an alkylated product. Hydrolysis and decarboxylation take place to form a product.

A strong base like LDA abstracts α proton from a carbon atom of the ketone to form an enolate ion. Enolate ion attacks on carbonyl of ester to form a product.

(d)

Interpretation Introduction

Interpretation: Products of given reactions has to be predicted.

Concept introduction: Given set of conditions gives a final product of reaction through a series of steps.

Ester reacts with a base to form an enolate ion which undergoes intramolecular reaction.

Carboxylic acid undergoes α substitution by Hell Volhard Zelinsky reaction.

A strong base like LDA abstracts α proton from a carbon atom of acetone to form an enolate ion. Enolate ion attacks on carbonyl of ester to form a product.

Ester reacts with a base to form an enolate ion which undergoes intramolecular reaction.

Ester reacts with a base to form an enolate ion which attacks alkyl bromide to form an alkylated product. Hydrolysis and decarboxylation take place to form a product.

A strong base like LDA abstracts α proton from a carbon atom of the ketone to form an enolate ion. Enolate ion attacks on carbonyl of ester to form a product.

(e)

Interpretation Introduction

Interpretation: Products of given reactions has to be predicted.

Concept introduction: Given set of conditions gives a final product of reaction through a series of steps.

Ester reacts with a base to form an enolate ion which undergoes intramolecular reaction.

Carboxylic acid undergoes α substitution by Hell Volhard Zelinsky reaction.

A strong base like LDA abstracts α proton from a carbon atom of acetone to form an enolate ion. Enolate ion attacks on carbonyl of ester to form a product.

Ester reacts with a base to form an enolate ion which undergoes intramolecular reaction.

Ester reacts with a base to form an enolate ion which attacks alkyl bromide to form an alkylated product. Hydrolysis and decarboxylation take place to form a product.

A strong base like LDA abstracts α proton from a carbon atom of the ketone to form an enolate ion. Enolate ion attacks on carbonyl of ester to form a product.

(f)

Interpretation Introduction

Interpretation: Products of given reactions has to be predicted.

Concept introduction: Given set of conditions gives a final product of reaction through a series of steps.

Ester reacts with a base to form an enolate ion which undergoes intramolecular reaction.

Carboxylic acid undergoes α substitution by Hell Volhard Zelinsky reaction.

A strong base like LDA abstracts α proton from a carbon atom of acetone to form an enolate ion. Enolate ion attacks on carbonyl of ester to form a product.

Ester reacts with a base to form an enolate ion which undergoes intramolecular reaction.

Ester reacts with a base to form an enolate ion which attacks alkyl bromide to form an alkylated product. Hydrolysis and decarboxylation take place to form a product.

A strong base like LDA abstracts α proton from a carbon atom of the ketone to form an enolate ion. Enolate ion attacks on carbonyl of ester to form a product.

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Answer 4

Question

Definition Definition Class of organic compounds that contain a carboxyl group ( - COOH ) and has a general formula R - COOH or R - CO 2 H , where R refers to the alkyl, alkenyl, aryl, or other groups. They can undergo different chemical reactions, such as acid-base reactions, esterification, and oxidation. These are essential components of living organisms, playing important roles in metabolic processes, signaling, and as pharmaceuticals.

Chapter 18, Problem 48P

(a)

Interpretation Introduction

Interpretation: Products of given reactions has to be predicted.

Concept introduction: Given set of conditions gives a final product of reaction through a series of steps.

Ester reacts with a base to form an enolate ion which undergoes intramolecular reaction.

Carboxylic acid undergoes α substitution by Hell Volhard Zelinsky reaction.

A strong base like LDA abstracts α proton from a carbon atom of acetone to form an enolate ion. Enolate ion attacks on carbonyl of ester to form a product.

Ester reacts with a base to form an enolate ion which undergoes intramolecular reaction.

Ester reacts with a base to form an enolate ion which attacks alkyl bromide to form an alkylated product. Hydrolysis and decarboxylation take place to form a product.

A strong base like LDA abstracts α proton from a carbon atom of the ketone to form an enolate ion. Enolate ion attacks on carbonyl of ester to form a product.

(b)

Interpretation Introduction

Interpretation: Products of given reactions has to be predicted.

