Organic Chemistry
Organic Chemistry
6th Edition
ISBN: 9781936221349
Author: Marc Loudon, Jim Parise
Publisher: W. H. Freeman
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Chapter 4, Problem 4.33P
Interpretation Introduction

(a)

Interpretation:

The product formed by the reaction of given alkene with large excess of hydrogen in the presence of Pd/C is to be drawn.

Concept introduction:

The addition of H2 in presence of catalyst is known as catalytic hydrogenation reaction. This is a syn addition. Hydrogenation reaction is exothermic in nature due to the fact that the bonds are stronger in product than in the reactant.

Interpretation Introduction

(b)

Interpretation:

The product formed by the reaction of given alkene with large excess of hydrogen in the presence of Pd/C is to be drawn.

Concept introduction:

The addition of H2 in presence of catalyst is known as catalytic hydrogenation reaction. This is a syn addition. Hydrogenation reaction is exothermic in nature due to the fact that the bonds are stronger in product than in reactant.

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Acid-catalyzed dehydration of 2,2-dimethyl-1-hexanol gave a number of isomeric alkenes including 2-methyl-2-heptene as shown in the following equation.(a) Write a stepwise mechanism for the formation of 2-methyl-2-heptene, using curved arrows to show the flow of electrons. (b) What other alkenes do you think are formed in this reaction?
Which is the major isolated organic product of the reaction shown? (A) (B) Pd(PPH3)4 KOH
Which of the following statements about 3-iodo-2-methylprop-1-ene is/are true? (i) It has an E isomer and a Z isomer. (ii) It can be converted to an alkyl lithium compound in one step by reacting with lithium metal. (iii) It would react with the following reagent to give 2-methylhept-1-ene as the product: CuLi
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