Organic Chemistry (9th Edition)
9th Edition
ISBN: 9780321971371
Author: Leroy G. Wade, Jan W. Simek
Publisher: PEARSON
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Textbook Question
Chapter 4, Problem 4.40SP
Label each hydrogen atom in the following compounds as primary (1°), secondary (2°), or tertiary (3°).
- a. CH3CH2CH(CH3)2
- b. (CH3)3CCH2CH3
- c. (CH3)2CHCH(CH3)CH2CH3
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4. Use the IUPAC Nomenclature System to name each of the following compounds:
a.
b.
CH,CCH₂CH,
0
HCCHCH₂CH₂
CI O
-C-C-CH₂
Br
CHỊCH,CH,CH,
CH,CCH₂CH₂CH
CH,
CI
CH₂CHCH₂CH
Br
CH, Ô
CH,CCH.CCH.CH.CH,
OH
0
CH₂
CH,CCH₂CH.CH,CHCH,C-H
H,CHCH.CH
CH₂
Part II (70 points)
Directions: Answer each of the questions that follow. Please read the
directions for each question carefully. When structures are required please
draw them Clearly and Neatly. Make sure questions are numbered
clearly as well.
1. (12 points; 2 points each) Give a correct name for each of the following compounds:
CH3
A) CH—CH,C—CHICHCHCH, CH
OH
alf
B) CH-CH₂-
CH₂
-CH₂-CH₂
How many asymmetric carbons are there in the compound below?
CH3
H₂C-N.
CH, OH
D
OA. TWO
B.One
OC. Four
OD. Three
O E. Five
-CEC-CH3
Chapter 4 Solutions
Organic Chemistry (9th Edition)
Ch. 4.3A - Draw Lewis structures for the following free...Ch. 4.3B - a. Write the propagation steps leading to the...Ch. 4.3C - Prob. 4.3PCh. 4.3C - Prob. 4.4PCh. 4.4 - The following reaction has a value of G =...Ch. 4.4 - Under base-catalyzed conditions two molecules of...Ch. 4.5B - When ethene is mixed with hydrogen in the presence...Ch. 4.5B - For each reaction, estimate whether S for the...Ch. 4.7 - a. Propose a mechanism for the free radical...Ch. 4.7 - a. Using bond-dissociation enthalpies from...
Ch. 4.8 - The reaction of tert-butyl chloride with methanol...Ch. 4.8 - Under certain conditions, the bromination of...Ch. 4.8 - When a small piece of plat num is added to a...Ch. 4.10 - Prob. 4.14PCh. 4.10 - Prob. 4.15PCh. 4.12 - The bromination of methane proceeds through the...Ch. 4.12 - a. Using me BDEs in Table4-2 (page 167 ), compute...Ch. 4.13A - What would be the product ratio in the...Ch. 4.13A - Classify each hydrogen atom in the following...Ch. 4.13B - Use the bond-dissociation enthalpies in Tabte4-2...Ch. 4.13B - Prob. 4.21PCh. 4.13B - Prob. 4.22PCh. 4.14 - a. Compute the heats of reaction for abstraction...Ch. 4.14 - 2,3-Dimethylbutane reacts with bromine in the...Ch. 4.14 - Prob. 4.25PCh. 4.15 - Prob. 4.26PCh. 4.15 - Prob. 4.27PCh. 4.16A - Prob. 4.28PCh. 4.16A - Prob. 4.29PCh. 4.16B - Prob. 4.30PCh. 4.16C - Prob. 4.31PCh. 4.16C - Acetonitrile (CH3C N) is deprotonated by very...Ch. 4.16D - Prob. 4.33PCh. 4 - The following reaction is a common synthesis used...Ch. 4 - Consider the following reaction-energy diagram. a....Ch. 4 - Draw a reaction-energy diagram for a one-step...Ch. 4 - Draw a reaction-energy diagram for a two-step...Ch. 4 - Prob. 4.38SPCh. 4 - Treatment of tert-butyl alcohol with concentrated...Ch. 4 - Label each hydrogen atom in the following...Ch. 4 - Prob. 4.41SPCh. 4 - Prob. 4.42SPCh. 4 - Prob. 4.43SPCh. 4 - Prob. 4.44SPCh. 4 - Prob. 4.45SPCh. 4 - Prob. 4.46SPCh. 4 - For each compound, predict the major product of...Ch. 4 - When exactly 1 mole of methane is mixed with...Ch. 4 - Prob. 4.49SPCh. 4 - Prob. 4.50SPCh. 4 - Prob. 4.51SPCh. 4 - When dichloromethane is treated with strong NaOH,...Ch. 4 - Prob. 4.53SPCh. 4 - When a small amount of iodine is added to a...Ch. 4 - Prob. 4.55SPCh. 4 - When healthy, Earths stratosphere contains a low...Ch. 4 - Prob. 4.57SPCh. 4 - lodination of alkanes using iodine (I2) is usually...
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- Which of the following structures have the correct IUPAC names? CI 1 111 H CH3 (R)-2-chloropentane OCH 3 H CH CH₂CH₂CH3 Br-C- RS-1,2-dibromo-1,2-dimethoxyethane O a. O b. I and III O c. I and IV O d. II and III III and IV C-Br OCH 3 || D IV (S)-4-fluoro-4-methylcyclohexene CI CH3 CH3 "F CF CH₂CH3 (S)-2-chloro-2-fluoro butanearrow_forward1. Give the IUPAC name for the following compounds: a. C. e. OH O || b. CH3–CH2–C–0–CH2–CH2–CH3 CH3–CH,—NH, Ο CH3 d. CH3-N-CH₂-CH3 Η | || CH3-CH₂-CH₂-C-N-CH₂-CH3arrow_forwardWhich of the following compounds is chrally? CH3 CH, CH H. H3C. "CH;CH3 CH, Br H. H Br 1 3. One answer must be chosen: only 2 -11 O 3 -1 1,2 O only a1 O only 3 -1 2 Oarrow_forward
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