Concept introduction: Given set of conditions gives a final product of reaction through a series of steps.

Ester reacts with a base to form an enolate ion which undergoes intramolecular reaction.

Carboxylic acid undergoes α substitution by Hell Volhard Zelinsky reaction.

A strong base like LDA abstracts α proton from a carbon atom of acetone to form an enolate ion. Enolate ion attacks on carbonyl of ester to form a product.

Ester reacts with a base to form an enolate ion which undergoes intramolecular reaction.

Ester reacts with a base to form an enolate ion which attacks alkyl bromide to form an alkylated product. Hydrolysis and decarboxylation take place to form a product.

A strong base like LDA abstracts α proton from a carbon atom of the ketone to form an enolate ion. Enolate ion attacks on carbonyl of ester to form a product.

(c)

Interpretation Introduction

Interpretation: Products of given reactions has to be predicted.

Concept introduction: Given set of conditions gives a final product of reaction through a series of steps.

Ester reacts with a base to form an enolate ion which undergoes intramolecular reaction.

Carboxylic acid undergoes α substitution by Hell Volhard Zelinsky reaction.

A strong base like LDA abstracts α proton from a carbon atom of acetone to form an enolate ion. Enolate ion attacks on carbonyl of ester to form a product.

Ester reacts with a base to form an enolate ion which undergoes intramolecular reaction.

Ester reacts with a base to form an enolate ion which attacks alkyl bromide to form an alkylated product. Hydrolysis and decarboxylation take place to form a product.

A strong base like LDA abstracts α proton from a carbon atom of the ketone to form an enolate ion. Enolate ion attacks on carbonyl of ester to form a product.

(d)

Interpretation Introduction

Interpretation: Products of given reactions has to be predicted.

Concept introduction: Given set of conditions gives a final product of reaction through a series of steps.

Ester reacts with a base to form an enolate ion which undergoes intramolecular reaction.

Carboxylic acid undergoes α substitution by Hell Volhard Zelinsky reaction.

A strong base like LDA abstracts α proton from a carbon atom of acetone to form an enolate ion. Enolate ion attacks on carbonyl of ester to form a product.

Ester reacts with a base to form an enolate ion which undergoes intramolecular reaction.

Ester reacts with a base to form an enolate ion which attacks alkyl bromide to form an alkylated product. Hydrolysis and decarboxylation take place to form a product.

A strong base like LDA abstracts α proton from a carbon atom of the ketone to form an enolate ion. Enolate ion attacks on carbonyl of ester to form a product.

(e)

Interpretation Introduction

Interpretation: Products of given reactions has to be predicted.

Concept introduction: Given set of conditions gives a final product of reaction through a series of steps.

Ester reacts with a base to form an enolate ion which undergoes intramolecular reaction.

Carboxylic acid undergoes α substitution by Hell Volhard Zelinsky reaction.

A strong base like LDA abstracts α proton from a carbon atom of acetone to form an enolate ion. Enolate ion attacks on carbonyl of ester to form a product.

Ester reacts with a base to form an enolate ion which undergoes intramolecular reaction.

Ester reacts with a base to form an enolate ion which attacks alkyl bromide to form an alkylated product. Hydrolysis and decarboxylation take place to form a product.

A strong base like LDA abstracts α proton from a carbon atom of the ketone to form an enolate ion. Enolate ion attacks on carbonyl of ester to form a product.

(f)

Interpretation Introduction

Interpretation: Products of given reactions has to be predicted.

Concept introduction: Given set of conditions gives a final product of reaction through a series of steps.

Ester reacts with a base to form an enolate ion which undergoes intramolecular reaction.

Carboxylic acid undergoes α substitution by Hell Volhard Zelinsky reaction.

A strong base like LDA abstracts α proton from a carbon atom of acetone to form an enolate ion. Enolate ion attacks on carbonyl of ester to form a product.

Ester reacts with a base to form an enolate ion which undergoes intramolecular reaction.

Ester reacts with a base to form an enolate ion which attacks alkyl bromide to form an alkylated product. Hydrolysis and decarboxylation take place to form a product.

