Concept explainers
A mixture contains only NaCland
a. the mass of iron in the sample
b. the mass of
c. the mass percent of
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Chemical Principles
- Magnesium metal (a component of alloys used in aircraft and a reducing agent used in the production of uranium, titanium, and other active metals) is isolated from sea water by the following sequence of reactions: Mg2+(aq)+Ca(OH)2(aq)Mg(OH)2(s)+Ca2+(aq)Mg(OH)2(s)+2HCl(aq)MgCl2(s)+2H2O(l)MgCl2(l)electrolysisMg(s)+Cl2+Cl2(g) Sea water has a density of 1.026 g/cm3 and contains 1272 parts per million of magnesium a5 Mg2+(aq) by mass. What mass, in kilograms, of Ca(OH)2; is required to precipitate 99.9% of the magnesium in 1.00103 L of sea water?arrow_forward39. Standard solutions of calcium ion used to test for water hardness are prepared by dissolving pure calcium carbonate. CaCO3, in dilute hydrochloric acid. A 1.745-g sample of CaCO3 is placed in a 250.O-mL volumetric flask and dissolved in HCI. Then the solution is diluted to the calibration mark of the volumetric flask. Calculate the resulting molarity of calcium ion.arrow_forwardOn Easter Sunday, April 3, 1983, nitric acid spilled from a tank car near downtown Denver, Colorado. The spill was neutralized with sodium carbonate: 2HNO3(aq)+Na2CO3(aq)2NaNO3(aq)+H2O(l)+CO2(g) a. Calculate H for this reaction. Approximately 2.0 104 gal nitric acid was spilled. Assume that the acid was an aqueous solution containing 70.0% HNO3 by mass with a density of 1.42 glcm3. What mass of sodium carbonate was required for complete neutralization of the spill, and what quantity of heat was evolved? (Hf for NaNO3(aq) = 467 kJ/mol) b. According to The Denver Post for April 4, 1983, authorities feared that dangerous air pollution might occur during the neutralization. Considering the magnitude of H, what was their major concern?arrow_forward
- When organic compounds containing sulfur are burned, sulfurdioxide is produced. The amount of SO2 formed can be determined by the reaction with hydrogen peroxide: H2O2(aq)+SO2(g)H2SO4(aq) The resulting sulfuric acid is then titrated with a standard NaOH solution. A 1.302-g sample of coal is burned and the SO2 is collected in a solution of hydrogen peroxide. It took 28.44 mL of a 0.1000-M NaOH solution to titrate the resulting sulfuric acid. Calculate the mass percent of sulfur in the coal sample. Sulfuric acid has two acidic hydrogens.arrow_forward4.112 A metallurgical firm wishes to dispose of 1300 gallons of waste sulfuric acid whose molarity is 1.37 M. Before disposal, it will be reacted with calcium hydroxide (slaked lime), which costs $0.23 per pound. (a) Write the balanced chemical equation for this process. (b) Determine the cost that the firm will incur from this use of slaked lime.arrow_forwardWhen organic compounds containing sulfur are burned, sulfur dioxide is produced. The amount of SO2formed can be determined by the reaction with hydrogen peroxide: H2O2(aq)+SO2(g)H2SO4(aq) The resulting sulfuric acid is then titrated with a standard NaOH solution. A 1 .302-g sample of coal is burned, and the SO2is collected in a solution of hydrogen peroxide. It took 28.44 mL of a 0.1000 M NaOH solution to titrate the resulting sulfuric acid. Calculate the mass percent of sulfur in the coal sample. Sulfuric acid has two acidic hydrogens.arrow_forward
- It is stated in Section 6.3 of the text that to balance equations by inspection you start “with the most complicated molecule.” What does this mean? Why is it best to do this?arrow_forwardDetermine the volume of sulfuric acid solution needed to prepare 37.4 g of aluminum sulfate, Al2(SO4)3, by the reaction 2Al(s)+3H2SO4(aq)Al2(SO4)3(aq)+3H2(g) The sulfuric acid solution, whose density is 1.104 g/mL, contains 15.0% H2SO4 by mass.arrow_forwardA 2.5624-g sample of a pure solid alkali metal chloride is dissolved in water and treated with excess silver nitrate. The resulting precipitate, filtered and dried, weighs 3.03707 g. What was the percent by mass of chloride ion in the original compound? What is the identity of the salt?arrow_forward
- A mixture consisting of only sodium chloride (NaCl) andpotassium chloride (KCl) weighs 1.0000 g. When the mixtureis dissolved in water and an excess of silver nitrate isadded, all the chloride ions associated with the originalmixture are precipitated as insoluble silver chloride (AgCl).The mass of the silver chloride is found to be 2.1476 g.Calculate the mass percentages of sodium chloride andpotassium chloride in the original mixture.arrow_forward94. Baking soda (sodium hydrogen carbonate. NaHCO3) is often used to neutralize spills of acids on the benchtop in the laboratory. What mass of NaHCO3 would be needed to neutralize a spill consisting of 25.2 mL of 6.01 M hydrochloric acid solution?arrow_forwardA 300.0-g sample of a solid is made up of a uniform mixture of NaNO3, MgCl2, and BaCl2. A 100.0-g sample of the mixture is dissolved in water and treated with an excess of KOH. The precipitate from the reaction has a mass of 13.47 g. The remaining 200.0-g sample is also dissolved in water and treated with an aqueous solution of AgNO3. The resulting precipitate has a mass of 195.8 g. What are the masses of NaNO3, MgCl2, and BaCl2 in the 300.0-g sample?arrow_forward
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