Concept explainers
(a)
Interpretation:
The product formed by the treatment of ethyl butanoate
Concept introduction:
The replacement or substitution of one
Answer to Problem 22.48P
No product is formed by the treatment of ethyl butanoate with
Explanation of Solution
Esters do not undergo reaction with
Figure 1
No product is formed by the treatment of ethyl butanoate with
(b)
Interpretation:
The product formed by the treatment of ethyl butanoate
Concept introduction:
The replacement or substitution of one functional group with another functional group in any chemical reaction is termed as substitution reaction. The electron rich chemical species that contains negative charge or lone pair of electrons is known as a nucleophile. In nucleophilic acyl substitution reaction, a nucleophile takes the position of a leaving group.
Answer to Problem 22.48P
The product formed by the treatment of ethyl butanoate
Explanation of Solution
Esters undergo hydrolysis under acidic and basic medium. In the given reaction, ester undergoes hydrolysis under acidic medium. One mole of carboxylic acid and one mole of alcohol are produced from the hydrolysis of ethyl butanoate as shown in Figure 2.
Figure 2
The product formed by the treatment of ethyl butanoate
(c)
Interpretation:
The product formed by the treatment of ethyl butanoate
Concept introduction:
The replacement or substitution of one functional group with another functional group in any chemical reaction is termed as substitution reaction. The electron rich chemical species that contains negative charge or lone pair of electrons is known as a nucleophile. In nucleophilic acyl substitution reaction, a nucleophile takes the position of a leaving group.
Answer to Problem 22.48P
The product formed by the treatment of ethyl butanoate
Explanation of Solution
Esters undergo hydrolysis under acidic and basic medium. In the given reaction, ester undergoes hydrolysis under basic medium. One mole of carboxylate ion and one mole of alcohol are produced from the hydrolysis of ethyl butanoate as shown in Figure 3.
Figure 3
The product formed by the treatment of ethyl butanoate
(d)
Interpretation:
The product formed by the treatment of ethyl butanoate
Concept introduction:
The replacement or substitution of one functional group with another functional group in any chemical reaction is termed as substitution reaction. The electron rich chemical species that contains negative charge or lone pair of electrons is known as a nucleophile. In nucleophilic acyl substitution reaction, a nucleophile takes the position of a leaving group.
Answer to Problem 22.48P
The product formed by the treatment of ethyl butanoate
Explanation of Solution
The reaction of ester with ammonia leads to the formation of amide and alcohol. The nitrogen atom of ammonia contains lone pair of electrons. The nitrogen atom acts as a nucleophile and attacks on the electron deficient carbonyl carbon atom of ester. The products formed by the reaction of ethyl butanoate with
Figure 4
The product formed by the treatment of ethyl butanoate
(e)
Interpretation:
The product formed by the treatment of ethyl butanoate
Concept introduction:
The replacement or substitution of one functional group with another functional group in any chemical reaction is termed as substitution reaction. The electron rich chemical species that contains negative charge or lone pair of electrons is known as a nucleophile. In nucleophilic acyl substitution reaction, a nucleophile takes the position of a leaving group.
Answer to Problem 22.48P
The product formed by the treatment of ethyl butanoate
Explanation of Solution
The reaction of ester with primary
Figure 5
The product formed by the treatment of ethyl butanoate
Want to see more full solutions like this?
Chapter 22 Solutions
Organic Chemistry
- OH 15. CH3-C-H ÓCH, The compound above is an example of a(n) a. acetal b. ketal O c. hemiacetal d. hemiketal e. none of the abovearrow_forwardDraw the products of each acid-base reaction. NaOH b. + NazCO3 a. + CH3CH,CH, HO, OHarrow_forwardWhat is the major product of this reaction? 1 equiv HCI -80 °C 身arrow_forward
- What is the reagent in this reaction? a. mCPBA, water, H+ b. H2, Pd c. NaBH4, water d. KMNO4arrow_forwardTollen's reagent, (Ag)+, is an oxidation agent. What are the products of Tollen's reagent reaction with the following molecule? H. Select one: O a. Propanoic acid and Ag+ Ob. Propanol and Ag+arrow_forwardExplain why HCl reacts more rapidly with compound A than compound B. A H H₂C H CH H Barrow_forward
- 4. Complete the following reaction. reagent X H. HCN a) A в reagent Y b) OHarrow_forwardWhich is a thiol? CH3 HS SH b. HO. CH3 H.CS CHa CH C. H. d. భిగింగడి 工 a.arrow_forwardWhat is the major organic product obtained from the following reaction? OH OCHS OH 1. NaOH, H₂O H OCHS 2. H₂O* 3 1arrow_forward
- 2. What is the product(s) of the following reaction? A HN B. N A NH2 [H+] -H₂O C. D. HN 3. What is/are the product(s) of the following reaction? A. B. D [H+] -H₂O C.arrow_forwardWhat is the product of the following reaction? a. C. HO HO LOH 1. OsO4 2. NaHSO3, H₂O b. d. Earrow_forwardWhich reaction will give butanoic acid? A) B) C) D) Br 1. CH3MgBr Na₂Cr₂O7 2. H₂O NaCN Br Mg all of the above Et₂0 H3O+ heat 1. CO₂ 2. H₂Oarrow_forward
- ChemistryChemistryISBN:9781305957404Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCostePublisher:Cengage LearningChemistryChemistryISBN:9781259911156Author:Raymond Chang Dr., Jason Overby ProfessorPublisher:McGraw-Hill EducationPrinciples of Instrumental AnalysisChemistryISBN:9781305577213Author:Douglas A. Skoog, F. James Holler, Stanley R. CrouchPublisher:Cengage Learning
- Organic ChemistryChemistryISBN:9780078021558Author:Janice Gorzynski Smith Dr.Publisher:McGraw-Hill EducationChemistry: Principles and ReactionsChemistryISBN:9781305079373Author:William L. Masterton, Cecile N. HurleyPublisher:Cengage LearningElementary Principles of Chemical Processes, Bind...ChemistryISBN:9781118431221Author:Richard M. Felder, Ronald W. Rousseau, Lisa G. BullardPublisher:WILEY