Essential Organic Chemistry (3rd Edition)
Essential Organic Chemistry (3rd Edition)
3rd Edition
ISBN: 9780321937711
Author: Paula Yurkanis Bruice
Publisher: PEARSON
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Chapter 4, Problem 1P
  1. a. Draw three constitutional isomers with molecular formula C3H8O.
  2. b. How many constitutional isomers can you draw for C4H10O?

(a)

Expert Solution
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Interpretation Introduction

Interpretation:

The three constitutional isomers of molecular formula C3H8O has to be drawn.

Concept introduction:

Constitutional isomers are having the same molecular formula and different bond connectivity between the atoms.

The general formula for an alkane is CnH2n+2.

Equation for finding constitutional isomers for a molecule

Answer to Problem 1P

  Essential Organic Chemistry (3rd Edition), Chapter 4, Problem 1P , additional homework tip  1

Explanation of Solution

The given molecular formula is C3H8O, it fulfils the general formula for an alkane CnH2n+2, so C3H8O contains only single bonds.

Therefore,

C3H8O can be an alcohol or ether.

The two possible alcohols are,

  CH3CH2CH2OH , Essential Organic Chemistry (3rd Edition), Chapter 4, Problem 1P , additional homework tip  2

The possible ether is,

  CH3CH2OCH3

(b)

Expert Solution
Check Mark
Interpretation Introduction

Interpretation:

The numbers of constitutional isomers of molecular formula C4H10O has to be determined.

Concept introduction:

Constitutional isomers are having the same molecular formula and different bond connectivity between the atoms.

Answer to Problem 1P

The numbers of constitutional isomers of molecular formula C4H10O is 7

Explanation of Solution

The given molecular formula is C4H10O, it fulfils the general formula for an alkane CnH2n+2, so C4H10O contains only single bonds.

Therefore,

C4H10O can be an alcohol or ether.

There will be five alcohol isomers (due to four carbons) and two ether isomers.

Hence,

C4H10O have 7 constitutional isomers.

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Students have asked these similar questions
6) Draw and build 3 isomers for the formula GH2CI2. a. Label one pair as constitutional isomers. b. Label another pair as configurational isomers. Apply the labels "cis" and "trans" to the configurational isomers. C.
a) Draw the two ring flipped conformers of each molecule A and B. Indicate the more stable conformer, respectively. CH3 fCH3 H,C. CH3 H3C. CH3 CI CI A B a) Which is more stable between A and B? Why?
1. Write out all the isomers of the compound with molecular formula C4H10O

Chapter 4 Solutions

Essential Organic Chemistry (3rd Edition)

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Chapter 4 Alkanes and Cycloalkanes Lesson 2; Author: Linda Hanson;https://www.youtube.com/watch?v=AL_CM_Btef4;License: Standard YouTube License, CC-BY
Chapter 4 Alkanes and Cycloalkanes Lesson 1; Author: Linda Hanson;https://www.youtube.com/watch?v=PPIa6EHJMJw;License: Standard Youtube License