Inorganic Chemistry
5th Edition
ISBN: 9780321811059
Author: Gary L. Miessler, Paul J. Fischer, Donald A. Tarr
Publisher: Prentice Hall
expand_more
expand_more
format_list_bulleted
Textbook Question
Chapter 4.3, Problem 4.6E
Prepare a representation flowchart according to the format of Table 4.8 for trans-
Expert Solution & Answer
Want to see the full answer?
Check out a sample textbook solutionStudents have asked these similar questions
Write the reducible representation for all molecular motions of triangular H3.
Make a list of all symmetry operations present in Bh3 and H2O?
HW 1-1: How many independent symmetry operations generate the
compound rotation axis S4 produce?
Chapter 4 Solutions
Inorganic Chemistry
Ch. 4.1 - Prob. 4.1ECh. 4.1 - Find all the symmetry elements in the following...Ch. 4.2 - Use the procedure described previously to verify...Ch. 4.3 - Prob. 4.4ECh. 4.3 - Verify the transformation matrices for the E and...Ch. 4.3 - Prepare a representation flowchart according to...Ch. 4.4 - Which point groups are possible for chiral...Ch. 4.4 - Write the corresponding 99 transformation matrices...Ch. 4.4 - Using the x, y, and z coordinates for each atom in...Ch. 4.4 - Reduce the following representations to their...
Ch. 4.4 - Prob. 4.11ECh. 4.4 - Analysis of the x, y, and z coordinates of each...Ch. 4.4 - Determine the number of IR-active CO stretching...Ch. 4.4 - Prob. 4.14ECh. 4 - Determine the point groups for a. Ethane...Ch. 4 - Determine the point groups for a. Ethylene b....Ch. 4 - Determine the point groups for a. Acetylene b....Ch. 4 - Determine the point groups for a. Naphthalene b....Ch. 4 - Determine the point groups for a. 1,1’ ...Ch. 4 - Determine the point groups for a. Cyclohexane...Ch. 4 - Determine the point groups for a. A sheet of...Ch. 4 - Determine the point groups for a. A flat oval...Ch. 4 - Determine the point groups for a. A triangular...Ch. 4 - Determine the point groups for the examples of...Ch. 4 - Determine the point groups of the molecules in the...Ch. 4 - Determine the point groups of the molecules and...Ch. 4 - Determine the point groups of the following atomic...Ch. 4 - a. Show that a cube has the same symmetry elements...Ch. 4 - Suppose an octahedron can have either yellow or...Ch. 4 - What point groups are represented by the symbols...Ch. 4 - Prob. 4.17PCh. 4 - Determine the point groups for the following flags...Ch. 4 - Prepare a representation flowchart according to...Ch. 4 - For trans-1,2-dichloroethylene, which has C2h...Ch. 4 - Ethylene has D2h symmetry. a. List all the...Ch. 4 - Using the D2d character table, a. Determine the...Ch. 4 - Reduce the following representations to...Ch. 4 - For D4h symmetry use sketches to show that dxy...Ch. 4 - Prob. 4.25PCh. 4 - XeOF4 has one of the more interesting structures...Ch. 4 - Repeat the procedure from the previous problem,...Ch. 4 - For the following molecules, determine the number...Ch. 4 - Prob. 4.29PCh. 4 - The structure of 1,1,2,2-tetraiododisilane is...Ch. 4 - Both cis and trans isomers of IO2F4 have been...Ch. 4 - White elemental phosphorus consists of tetrahedral...Ch. 4 - Complexes of the general formula Fe(CO)5x( PR3)x...Ch. 4 - Prob. 4.35PCh. 4 - Prob. 4.36PCh. 4 - Prob. 4.37PCh. 4 - Prob. 4.38PCh. 4 - Determine the point groups of the following...Ch. 4 - Prob. 4.40PCh. 4 - Determine the point groups of the following: a....Ch. 4 - Use the Internet to search for molecules with the...