A strong base like LDA abstracts α proton from a carbon atom of the ketone to form an enolate ion. Enolate ion attacks on carbonyl of ester to form a product.

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Answer 5

Chapter 18, Problem 48P

(a)

Interpretation Introduction

Interpretation: Products of given reactions has to be predicted.

Concept introduction: Given set of conditions gives a final product of reaction through a series of steps.

Ester reacts with a base to form an enolate ion which undergoes intramolecular reaction.

Carboxylic acid undergoes α substitution by Hell Volhard Zelinsky reaction.

A strong base like LDA abstracts α proton from a carbon atom of acetone to form an enolate ion. Enolate ion attacks on carbonyl of ester to form a product.

Ester reacts with a base to form an enolate ion which undergoes intramolecular reaction.

Ester reacts with a base to form an enolate ion which attacks alkyl bromide to form an alkylated product. Hydrolysis and decarboxylation take place to form a product.

A strong base like LDA abstracts α proton from a carbon atom of the ketone to form an enolate ion. Enolate ion attacks on carbonyl of ester to form a product.

(b)

Interpretation Introduction

Interpretation: Products of given reactions has to be predicted.

Concept introduction: Given set of conditions gives a final product of reaction through a series of steps.

Ester reacts with a base to form an enolate ion which undergoes intramolecular reaction.

Carboxylic acid undergoes α substitution by Hell Volhard Zelinsky reaction.

A strong base like LDA abstracts α proton from a carbon atom of acetone to form an enolate ion. Enolate ion attacks on carbonyl of ester to form a product.

Ester reacts with a base to form an enolate ion which undergoes intramolecular reaction.

Ester reacts with a base to form an enolate ion which attacks alkyl bromide to form an alkylated product. Hydrolysis and decarboxylation take place to form a product.

A strong base like LDA abstracts α proton from a carbon atom of the ketone to form an enolate ion. Enolate ion attacks on carbonyl of ester to form a product.

(c)

Interpretation Introduction

Interpretation: Products of given reactions has to be predicted.

Concept introduction: Given set of conditions gives a final product of reaction through a series of steps.

Ester reacts with a base to form an enolate ion which undergoes intramolecular reaction.

Carboxylic acid undergoes α substitution by Hell Volhard Zelinsky reaction.

A strong base like LDA abstracts α proton from a carbon atom of acetone to form an enolate ion. Enolate ion attacks on carbonyl of ester to form a product.

Ester reacts with a base to form an enolate ion which undergoes intramolecular reaction.

Ester reacts with a base to form an enolate ion which attacks alkyl bromide to form an alkylated product. Hydrolysis and decarboxylation take place to form a product.

A strong base like LDA abstracts α proton from a carbon atom of the ketone to form an enolate ion. Enolate ion attacks on carbonyl of ester to form a product.

(d)

Interpretation Introduction

Interpretation: Products of given reactions has to be predicted.

Concept introduction: Given set of conditions gives a final product of reaction through a series of steps.

Ester reacts with a base to form an enolate ion which undergoes intramolecular reaction.

Carboxylic acid undergoes α substitution by Hell Volhard Zelinsky reaction.

A strong base like LDA abstracts α proton from a carbon atom of acetone to form an enolate ion. Enolate ion attacks on carbonyl of ester to form a product.

Ester reacts with a base to form an enolate ion which undergoes intramolecular reaction.

Ester reacts with a base to form an enolate ion which attacks alkyl bromide to form an alkylated product. Hydrolysis and decarboxylation take place to form a product.

A strong base like LDA abstracts α proton from a carbon atom of the ketone to form an enolate ion. Enolate ion attacks on carbonyl of ester to form a product.

(e)

Interpretation Introduction

Interpretation: Products of given reactions has to be predicted.

Concept introduction: Given set of conditions gives a final product of reaction through a series of steps.

Ester reacts with a base to form an enolate ion which undergoes intramolecular reaction.

Carboxylic acid undergoes α substitution by Hell Volhard Zelinsky reaction.

A strong base like LDA abstracts α proton from a carbon atom of acetone to form an enolate ion. Enolate ion attacks on carbonyl of ester to form a product.

Ester reacts with a base to form an enolate ion which undergoes intramolecular reaction.

