General Chemistry: Atoms First
2nd Edition
ISBN: 9780321809261
Author: John E. McMurry, Robert C. Fay
Publisher: Prentice Hall
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Question
Chapter 3, Problem 3.114CHP
(a)
Interpretation Introduction
Interpretation:
An element with greatest
Concept introduction:
Electron affinity:
In a gaseous state isolated neutral atom, energy released when an electron is introduced in outermost shell is known as electron affinity. Greater the negative value of electron affinity, the atom has more tendency to accept an electron.
(b)
Interpretation Introduction
Interpretation:
An ion with largest ionic radii in the given set has to be identified and explained.
Concept introduction:
Ionic radii:
It is the half of the distance between two ions which are close together. The size of ions depends on charges of the ions. Ions with positive charge called cations are smaller in size than negative charged anions.
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Arrange the following chemical species in order of increasing atomic radius. Explain your arrangement in each case.
(a) K, Mg, Ca, Al
(b) F–, S2–, Cl–.
5. The atoms and ions Ne, N³-, F, Mg2+, and Si4+ are part of an
isoelectronic series.
(a) Which of these will have the smallest effective nuclear
charge acting on the outermost electron?
(b) Which one possess the greatest effective nuclear charge?
(c) Which ion will be the largest in size? Explain why.
Boron, atomic number 5, occurs naturally as two isotopes, 10B and 11B, with natural abundances of 19.9% and 80.1%, respectively.
(a) In what ways do the two isotopes differ from each other? Does the electronic configuration of 10B differ from that of 11B?
(b) Draw the orbital diagram for an atom of 11B. Which electrons are the valence electrons?
(c) Indicate three ways in which the 1s electrons in boron differ from its 2s electrons.
(d) Elemental boron reacts with fluorine to form BF3, a gas. Write a balanced chemical equation for the reaction of solid boron with fluorine gas.
(e) ΔHf° for BF3(g) is -1135.6 kj/mol. Calculate the standard enthalpy change in the reaction of boron with fluorine.
(f) Will the mass percentage of F be the same in 10BF3 and 11BF3? If not, why is that the case?
Chapter 3 Solutions
General Chemistry: Atoms First
Ch. 3.1 - Prob. 3.1PCh. 3.1 - Which of the following drawings is most likely to...Ch. 3.2 - Give systematic names for the following compounds:...Ch. 3.2 - Write formulas for the following compounds: (a)...Ch. 3.2 - Prob. 3.5CPCh. 3.2 - Give systematic names for the following compounds:...Ch. 3.2 - Prob. 3.7PCh. 3.2 - Prob. 3.8CPCh. 3.3 - Predict the ground-state electron configuration...Ch. 3.3 - What doubly positive ion has the following...
