Organic Chemistry
9th Edition
ISBN: 9781305080485
Author: John E. McMurry
Publisher: Cengage Learning
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Chapter 27.SE, Problem 18AP
Fats can be either optically active or optically inactive, depending on their structure. Draw the structure of an optically active fat that yields 2 equivalents of stearic acid and 1 equivalent of oleic acid on hydrolysis. Draw the structure of an optically inactive fat that yields the same products.
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Chapter 27 Solutions
Organic Chemistry
Ch. 27.1 - Carnauba wax, used in floor and furniture...Ch. 27.1 - Draw structures of glyceryl tripalmitate and...Ch. 27.2 - Prob. 3PCh. 27.2 - Write the saponication reaction of glyceryl...Ch. 27.4 - Prob. 5PCh. 27.5 - Prob. 6PCh. 27.5 - Prob. 7PCh. 27.6 - Draw the following molecules in chair...Ch. 27.6 - Lithocholic acid is an A–B cis steroid found in...Ch. 27.7 - Prob. 10P
Ch. 27.SE - Prob. 11VCCh. 27.SE - Propose a biosynthetic pathway for the...Ch. 27.SE - Identify the following fatty acid, and tell...Ch. 27.SE - Prob. 14MPCh. 27.SE - Prob. 15MPCh. 27.SE - Prob. 16MPCh. 27.SE - Prob. 17APCh. 27.SE - Fats can be either optically active or optically...Ch. 27.SE - Prob. 19APCh. 27.SE - Show the products you would expect to obtain from...Ch. 27.SE - Draw a Newman projection along the C2-C3 bond of...Ch. 27.SE - The plasmalogens are a group of lipids found in...Ch. 27.SE - Prob. 23APCh. 27.SE - Prob. 24APCh. 27.SE - Prob. 25APCh. 27.SE - Prob. 26APCh. 27.SE - Prob. 27APCh. 27.SE - Prob. 28APCh. 27.SE - Prob. 29APCh. 27.SE - Assume that acetyl CoA containing a 14C isotopic...Ch. 27.SE - Assume that acetyl CoA containing a 14C isotopic...Ch. 27.SE - Assume that acetyl CoA containing a 14C isotopic...Ch. 27.SE - Assume that acetyl CoA containing a 14C isotopic...Ch. 27.SE - Prob. 34APCh. 27.SE - Draw the most stable chair conformation of...Ch. 27.SE - Draw the most stable chair conformation of...Ch. 27.SE - Prob. 37APCh. 27.SE - Prob. 38APCh. 27.SE - Prob. 39APCh. 27.SE - What product would you obtain by reduction of...Ch. 27.SE - Prob. 41APCh. 27.SE - Eleostearic acid, C18H30O2, is a rare fatty acid...Ch. 27.SE - Prob. 43APCh. 27.SE - Prob. 44APCh. 27.SE - Propose a synthesis of diethylstilbestrol (Problem...Ch. 27.SE - Prob. 46APCh. 27.SE - Cembrene, C20H32, is a diterpenoid hydrocarbon...Ch. 27.SE - α-Fenchone is a pleasant-smelling terpenoid...Ch. 27.SE - Prob. 49APCh. 27.SE - Propose a mechanism for the biosynthesis of the...
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Need a deep-dive on the concept behind this application? Look no further. Learn more about this topic, chemistry and related others by exploring similar questions and additional content below.Similar questions
- Complete the following statements: a. Oxidation of a secondary alcohol produces ___________. b. Oxidation of a primary alcohol produces an aldehyde that can be further oxidized to a ________. c. Hydrogenation of a ketone produces __________. d. Hydrogenation of an aldehyde produces __________. e. Hydrolysis of an acetal produces _________. f. Hydrolysis of a ketal produces _________.arrow_forwardConstruct models of the stereoisomers of 2,3-dihydroxysuccinic acid (COOH-CHOHCHOH-COOH). Draw the flying wedge models of the four stereoisomers.arrow_forward+ Mannose is a monosaccharide involved in the glycosylation of certain proteins. Several genetic disorders are associated with enzymes involved in mannose metabolism. Monosaccharides form a new functional group when the straight chain sugar cyclizes. What is the type of functional group formed in mannose after it undergoes cyclization to form the furanose ring? HO OH OH 0- OH OH A) aldehyde B) ketone C) hemi-acetal D) ether E) esterarrow_forward
- 1. What is the main sweetener in your gum? sucrose C₁2H22011 isomalt C12H24O11 mannitol C₁H₁406 maltitol C12H24O11 O sorbitol C6H₁406 Ⓒxyitol C-H12O5arrow_forwardWhen Fructose (shown below) undergoes reduction in the presence of H2 and Pd, two compounds are generated. What is the relationship between the two compounds generated? ОН Но— Н H. OH H OH HO.arrow_forwardDraw a structure for a lactone with 5 carbonsarrow_forward
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- Part 3 of 3 Modify the structure of lactulose to show the monosaccharide products that form from hydrolysis. You may draw the structures in any arrangement that you like, so long as they aren't touching. он H сн, он :☐ Он × 5 H H HO снон Сн, он H Он Н д- Н Н OH Нarrow_forwardDraw the structure of CH3CH(OH)CH2CH2CHO, where -CHO represents an aldehyde group and answer the following questions: 1. What is the name of this compound? 2. Does this compound contain a chiral carbon? If so, what number carbon is chiral? 3. Does this compound give a positive Tollen's test? If so, what would be the observations for this test? Draw the structure for the product of adding Tollen's reagent to the aldehyde? No molecular formulas. 4. What is oxidized? What is reduced? 5. This compound can form a cyclic hemiacetal, since it has an internal OH group and an aldehyde group. What size ring would be formed from this cyclic hemiacetal?arrow_forwardThe esterification reaction of 1 mL each of 1-propanol and propanoic acid is catalyzed with 2-3 drops of sulfuric acid, which is then placed in a test tube in a hot-water bath. After 15 or more minutes, ice water was added. Propyl propanoate is formed. Write the complete equation for the reaction and describe the odor or 1-propanol, propanoic acid, and propyl propanoate.arrow_forward
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