Ester reacts with a base to form an enolate ion which attacks alkyl bromide to form an alkylated product. Hydrolysis and decarboxylation take place to form a product.

A strong base like LDA abstracts α proton from a carbon atom of the ketone to form an enolate ion. Enolate ion attacks on carbonyl of ester to form a product.

(f)

Interpretation Introduction

Interpretation: Products of given reactions has to be predicted.

Concept introduction: Given set of conditions gives a final product of reaction through a series of steps.

Ester reacts with a base to form an enolate ion which undergoes intramolecular reaction.

Carboxylic acid undergoes α substitution by Hell Volhard Zelinsky reaction.

A strong base like LDA abstracts α proton from a carbon atom of acetone to form an enolate ion. Enolate ion attacks on carbonyl of ester to form a product.

Ester reacts with a base to form an enolate ion which undergoes intramolecular reaction.

Ester reacts with a base to form an enolate ion which attacks alkyl bromide to form an alkylated product. Hydrolysis and decarboxylation take place to form a product.

A strong base like LDA abstracts α proton from a carbon atom of the ketone to form an enolate ion. Enolate ion attacks on carbonyl of ester to form a product.

Answer 6

Chapter 18, Problem 48P

(a)

Interpretation Introduction

Interpretation: Products of given reactions has to be predicted.

Concept introduction: Given set of conditions gives a final product of reaction through a series of steps.

Ester reacts with a base to form an enolate ion which undergoes intramolecular reaction.

Carboxylic acid undergoes α substitution by Hell Volhard Zelinsky reaction.

A strong base like LDA abstracts α proton from a carbon atom of acetone to form an enolate ion. Enolate ion attacks on carbonyl of ester to form a product.

Ester reacts with a base to form an enolate ion which undergoes intramolecular reaction.

Ester reacts with a base to form an enolate ion which attacks alkyl bromide to form an alkylated product. Hydrolysis and decarboxylation take place to form a product.

A strong base like LDA abstracts α proton from a carbon atom of the ketone to form an enolate ion. Enolate ion attacks on carbonyl of ester to form a product.

Answer 7

Chapter 18, Problem 48P

(a)

Interpretation Introduction

Interpretation: Products of given reactions has to be predicted.

Concept introduction: Given set of conditions gives a final product of reaction through a series of steps.

Ester reacts with a base to form an enolate ion which undergoes intramolecular reaction.

Carboxylic acid undergoes α substitution by Hell Volhard Zelinsky reaction.

A strong base like LDA abstracts α proton from a carbon atom of acetone to form an enolate ion. Enolate ion attacks on carbonyl of ester to form a product.

Ester reacts with a base to form an enolate ion which undergoes intramolecular reaction.

Ester reacts with a base to form an enolate ion which attacks alkyl bromide to form an alkylated product. Hydrolysis and decarboxylation take place to form a product.

A strong base like LDA abstracts α proton from a carbon atom of the ketone to form an enolate ion. Enolate ion attacks on carbonyl of ester to form a product.

Answer 8

(b)

Interpretation Introduction

Interpretation: Products of given reactions has to be predicted.

Concept introduction: Given set of conditions gives a final product of reaction through a series of steps.

Ester reacts with a base to form an enolate ion which undergoes intramolecular reaction.

Carboxylic acid undergoes α substitution by Hell Volhard Zelinsky reaction.

A strong base like LDA abstracts α proton from a carbon atom of acetone to form an enolate ion. Enolate ion attacks on carbonyl of ester to form a product.

Ester reacts with a base to form an enolate ion which undergoes intramolecular reaction.

Ester reacts with a base to form an enolate ion which attacks alkyl bromide to form an alkylated product. Hydrolysis and decarboxylation take place to form a product.

A strong base like LDA abstracts α proton from a carbon atom of the ketone to form an enolate ion. Enolate ion attacks on carbonyl of ester to form a product.

Answer 9

(b)

Interpretation Introduction

Interpretation: Products of given reactions has to be predicted.

Concept introduction: Given set of conditions gives a final product of reaction through a series of steps.

Ester reacts with a base to form an enolate ion which undergoes intramolecular reaction.

Carboxylic acid undergoes α substitution by Hell Volhard Zelinsky reaction.

