Pushing Electrons
4th Edition
ISBN: 9781133951889
Author: Weeks, Daniel P.
Publisher: Cengage Learning
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Question
Chapter 3, Problem 26EQ
Interpretation Introduction
Interpretation:
The bond making and breaking in the given species is to be represented.
Concept Introduction:
Molecules also show a simultaneous bond making and breaking. This can be illustrated nicely in the familiar SN2 reaction. A negatively charged nucleophile approaches a carbon atom having a leaving group in a direction anti to the leaving group. The pushable electrons are possessed by the nucleophile and the receptor is the carbon atom. The products are a compound having a C-Nu bond and the anion of the leaving group. Thus, Nu has been substituted for L.
But Carbon need not always be the center of this type of reaction. The removal of an acidic proton from an organic compound by a base is a common occurrence.
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2. What is produced when an amine reacts with water?
A. A primary alcohol and ammonia
B. An amide and a hydrogen (H+) ion
C. An ammonium ion and a hydroxide (OH-) ion
D. An amide and a hydroxide (OH-) ion
1. The distinguishing chemical property that
both an amine and ammonia share is both are
weak bases. What type of product is formed by
the addition of an acid, for instance HCl? Draw
the reaction between a 5 carbon amine and
HCI. Don't forget charges.
2. What is produced when an amine reacts with a strong acid such as HCl?
A. An amine and the OH- ion
B. An amide and the H+ ion
C. An ammonium hydroxide
D. An ammonium salt
Chapter 3 Solutions
Pushing Electrons
Ch. 3 - Prob. 1EQCh. 3 - Prob. 2EQCh. 3 - Prob. 3EQCh. 3 - Prob. 4EQCh. 3 - Prob. 5EQCh. 3 - Prob. 6EQCh. 3 - Here are some exercises in sigma bond breaking....Ch. 3 - Prob. 8EQCh. 3 - Prob. 9EQCh. 3 - Prob. 10EQ
Ch. 3 - Prob. 11EQCh. 3 - Prob. 12EQCh. 3 - Prob. 13EQCh. 3 - Prob. 14EQCh. 3 - Prob. 15EQCh. 3 - Prob. 16EQCh. 3 - Prob. 17EQCh. 3 - Prob. 18EQCh. 3 - Prob. 19EQCh. 3 - Prob. 20EQCh. 3 - Prob. 21EQCh. 3 - Prob. 22EQCh. 3 - Prob. 23EQCh. 3 - Prob. 24EQCh. 3 - Prob. 25EQCh. 3 - Prob. 26EQCh. 3 - Prob. 27EQCh. 3 - Prob. 28EQCh. 3 - Prob. 29EQCh. 3 - Prob. 30EQCh. 3 - The reaction just described is reversible....Ch. 3 - Prob. 32EQCh. 3 - Prob. 59EQ
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