Organic Chemistry: Structure and Function
Organic Chemistry: Structure and Function
8th Edition
ISBN: 9781319079451
Author: K. Peter C. Vollhardt, Neil E. Schore
Publisher: W. H. Freeman
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Chapter 5, Problem 34P
Interpretation Introduction

Interpretation : From the given compounds, the compounds which are chiral in nature needs to be determined.

Concept Introduction : When in a compound, four different groups are attached to a single atom then it is known as a chiral compound.

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Q5.3 C CH3 CH3 "CH3 CH3 H3C CH3 A в D E るうる。5 OH OH OH OH HO" HO HO"CH3 HO 'CH3 F G H I Is molecule C achiral (and not meso), chiral, or meso? O achiral (and not meso) O chiral O meso Q5.4 D CH3 CH3 CH3 "CH3 CH3 H3C CH3 В E 5555. OH OH OH OH HO HO HO"CH3 HO 'CH3 F G H I Is molecule D achiral (and not meso), chiral, or meso? O achiral (and not meso) O chiral O meso
Draw a structural formula of the S configuration of the compound shown below. • Use the wedge /hash bond tools to indicate stereochemistry where it exists. Include H atoms at chiral centers only. • Ifa group is achiral, do not use wedged or hashed bonds on it. CH3 CH3 CH;CHCHCN CH,CH,CH,CHCH,CH, CH2NH2 Draw a structural formula of the RS configuration of the compound shown below. Use the wedge /hash bond tools to indicate stereochemistry where it exists. • Include H atoms at chiral centers only. If a group is achiral, do not use wedged or hashed bonds on it. ÇI
Consider the following molecule: CH3 H NH₂ 1. Assign the priorities of the four different groups attached to the asymmetric (chiral) carbon in the following compound 2. Hence assign the configuration (R, S) of the stereocentre in the above compound: 3. Identify the two depictions of the correct enantiomer of the compound above: A B C D CH3 NH₂ H CH3 CH3 NH₂ Hi H₂N H H₂C NH₂
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