Knowledge Booster
Learn more about
Need a deep-dive on the concept behind this application? Look no further. Learn more about this topic, chemistry and related others by exploring similar questions and additional content below.Similar questions
- Neopentane, C(CH3)4, has Tď symmetry, with character table provided below. Suppose the characters of a reducible representation of this point group are x(E) = 17, x(C3) = 2, x(C₂) = 5, x(S4) = -3, and x(od) = -5 (this is shown explicitly in the last row of the character table). (a) Use the T₁ irreducible representation to determine the order of the point group using the Little Orthogonality Theorem (Vallance Eq. 1.15.13, see Problem 3). (b) Determine how many times each irreducible representation in Ta is contained in this reducible representation. Td A₁ A₂ E Τ1 T₂ r E 1 1 2 3 3 17 8C3 1 1 -1 1 0 0 2 3C₂ 1 1 2 -1 6S4 1 -1 1 101 1.5 7 0 1 713 7. 1.5 -1 -1 60d -3 -1 -1 -5arrow_forward1. What can you conclude about the symmetry of the C3H5+ ion as it actually exists, as regards the bond lengths and the distribution of the positive charge?arrow_forward2. We can form a group of symmetry operations, with our operation being do one operation and do another. For a molecule with an isosceles triangle molecule like water, we talked about the 4 symmetry operations as E (do nothing), C2 (rotation by 180°), σv (the reflection of one hydrogen to the other), and σv’ (the reflection from front to back). By putting coordinates on each of the three atoms (z points along the C2 rotation axis, x points from one hydrogen to the other, and y points out of the plane of the molecule) find the “multiplication” table for this group.arrow_forward
- Take the four hydrogen 1s orbitals of CH4 and determine how they transform under Td. b) Confirm that it is possible to reduce this representation to A1 + T2. c) With which atomic orbitals on C would it be possible to form MOs with H1s SALCs of symmetry A1 + T2?arrow_forwardPrepare a representation flowchart for trans- N2F2, which has C2h symmetry.arrow_forward5. Find all the symmetry elements in H2O and derive its character table (Assume the bases are linear, quadratic functions and rotations; x, y, z, x', y, 2, xy, xz, yz, Rr, Ry, Rz) 6. Find all the symmetry elements in NH; and derive its character table also. 7. (1) Using the x, y, and z coordinates for each atom in XeF4, determine the reducible representation for all molecular motions (2) And reduce this representation to its irreducible components (3) And classify these representations into translational, rotational, and vibrational modes. 8. (1) Using the x, y, and z coordinates for each atom in H20, determine the reducible representation for all molecular motions. (2) And reduce this representation to its irreducible components. 9. (1) Classify these representations of H20 into a translational, rotational, and vibrational mode. (2) Do they have a temporary or permanent dipole moment? Please explain it based on the derived modes. 10. (1) Write the corresponding 9 x 9 transformation…arrow_forward
- 1. (7 points) Symmetry is an important topic in chemistry because the symmetry of a molecule may affect its physical and chemical properties. One important task is to identify the point group of a given molecule. Please complete the following tasks for each molecule. Molecule Any LC₂ ? Any oh? Any ov? Point Highest symmetry rotation Group CI H H P H H H H H + CI cl H H 2- H H Br Br H H CI OC MICO OC CO COarrow_forwardGive the ground state electron configurations of(a) Li2 (b) Be2 (c) C2 .Use the symmetry-specific nomenclature appropriate for homonuclear diatomics. Example, Sg would stand for σg. Enclose each MO in parenthesis followed by the number of electrons in that MO, e.g., the entry (1Sg)2 would represent 1σg2. Letter P then is used to represent a pair of π MO's.arrow_forwardTreating the sigma bonds in boron trifluoride, BF3 as vectors, the following reducible representation were D3h E 2C3 3C2 on 253 30 v Tred 3 1 3 To what symmetry representation labels does this reduces to? D E 2C3 3C2 253 30, * + y°. z? A,' 1 1 A2' 1 -1 1 1 -1 R. E' 2 (х, у) (x² – y², xy) A," 1 1 -1 -1 A," 1 1 -1 -1 -1 (R, R,) (xz, yz) E" -1 -2 1 O 2'+E' O 2A1'+ A2' A1" + E" O A1'+ E' O Aj' +E" 2.arrow_forward
- Determine the major axis of symmetry for the following 2-dimensional shape: (А) С, (В) С, (С) С, (D) C6arrow_forwarda )Find the representation of the C2v point group to which a px orbital belongs. b)The four symmetry-adapted linear combinations (SALCs) built from the Cl 3s orbitals in the square planar (D4h) [PtCl4]2– anion have symmetry A1g, B1g, and Eu. List all expected Pt – SALC orbital combinations. and What information does the extended 1D2 term symbol provide about a given atom?arrow_forwardReduce the following reducible representation, r, to obtain the number of constituent reducible representations and then put your answers in the boxes below. Find the character table at this link 2. Ta 8C; 3C, 6S, 60, Г, -1 4 -2 Σ Σ/24 A1 A2 т, T2 Г, - A1+ A2+ E+ T1+ T2arrow_forward
arrow_back_ios
SEE MORE QUESTIONS
arrow_forward_ios
Recommended textbooks for you
- Organic Chemistry: A Guided InquiryChemistryISBN:9780618974122Author:Andrei StraumanisPublisher:Cengage Learning
Organic Chemistry: A Guided Inquiry
Chemistry
ISBN:9780618974122
Author:Andrei Straumanis
Publisher:Cengage Learning
Group Theory - Learn like Expert with 3D animation | Introduction for Beginners | ONE Chemistry; Author: One Chemistry;https://www.youtube.com/watch?v=Lz2ih8fkgDs;License: Standard YouTube License, CC-BY