Ch. 3.4 - Prob. 3.11PCh. 3.4 - which of the following spheres represents a K+...Ch. 3.5 - Using the periodic table as your guide, predict...Ch. 3.6 - (a) Which has the larger third ionization energy,...Ch. 3.6 - Three atoms have the following electron...Ch. 3.6 - Order the indicated three elements according to...Ch. 3.7 - Prob. 3.17PCh. 3.7 - Which of the indicated three elements has the...Ch. 3.8 - What noble-gas configurations are the following...Ch. 3.8 - Prob. 3.20PCh. 3.9 - Calculate the net energy change in kilojoules per...Ch. 3.10 - Which substance in each of the following pairs has...Ch. 3.10 - One of the following pictures represents NaCl and...Ch. 3.11 - Prob. 3.24PCh. 3.11 - Complete the following equations so that the same...Ch. 3.12 - Prob. 3.26PCh. 3.12 - Prob. 3.27PCh. 3.14 - Prob. 3.28PCh. 3 - In the following drawings, red spheres represent...Ch. 3 - Which of the following drawings is more likely to...Ch. 3 - Prob. 3.31CPCh. 3 - Prob. 3.32CPCh. 3 - Prob. 3.33CPCh. 3 - Prob. 3.34CPCh. 3 - Prob. 3.35CPCh. 3 - Prob. 3.36CPCh. 3 - Prob. 3.37CPCh. 3 - Prob. 3.38SPCh. 3 - Prob. 3.39SPCh. 3 - Prob. 3.40SPCh. 3 - Prob. 3.41SPCh. 3 - Prob. 3.42SPCh. 3 - Prob. 3.43SPCh. 3 - Prob. 3.44SPCh. 3 - Prob. 3.45SPCh. 3 - Prob. 3.46SPCh. 3 - Prob. 3.47SPCh. 3 - Prob. 3.48SPCh. 3 - Prob. 3.49SPCh. 3 - Prob. 3.50SPCh. 3 - Prob. 3.51SPCh. 3 - Prob. 3.52SPCh. 3 - What is the identity of the element X in the...Ch. 3 - Prob. 3.54SPCh. 3 - Prob. 3.55SPCh. 3 - Prob. 3.56SPCh. 3 - Prob. 3.57SPCh. 3 - Prob. 3.58SPCh. 3 - Prob. 3.59SPCh. 3 - Prob. 3.60SPCh. 3 - Prob. 3.61SPCh. 3 - Prob. 3.62SPCh. 3 - Prob. 3.63SPCh. 3 - Prob. 3.64SPCh. 3 - Prob. 3.65SPCh. 3 - Prob. 3.66SPCh. 3 - Prob. 3.67SPCh. 3 - Which element in each of the following sets has...Ch. 3 - Prob. 3.69SPCh. 3 - Prob. 3.70SPCh. 3 - Prob. 3.71SPCh. 3 - Prob. 3.72SPCh. 3 - Prob. 3.73SPCh. 3 - Prob. 3.74SPCh. 3 - Prob. 3.75SPCh. 3 - Prob. 3.76SPCh. 3 - Prob. 3.77SPCh. 3 - Prob. 3.78SPCh. 3 - Order the following compounds according to their...Ch. 3 - Calculate the energy change in kilojoules per mole...Ch. 3 - Prob. 3.81SPCh. 3 - Prob. 3.82SPCh. 3 - Prob. 3.83SPCh. 3 - Prob. 3.84SPCh. 3 - Prob. 3.85SPCh. 3 - Calculate the overall energy change in kilojoules...Ch. 3 - The estimated lattice energy for CsF2(s) is +2347...Ch. 3 - Prob. 3.88SPCh. 3 - Prob. 3.89SPCh. 3 - Prob. 3.90SPCh. 3 - Prob. 3.91SPCh. 3 - Prob. 3.92SPCh. 3 - Prob. 3.93SPCh. 3 - Prob. 3.94SPCh. 3 - Prob. 3.95SPCh. 3 - Prob. 3.96SPCh. 3 - Prob. 3.97SPCh. 3 - Prob. 3.98SPCh. 3 - Prob. 3.99SPCh. 3 - Prob. 3.100CHPCh. 3 - Prob. 3.101CHPCh. 3 - Prob. 3.102CHPCh. 3 - Prob. 3.103CHPCh. 3 - Prob. 3.104CHPCh. 3 - Prob. 3.105CHPCh. 3 - Prob. 3.106CHPCh. 3 - Prob. 3.107CHPCh. 3 - Prob. 3.108CHPCh. 3 - Prob. 3.109CHPCh. 3 - Prob. 3.110CHPCh. 3 - Prob. 3.111CHPCh. 3 - Prob. 3.112CHPCh. 3 - Prob. 3.113CHPCh. 3 - Prob. 3.114CHPCh. 3 - Given the following information, construct a...Ch. 3 - Given the following information, construct a...Ch. 3 - Consider the electronic structure of the element...Ch. 3 - Prob. 3.118MPCh. 3 - Prob. 3.119MP
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