A strong base like LDA abstracts α proton from a carbon atom of acetone to form an enolate ion. Enolate ion attacks on carbonyl of ester to form a product.

Ester reacts with a base to form an enolate ion which undergoes intramolecular reaction.

Ester reacts with a base to form an enolate ion which attacks alkyl bromide to form an alkylated product. Hydrolysis and decarboxylation take place to form a product.

A strong base like LDA abstracts α proton from a carbon atom of the ketone to form an enolate ion. Enolate ion attacks on carbonyl of ester to form a product.

Answer 10

(c)

Interpretation Introduction

Interpretation: Products of given reactions has to be predicted.

Concept introduction: Given set of conditions gives a final product of reaction through a series of steps.

Ester reacts with a base to form an enolate ion which undergoes intramolecular reaction.

Carboxylic acid undergoes α substitution by Hell Volhard Zelinsky reaction.

A strong base like LDA abstracts α proton from a carbon atom of acetone to form an enolate ion. Enolate ion attacks on carbonyl of ester to form a product.

Ester reacts with a base to form an enolate ion which undergoes intramolecular reaction.

Ester reacts with a base to form an enolate ion which attacks alkyl bromide to form an alkylated product. Hydrolysis and decarboxylation take place to form a product.

A strong base like LDA abstracts α proton from a carbon atom of the ketone to form an enolate ion. Enolate ion attacks on carbonyl of ester to form a product.

Answer 11

(c)

Interpretation Introduction

Interpretation: Products of given reactions has to be predicted.

Concept introduction: Given set of conditions gives a final product of reaction through a series of steps.

Ester reacts with a base to form an enolate ion which undergoes intramolecular reaction.

Carboxylic acid undergoes α substitution by Hell Volhard Zelinsky reaction.

A strong base like LDA abstracts α proton from a carbon atom of acetone to form an enolate ion. Enolate ion attacks on carbonyl of ester to form a product.

Ester reacts with a base to form an enolate ion which undergoes intramolecular reaction.

Ester reacts with a base to form an enolate ion which attacks alkyl bromide to form an alkylated product. Hydrolysis and decarboxylation take place to form a product.

A strong base like LDA abstracts α proton from a carbon atom of the ketone to form an enolate ion. Enolate ion attacks on carbonyl of ester to form a product.

Answer 12

(d)

Interpretation Introduction

Interpretation: Products of given reactions has to be predicted.

Concept introduction: Given set of conditions gives a final product of reaction through a series of steps.

Ester reacts with a base to form an enolate ion which undergoes intramolecular reaction.

Carboxylic acid undergoes α substitution by Hell Volhard Zelinsky reaction.

A strong base like LDA abstracts α proton from a carbon atom of acetone to form an enolate ion. Enolate ion attacks on carbonyl of ester to form a product.

Ester reacts with a base to form an enolate ion which undergoes intramolecular reaction.

Ester reacts with a base to form an enolate ion which attacks alkyl bromide to form an alkylated product. Hydrolysis and decarboxylation take place to form a product.

A strong base like LDA abstracts α proton from a carbon atom of the ketone to form an enolate ion. Enolate ion attacks on carbonyl of ester to form a product.

Answer 13

(d)

Interpretation Introduction

Interpretation: Products of given reactions has to be predicted.

Concept introduction: Given set of conditions gives a final product of reaction through a series of steps.

Ester reacts with a base to form an enolate ion which undergoes intramolecular reaction.

Carboxylic acid undergoes α substitution by Hell Volhard Zelinsky reaction.

A strong base like LDA abstracts α proton from a carbon atom of acetone to form an enolate ion. Enolate ion attacks on carbonyl of ester to form a product.

Ester reacts with a base to form an enolate ion which undergoes intramolecular reaction.

Ester reacts with a base to form an enolate ion which attacks alkyl bromide to form an alkylated product. Hydrolysis and decarboxylation take place to form a product.

A strong base like LDA abstracts α proton from a carbon atom of the ketone to form an enolate ion. Enolate ion attacks on carbonyl of ester to form a product.

Answer 14

(e)

Interpretation Introduction

Interpretation: Products of given reactions has to be predicted.

