Organic Chemistry: Principles and Mechanisms (Second Edition)
2nd Edition
ISBN: 9780393663556
Author: Joel Karty
Publisher: W. W. Norton & Company
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Question
Chapter 3, Problem 3.9P
Interpretation Introduction
Interpretation:
The hybridization of the N atom in the given molecule is to be determined.
Concept introduction:
Atomic orbitals mix and form an equal number of hybrid orbitals. The number of hybrid orbitals required by an atom in a molecule or an ion is equal to the number of electron groups in its valence shell. In case of atoms from the second row, like carbon, these are formed by mixing of one s AO and the necessary number of p AO(s).
An electron group is a lone pair or a bond. The bond, whether single, double, or triple, counts as just one electron group.
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Instruction: Identify the hybrid orbitals used in the given molecules
Match the given molecular formula with the expected hybridization about the central atom.
What is the hybridization of the atom labeled with arrows in each of the following molecules?
Chapter 3 Solutions
Organic Chemistry: Principles and Mechanisms (Second Edition)
Ch. 3 - Prob. 3.1PCh. 3 - Prob. 3.2PCh. 3 - Prob. 3.3PCh. 3 - Prob. 3.4PCh. 3 - Prob. 3.5PCh. 3 - Prob. 3.6PCh. 3 - Prob. 3.7PCh. 3 - Prob. 3.8PCh. 3 - Prob. 3.9PCh. 3 - Prob. 3.10P
Ch. 3 - Prob. 3.11PCh. 3 - Prob. 3.12PCh. 3 - Prob. 3.13PCh. 3 - Prob. 3.14PCh. 3 - Prob. 3.15PCh. 3 - Prob. 3.16PCh. 3 - Prob. 3.17PCh. 3 - Prob. 3.18PCh. 3 - Prob. 3.19PCh. 3 - Prob. 3.20PCh. 3 - Prob. 3.21PCh. 3 - Prob. 3.22PCh. 3 - Prob. 3.23PCh. 3 - Prob. 3.24PCh. 3 - Prob. 3.25PCh. 3 - Prob. 3.26PCh. 3 - Prob. 3.27PCh. 3 - Prob. 3.28PCh. 3 - Prob. 3.29PCh. 3 - Prob. 3.30PCh. 3 - Prob. 3.31PCh. 3 - Prob. 3.32PCh. 3 - Prob. 3.33PCh. 3 - Prob. 3.34PCh. 3 - Prob. 3.35PCh. 3 - Prob. 3.36PCh. 3 - Prob. 3.37PCh. 3 - Prob. 3.38PCh. 3 - Prob. 3.39PCh. 3 - Prob. 3.40PCh. 3 - Prob. 3.41PCh. 3 - Prob. 3.42PCh. 3 - Prob. 3.43PCh. 3 - Prob. 3.44PCh. 3 - Prob. 3.45PCh. 3 - Prob. 3.46PCh. 3 - Prob. 3.47PCh. 3 - Prob. 3.48PCh. 3 - Prob. 3.49PCh. 3 - Prob. 3.50PCh. 3 - Prob. 3.51PCh. 3 - Prob. 3.52PCh. 3 - Prob. 3.53PCh. 3 - Prob. 3.54PCh. 3 - Prob. 3.55PCh. 3 - Prob. 3.56PCh. 3 - Prob. 3.1YTCh. 3 - Prob. 3.2YTCh. 3 - Prob. 3.3YTCh. 3 - Prob. 3.4YTCh. 3 - Prob. 3.5YTCh. 3 - Prob. 3.6YTCh. 3 - Prob. 3.7YTCh. 3 - Prob. 3.8YTCh. 3 - Prob. 3.9YTCh. 3 - Prob. 3.10YTCh. 3 - Prob. 3.11YTCh. 3 - Prob. 3.12YTCh. 3 - Prob. 3.13YT
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- What is the hybridization of the atom labelled (arrow pointing) in each molecule belowarrow_forwardOrbital representation of the molecule in the image.arrow_forwardProblem Which of the following substances exhibits H bonding? For any that do, show the H bonds between two of its molecules. (a) C̟H, (b) CH;OH (c) CH3C–NH,arrow_forward
- Determine the hybridization of the labeled atom in attached species ?arrow_forwardAssign hybridization state of each carbon, nitrogen, oxygen, halogen, and boron atom indicated with arrows in the molecules below.arrow_forwardIn each of the following equations, what hybridization change, if any, occurs for the underlined atom?arrow_forward
- What is the hybridization at the bond being pointed to?arrow_forwardDetermining Hybridization in a Conjugated System Determine the hybridization around the labeled carbon atom in the following anion.arrow_forwarda) Using the LCAO method, draw the following molecule including all lone pairs of electrons.b) List all atomic and molecular orbitals.arrow_forward
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