Organic Chemistry: Structure and Function
8th Edition
ISBN: 9781319079451
Author: K. Peter C. Vollhardt, Neil E. Schore
Publisher: W. H. Freeman
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Chapter 5, Problem 34P
Interpretation Introduction
Interpretation : From the given compounds, the compounds which are chiral in nature needs to be determined.
Concept Introduction : When in a compound, four different groups are attached to a single atom then it is known as a chiral compound.
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Q5.3 C
CH3
CH3
"CH3
CH3 H3C
CH3
A
в
D
E
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OH
OH
OH
OH
HO"
HO
HO"CH3
HO
'CH3
F
G
H
I
Is molecule C achiral (and not meso), chiral, or meso?
O achiral (and not meso)
O chiral
O meso
Q5.4 D
CH3
CH3
CH3
"CH3
CH3 H3C
CH3
В
E
5555.
OH
OH
OH
OH
HO
HO
HO"CH3
HO
'CH3
F
G
H
I
Is molecule D achiral (and not meso), chiral, or meso?
O achiral (and not meso)
O chiral
O meso
Draw a structural formula of the S configuration of the compound shown below.
• Use the wedge /hash bond tools to indicate stereochemistry where it exists.
Include H atoms at chiral centers only.
• Ifa group is achiral, do not use wedged or hashed bonds on it.
CH3
CH3
CH;CHCHCN
CH,CH,CH,CHCH,CH,
CH2NH2
Draw a structural formula of the RS configuration of the compound shown below.
Use the wedge /hash bond tools to indicate stereochemistry where it exists.
• Include H atoms at chiral centers only.
If a group is achiral, do not use wedged or hashed bonds on it.
ÇI
Consider the following molecule:
CH3
H
NH₂
1. Assign the priorities of the four different groups attached to the asymmetric (chiral) carbon in the following compound
2. Hence assign the configuration (R, S) of the stereocentre in the above compound:
3. Identify the two depictions of the correct enantiomer of the compound above:
A
B
C
D
CH3
NH₂
H
CH3
CH3
NH₂
Hi
H₂N
H
H₂C
NH₂
Chapter 5 Solutions
Organic Chemistry: Structure and Function
Ch. 5.1 - Prob. 5.3ECh. 5.1 - Prob. 5.4ECh. 5.1 - Prob. 5.5ECh. 5.2 - Prob. 5.6ECh. 5.2 - Prob. 5.8TIYCh. 5.3 - Prob. 5.9ECh. 5.3 - Prob. 5.11TIYCh. 5.3 - Prob. 5.12ECh. 5.4 - Prob. 5.13ECh. 5.4 - Prob. 5.14E
Ch. 5.4 - Prob. 5.16TIYCh. 5.4 - Prob. 5.17ECh. 5.5 - Prob. 5.18ECh. 5.5 - Prob. 5.19ECh. 5.5 - Prob. 5.20ECh. 5.6 - Prob. 5.21ECh. 5.6 - Prob. 5.22ECh. 5.6 - Prob. 5.23ECh. 5.7 - Prob. 5.24ECh. 5.7 - Prob. 5.26TIYCh. 5.7 - Prob. 5.27ECh. 5 - Prob. 5.1ECh. 5 - Prob. 5.2ECh. 5 - Prob. 30PCh. 5 - Prob. 31PCh. 5 - Prob. 32PCh. 5 - Prob. 33PCh. 5 - Prob. 34PCh. 5 - Prob. 35PCh. 5 - Prob. 36PCh. 5 - Prob. 37PCh. 5 - Prob. 38PCh. 5 - Prob. 39PCh. 5 - Prob. 40PCh. 5 - Prob. 41PCh. 5 - Prob. 42PCh. 5 - Prob. 43PCh. 5 - Prob. 44PCh. 5 - Prob. 45PCh. 5 - Prob. 46PCh. 5 - Prob. 47PCh. 5 - Prob. 48PCh. 5 - Prob. 49PCh. 5 - Prob. 50PCh. 5 - Prob. 51PCh. 5 - Prob. 52PCh. 5 - Prob. 53PCh. 5 - Prob. 54PCh. 5 - Prob. 55PCh. 5 - Prob. 56PCh. 5 - Prob. 57PCh. 5 - Prob. 58PCh. 5 - Prob. 59PCh. 5 - Prob. 60PCh. 5 - Prob. 61PCh. 5 - Prob. 62PCh. 5 - Prob. 63PCh. 5 - Prob. 64PCh. 5 - Prob. 65PCh. 5 - Prob. 66PCh. 5 - Prob. 67PCh. 5 - Prob. 68PCh. 5 - Prob. 69PCh. 5 - Prob. 70PCh. 5 - Prob. 71P
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- Which of the following molecules is/ are chiral? بر H3C H3C H₂C CI CH₂OH H CH3 Main Content CF3 CH3 Br millBrarrow_forwardFor the following compounds, indicate if they are chiral, achiral, or meso НО Н Br Brarrow_forward3. Assign R or S stereochemistry to each of the chiral centers in the molecules below. OH H3C NH2 OH Br CI CH3 OH Br Br Br HO H Harrow_forward
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