Concept introduction: Given set of conditions gives a final product of reaction through a series of steps.

Ester reacts with a base to form an enolate ion which undergoes intramolecular reaction.

Carboxylic acid undergoes α substitution by Hell Volhard Zelinsky reaction.

A strong base like LDA abstracts α proton from a carbon atom of acetone to form an enolate ion. Enolate ion attacks on carbonyl of ester to form a product.

Ester reacts with a base to form an enolate ion which undergoes intramolecular reaction.

Ester reacts with a base to form an enolate ion which attacks alkyl bromide to form an alkylated product. Hydrolysis and decarboxylation take place to form a product.

A strong base like LDA abstracts α proton from a carbon atom of the ketone to form an enolate ion. Enolate ion attacks on carbonyl of ester to form a product.

Answer 15

(e)

Interpretation Introduction

Interpretation: Products of given reactions has to be predicted.

Concept introduction: Given set of conditions gives a final product of reaction through a series of steps.

Ester reacts with a base to form an enolate ion which undergoes intramolecular reaction.

Carboxylic acid undergoes α substitution by Hell Volhard Zelinsky reaction.

A strong base like LDA abstracts α proton from a carbon atom of acetone to form an enolate ion. Enolate ion attacks on carbonyl of ester to form a product.

Ester reacts with a base to form an enolate ion which undergoes intramolecular reaction.

Ester reacts with a base to form an enolate ion which attacks alkyl bromide to form an alkylated product. Hydrolysis and decarboxylation take place to form a product.

A strong base like LDA abstracts α proton from a carbon atom of the ketone to form an enolate ion. Enolate ion attacks on carbonyl of ester to form a product.

Answer 16

(f)

Interpretation Introduction

Interpretation: Products of given reactions has to be predicted.

Concept introduction: Given set of conditions gives a final product of reaction through a series of steps.

Ester reacts with a base to form an enolate ion which undergoes intramolecular reaction.

Carboxylic acid undergoes α substitution by Hell Volhard Zelinsky reaction.

A strong base like LDA abstracts α proton from a carbon atom of acetone to form an enolate ion. Enolate ion attacks on carbonyl of ester to form a product.

Ester reacts with a base to form an enolate ion which undergoes intramolecular reaction.

Ester reacts with a base to form an enolate ion which attacks alkyl bromide to form an alkylated product. Hydrolysis and decarboxylation take place to form a product.

A strong base like LDA abstracts α proton from a carbon atom of the ketone to form an enolate ion. Enolate ion attacks on carbonyl of ester to form a product.

Answer 17

(f)

Interpretation Introduction

Interpretation: Products of given reactions has to be predicted.

Concept introduction: Given set of conditions gives a final product of reaction through a series of steps.

Ester reacts with a base to form an enolate ion which undergoes intramolecular reaction.

Carboxylic acid undergoes α substitution by Hell Volhard Zelinsky reaction.

A strong base like LDA abstracts α proton from a carbon atom of acetone to form an enolate ion. Enolate ion attacks on carbonyl of ester to form a product.

Ester reacts with a base to form an enolate ion which undergoes intramolecular reaction.

Ester reacts with a base to form an enolate ion which attacks alkyl bromide to form an alkylated product. Hydrolysis and decarboxylation take place to form a product.

A strong base like LDA abstracts α proton from a carbon atom of the ketone to form an enolate ion. Enolate ion attacks on carbonyl of ester to form a product.

Answer 18

Expert Solution & Answer

Answer 19

Expert Solution & Answer

Answer 20

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Answer 21

Ch. 18.1 - Prob. 1P Ch. 18.1 - Prob. 2P Ch. 18.1 - Prob. 3P Ch. 18.1 - Prob. 4P Ch. 18.1 - PROBLEM 5♦ List the compounds in each of the...Ch. 18.2 - Explain why 92% of 2,4-pemtanedione exists as the...Ch. 18.3 - Draw the enol tautomers for each of the following...Ch. 18.3 - Prob. 8P Ch. 18.4 - Prob. 9P Ch. 18.4 - Prob. 10P

Solution Summary: The author explains that Ester reacts with a base to form an enolate ion which undergoes intramolecular reaction.

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Chapter 18 Solutions